Linear and Nonlinear Optical Properties of 1,2,3,4-Tetrahydroquinolin-4-one Derivatives

Acta Chimica Sinica ›› 2008, Vol. 66 ›› Issue (14): 1700-1706. Previous Articles Next Articles

1,2,3,4-四氢喹啉-4-酮衍生物的线性及非线性光学性质

吴伟兵a,c 王明亮*,a 黄维b 孙岳明a
崔一平b 徐春祥b

(a东南大学化学化工学院南京 211189)
(b东南大学电子科学与工程学院南京 210096)
(c南京林业大学制浆造纸工程系南京 210037)

投稿日期:2007-11-12 修回日期:2008-02-26 发布日期:2008-07-28
通讯作者: 王明亮

Linear and Nonlinear Optical Properties of 1,2,3,4-Tetrahydroquinolin-4-one Derivatives

WU, Wei-Bing ^a,c WANG, Ming-Liang ^*,a HUANG, Wei ^b SUN, Yue-Ming ^a
CUI, Yi-Ping ^bXU, Chun-Xiang^b

(a School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189)
(b School of Electronic Science and Engineering, Southeast University, Nanjing 210096)
(c Department of pulp and Paper Making, Nanjing Forestry University, Nanjing 210037)

Received:2007-11-12 Revised:2008-02-26 Published:2008-07-28
Contact: WANG, Ming-Liang

Abstract

A series of 4-dihydroquinolinone derivatives with planar push-pull structure were synthesized including 1-benzyl-2,3-dihydroquinolin-4-one (BDHQ), 2-(2,3-dihydroquinolin-4(1H)-ylidene)malononitrile (DHQM), 1, 6-diketojulolidine (DKJ) and 1, 6-bisdicyanomethylene julolidine (BDCJ). The absorption spectra, one-photon excited fluorescence and two-photon excited fluorescence spectra have been recorded. The derivatives show strong solvatochromism in both their one-photon and two-photon excited fluorescence, sug-gesting great polarity of their excited states. Pumped by femtosecond laser at 800 nm, strong up-conversion emissions in the solution of CH2Cl2 have been observed. Their two-photon absorption cross-sections ob-tained by nonlinear transmission method are in the range of 0.83~23.95×10-50 cm4•s•photon-1. The in-tramolecular charge state upon excited state makes the dominant contribution to the two-photon absorption and two-photon excited fluorescence of theses compounds.

Key words: 1,2,3,4-tetrahydroquinolin-4-one, two-photon excited fluorescence, two-photon absorption, push-pull structure

Cite this article

WU, Wei-Bing ^a,c WANG, Ming-Liang ^*,a HUANG, Wei ^b SUN, Yue-Ming ^a
CUI, Yi-Ping ^b XU, Chun-Xiang^b

. Linear and Nonlinear Optical Properties of 1,2,3,4-Tetrahydroquinolin-4-one Derivatives[J]. Acta Chimica Sinica, 2008, 66(14): 1700-1706.

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1,2,3,4-四氢喹啉-4-酮衍生物的线性及非线性光学性质

Linear and Nonlinear Optical Properties of 1,2,3,4-Tetrahydroquinolin-4-one Derivatives

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