Synthesis and Characterization ofα-Fe2O3/C Composite Anode for Lithium Ion Batteries

doi:10.6023/A1106242

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (01): 51-57.DOI: 10.6023/A1106242 Previous Articles Next Articles

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α-Fe₂O₃/C复合材料的制备及性能研究

吴超^a,b, 庄全超^a, 徐守冬^a, 崔永丽^a, 强颖怀^a, 孙智^a

a. 中国矿业大学材料科学与工程学院锂离子电池实验室徐州221116;
b. 中国矿业大学化学工程学院徐州221116

投稿日期:2011-06-24 修回日期:2011-09-16 发布日期:2012-02-25
通讯作者: 庄全超 E-mail:zhuangquanchao@126.com
基金资助:
中央高校基本科研业务费专项资金(Nos.2010LKHX03,2010QNB04,2010QNB05)、中国矿业大学科技攀登计划(No.ON090237)、江苏省普通高校研究生科研创新计划(No.CX10B-153Z)及2011中国矿业大学培育学科创新能力提升基金(No.2011XK07)资助项目.

Synthesis and Characterization ofα-Fe₂O₃/C Composite Anode for Lithium Ion Batteries

Wu Chao^a,b, Zhuang Quanchao^a, Xu Shoudong^a, Cui Yongli^a, Qiang Yinghuai^a, Sun Zhi^a

a. Li-ion Batteries Lab, School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116;
b. School of Chemical Engineering, China University of Mining and Technology, Xuzhou 221116

Received:2011-06-24 Revised:2011-09-16 Published:2012-02-25
Supported by:
Project was supported by the Fundamental Research Funds for the Central Universities(Nos.2010LKHX03,2010QNB04,2010QNB05)and the Science, Technology“Climbing”Program of CUMT(No.ON090237),the Research&Innovation Funds for Jiangsu Ordinary University Graduate(No.CX10B-153Z) and the Innovation&Ability Enhancement Funds for Fostering Subject of CUMT(No.2011XK07).

The α-Fe₂O₃/C composite was prepared by high-temperature solid-state reaction,its structure and electrochemical performance were characterized by X-ray diffraction(XRD),scanning electron miscro- scopy(SEM),charge/discharge test and electrochemical impedance spectroscopy(EIS).The electrochemical test results indicated that the α-Fe₂O₃/C composite showed an reversible charge capacity of 935.3 mAh·g^-1 after 50 cycles,and had better cycle performance compared with commercial α-Fe₂O₃.Electrochemical impedance spectroscopy test indicated that there appeared three semicircles respectively representing the Li-ion migration in solid electrolyte interface film(SEI film),electrical conductivity and charge transfer in the first lithiation,and their evolutive principles were also investigated.

Key words: lithium ion battery, α-Fe₂O₃/C composite material, EIS, SEI film

Cite this article

Wu Chao, Zhuang Quanchao, Xu Shoudong, Cui Yongli, Qiang Yinghuai, Sun Zhi. Synthesis and Characterization ofα-Fe₂O₃/C Composite Anode for Lithium Ion Batteries[J]. Acta Chimica Sinica, 2012, 70(01): 51-57.

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α-Fe₂O₃/C复合材料的制备及性能研究

Synthesis and Characterization ofα-Fe₂O₃/C Composite Anode for Lithium Ion Batteries

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α-Fe2O3/C复合材料的制备及性能研究