Complexes of crown ether with the rare earth nitrates  Studies on solubilities of the ternary system, Y(NO3)3.3H2O-B15C5-CH3CN, at 18`C

Acta Chimica Sinica ›› 1983, Vol. 41 ›› Issue (7): 610-615. Previous Articles Next Articles

Original Articles

烯土硝酸盐冠醚配合物Y(NO3)3 3H2O-B15C5-CH3CN三元体系18`C时溶解度的研究

蒋海盈;任德厚;薛鸿福;惠西庆;王秀容

西北大学化学系

发布日期:1983-07-15

Complexes of crown ether with the rare earth nitrates Studies on solubilities of the ternary system, Y(NO3)3.3H2O-B15C5-CH3CN, at 18`C

JIANG HAIYING;REN DEHOU;XUE HONGFU;HUI XIQING;WANG XIURONG

Published:1983-07-15

Abstract

A semimicro method has been used to study the solubilities of the ternary system, Y(NO3)3.3H2O-B15C5-CH3CN, at 18C. The results indicated that there is only one complex formed in this system. The stable complex has been isolated and its composition was determined by chemical analysis to be Y(NO3)3.B15C5.3H2O and the dehydration behavior of the complex was studied using DTA and TG methods.

Key words: PHASE EQUILIBRIUM, SOLUBILITY, TERNARY SYSTEM, CROWN ETHER COMPOUNDS, NITRATE, RARE EARTH METAL COMPLEX

CLC Number:

O611.662

Cite this article

JIANG HAIYING;REN DEHOU;XUE HONGFU;HUI XIQING;WANG XIURONG. Complexes of crown ether with the rare earth nitrates Studies on solubilities of the ternary system, Y(NO3)3.3H2O-B15C5-CH3CN, at 18`C[J]. Acta Chimica Sinica, 1983, 41(7): 610-615.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Lü Xijuan, Zhang Yunhong. Volatility of Ammonium Nitrate in Ultra-viscous Aerosol Droplets by Optical Tweezers [J]. Acta Chimica Sinica, 2020, 78(4): 326-329.
[2]	Wang Chen, Chen Rui, Song Lin, Zhang Naidong. Characteristics of Some Typical Inorganic Oxyacid Free Radicals [J]. Acta Chim. Sinica, 2019, 77(3): 205-212.
[3]	Wu Keyi, Guo Jia. Controllable Synthesis of Multi-Scale Conjugated Microporous Polymer [J]. Acta Chim. Sinica, 2015, 73(6): 480-486.
[4]	Li Mengshan, Huang Xingyuan, Liu Hesheng, Liu Bingxiang, Wu Yan, Ai Fanrong. Solubility Prediction of Gases in Polymers based on Chaotic Self-adaptive Particle Swarm Optimization Artificial Neural Networks [J]. Acta Chimica Sinica, 2013, 71(07): 1053-1058.
[5]	Qiu Yixiang, Wang Shuguang. Theoretical Investigations on Tris(pentamethylcyclopentadienyl) Rare Earth Metal Complexes (C₅Me₅)₃Ln (Ln=Sc, Y, La) [J]. Acta Chimica Sinica, 2012, 70(18): 1930-1938.
[6]	Li Yanxia, Duan Xiaoyong, Li Xianguo, Tang Xuli. Mechanism Study on Photodegradation of Nonylphenol in Water by Intermediate Products Analysis [J]. Acta Chimica Sinica, 2012, 70(17): 1819-1826.
[7]	Hu Jingfang, Sun Jizhou, Bian Chao, Tong Jianhuaa, Li Yang, Xia Shanhong. Study on Micro-sensing Chip of Nitrate Based on Three-dimensional Nano-structured Silver Modified Electrode [J]. Acta Chimica Sinica, 2012, 70(03): 291-296.
[8]	Lü Shaoyi, Shao Ziqiang, Zhang Zhenling, Wang Huiqing, Wang Wenjun. Studies on Rheological Properties of Gelled Propellant Based on New Energetic Cellulose [J]. Acta Chimica Sinica, 2012, 70(02): 200-206.
[9]	CHEN Xiao-Wei, ZHAN Zu-Jin, LI Pu-Rui, GE Zhong-Xue, LEI Ming. Kinetics Study of the Synthesis of Butyl(2-azidoethyl)nitramine from the Reaction of 2-[Butyl(nitro)amino]ethyl nitrate with Sodium Azide [J]. Acta Chimica Sinica, 2011, 69(20): 2523-2526.
[10]	ZHOU Quan-Bao, YIN Xia, WANG Qiong, WANG Cheng. Phase Diagram Prediction of the System Mg(NO₃)₂-MgCl₂-H₂O as Phase Change Materials [J]. Acta Chimica Sinica, 2011, 69(15): 1725-1730.
[11]	DONG Nan, WANG Xiu-Lin, PAN Jin-Pin, TAO Zhu. Influence of Cucurbit(n＝7,8)uril on the Solubility and Stability of Chlorambucil [J]. Acta Chimica Sinica, 2011, 69(12): 1431-1437.
[12]	XU Li-Wei, ZHU Yi-Nian, LIANG Mei-Na, HE Na, LONG Teng-Rui. Study on the Solubility and Stability of the Arsenate/phosphate Fluorapatite Solid Solution at 25 ℃ [J]. Acta Chimica Sinica, 2011, 69(04): 418-424.
[13]	SONG Bo, YU Hao, LIU Cui-Cui, MA Wen-Hui, PENG Xiao-Jun. Synthesis of Near-infrared Water-soluble Asymmetrcial Squarylium Indocyanine Dyes [J]. Acta Chimica Sinica, 2010, 68(24): 2569-2573.
[14]	SANG Shi-Hua, ZHANG Xiao, DIAO Xiang-Pi, XIAO Long-Jun. Metastable Equilibria in the Quinary System of Li^＋, K^＋//, , CO₃^2- ,SO₄^2- , B₄O₇², -H₂O at 288 K [J]. Acta Chimica Sinica, 2010, 68(06): 476-480.
[15]	HONG Chen-Yi, DIAO Hui-Feng, LI Guang, JIANG Jian-Meng. Synthesis and Characterization of Fluorinated Polyimide with High Solubility and Optical Transparency [J]. Acta Chimica Sinica, 2010, 68(05): 449-452.

烯土硝酸盐冠醚配合物Y(NO3)3 3H2O-B15C5-CH3CN三元体系18`C时溶解度的研究

Complexes of crown ether with the rare earth nitrates Studies on solubilities of the ternary system, Y(NO3)3.3H2O-B15C5-CH3CN, at 18`C

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments