Acta Chimica Sinica ›› 2001, Vol. 59 ›› Issue (7): 1121-1124. Previous Articles     Next Articles

Original Articles

低温-低压水热合成Ba1-xSrxTi1-ySnyO3纳米材料及其 结构与性能研究

丁士文;翟永青;秦江雷;王静;李希茂;孟冬燕;郝凤春   

  1. 河北大学化学与环境科学学院;衡水师范科学校化学系;河北兴隆县半壁山中学
  • 发布日期:2001-07-15

Hydrothermal synthesis, structure and property of Ba1-xSrxTi1-ySnyO3 nanometer materials

Ding Shiwen;Di Yongqing;Qin Jianglei;Wang Jing;Li Ximao;Meng Dongyan;Hao Fengchun   

  • Published:2001-07-15

A series of Ba1-xSrxTi1-ySnyO3(0≤x≤0.5,0≤y≤0.4) solid solutions were synthesized by low-temperature/low- pressure hydrothermal method below 150℃, 0.5MPa XRD pattern and cell parameters-composition figures of these prepared powders demonstrated that they were completely miscible solid solutions in BaTiO3. Furthermore, TEM showed that they were uniform, substantially spherical particles with an average particle size of 80nm in diameter. The sintered ceramics of those powders doped by Sr^2+ and Sn^4+ had dielectric constant ten times higher and dielectric loss six times lower than pure BaTiO3 phase at room temperature.

Key words: STANNATE, STRONTIUM COMPOUNDS, BARIUM COMPOUND, TITANATE, DOPE EFFECT, DIELECTRIC PROPERTY, HYDRO- THERMAL METHOD, NANOPHASE MATERIALS

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