Phase Behavior Study of Diblock Copolymer and Star Homopolymer Blend by Self-consistent Field Theory

Acta Chimica Sinica ›› 2008, Vol. 66 ›› Issue (14): 1707-1712. Previous Articles Next Articles

嵌段共聚物和星型均聚物共混体系相行为的自洽场理论研究

韩文驰唐萍* 张红东杨玉良

(聚合物分子工程教育部重点实验室复旦大学高分子科学系上海 200433)

投稿日期:2007-11-23 修回日期:2008-01-31 发布日期:2008-07-28
通讯作者: 唐萍

Phase Behavior Study of Diblock Copolymer and Star Homopolymer Blend by Self-consistent Field Theory

HAN, Wen-Chi TANG, Ping* ZHANG, Hong-Dong YANG, Yu-Liang

(Key Laboratory of Molecular Engineering of Polymer of Ministry of Education, and Department of Macromolecular Science, Fudan University, Shanghai 200433)

Received:2007-11-23 Revised:2008-01-31 Published:2008-07-28
Contact: TANG, Ping

Abstract

The microphases of blend of AB diblock copolymer and 3-arm A star homopolymer were calculated by using self-consistent field theory (SCFT). The lamellae phase of AB diblock copolymer melts was considered in order to simplify the calculation. It was found that the phase behavior of the blend depended on both the chain length and volume fraction of the star homopolymer. The distribution of star homopolymer within the microphases was investigated based on enthalpic and entropic effects.

Key words: self-consistent field theory (SCFT), diblock copolymer, star homopolymer, blend

Cite this article

HAN, Wen-Chi TANG, Ping* ZHANG, Hong-Dong YANG, Yu-Liang. Phase Behavior Study of Diblock Copolymer and Star Homopolymer Blend by Self-consistent Field Theory[J]. Acta Chimica Sinica, 2008, 66(14): 1707-1712.

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嵌段共聚物和星型均聚物共混体系相行为的自洽场理论研究

Phase Behavior Study of Diblock Copolymer and Star Homopolymer Blend by Self-consistent Field Theory

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