Acta Chimica Sinica ›› 2009, Vol. 67 ›› Issue (23): 2685-2691. Previous Articles     Next Articles

Full Papers

触变性含蜡原油等温胶凝过程特性及模型研究

林名桢,李传宪*,杨飞,马勇   

  1. (中国石油大学(华东) 储运与建筑工程学院 青岛 266555)
  • 投稿日期:2009-03-11 修回日期:2009-06-21 发布日期:2009-08-10
  • 通讯作者: 林名桢 E-mail:linmz1221@126.com

Model and Properties of Isothermal Gelling Process for Thixotropic Waxy Crude Oil

Lin, Mingzhen,Li, Chuanxian*,Yang, Fei, Ma, Yong   

  1. (College of Architecture & Storage Engineering, China University of Petroleum, Qingdao 266555, Shandong Province, China)
  • Received:2009-03-11 Revised:2009-06-21 Published:2009-08-10

The isothermal gelling process of thixotropic waxy crude oil was studied by using a combination of a rheological method and theoretical derivation. A model was established by using a structure parameter method, which has been proved to fit well with the experimental data of four different waxy crude oils; and by taking Qinghai waxy crude oil for example, the properties of isothermal gelling process were analyzed by both experimental data and correlation coefficient of the fitting curves. The results show that the increase of temperature, pre-shear rate and pre-shear time all can result in the weaker structure of waxy crude oil. And the changing rate of structure parameter (dλ/dt) increases with increasing the test temperature and pre-shear time; while the higher the pre-shear rate is, the higher the initial dλ/dt is and the smaller the final dλ/dt is, but the dλ/dt values for the waxy crude oils with pre-shear are all higher than those of the oil without pre-shear all the time.

Key words: waxy crude oil, isothermal gelling process, structure parameter, thixotropy, model