Alkylation Catalysis over the WO3/ZrO2 Solid Acid Catalyst with Hierarchically Porous Structure

doi:10.6023/A1106151

Acta Chimica Sinica ›› 2012, Vol. 0 ›› Issue (04): 423-428.DOI: 10.6023/A1106151 Previous Articles Next Articles

Full Papers

多级孔结构WO₃/ZrO₂ 固体酸催化剂的烷基化催化性能研究

陈崇城^a,b, 陈航榕^b, 叶争青^b, 施剑林^b, 俞建长^a

a 福州大学材料学院福州 350108;
b 中国科学院上海硅酸盐研究所上海 200050

投稿日期:2011-06-15 修回日期:2011-09-25 发布日期:2011-10-24
通讯作者: 陈航榕, 俞建长
基金资助:
国家自然科学基金(No. 50872140)资助项目.

Alkylation Catalysis over the WO₃/ZrO₂ Solid Acid Catalyst with Hierarchically Porous Structure

Chen Chongcheng^a,b, Chen Hangrong^b, Ye Zhengqing^b, Shi Jianlin^b, Yu Jianchang^a

a College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108;
b Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050

Received:2011-06-15 Revised:2011-09-25 Published:2011-10-24
Supported by:
Project supported by National Natural Science Foundation of China (No. 50872140).

Series of WO₃/ZrO₂ solid acid catalysts with hierarchically porous structure were prepared by the one-pot hydrothermal method involving templating from a composite surfactant. The effect of calcination temperatures of the prepared catalysts on the acid strength was studied as well as the total amount of acidity. The reaction of benzene alkylation with 1-dodecene was chosen as model acid catalysis. The results indicated that the acid strength and the total amount of acidity of the prepared catalysts increased with increasing of surface area and crystallization of t-ZrO₂. Such catalyst shows a strong catalytic activity of the alkylation, and both the alkylation conversion and selectivity increase with acid strength. Herein, the catalyst sample calcined at 450 ℃ for 5 h has the highest catalytic activity and selectivity.

Key words: tungsten oxide, zirconia, hierarchically porous, solid acid, alkylation, selectivity

Cite this article

Chen Chongcheng, Chen Hangrong, Ye Zhengqing, Shi Jianlin, Yu Jianchang. Alkylation Catalysis over the WO₃/ZrO₂ Solid Acid Catalyst with Hierarchically Porous Structure[J]. Acta Chimica Sinica, 2012, 0(04): 423-428.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

1 Tian, L.; Li, J. W.; Li, Y. X. Chin. J. Catal. 2008, 29(9), 889.

2 Liu, Y.; Hu, R.-S.; Liu, G.-L.; Xu, C.-M. J. Mol. Catal. 2010, 24(3), 217 (in Chinese). (刘鹰, 胡瑞生, 刘贵丽, 徐春明, 分子催化, 2010, 24(3), 217.)

3 Song, W.; Xu, X.-L.; Shi, H.-X. Fine Chem. Intermed. 2008, 38(3), 62 (in Chinese). (宋伟, 徐雪丽, 史恒欣, 精细化工中间体, 2008, 38(3), 62.)

4 Guerra, S. R.; Merat, L. M. O. C.; San Gil, R. A. S.; Dieguez, L. C. Catal. Today 2008, 223, 133.

5 Craciun, I.; Reyniers, M.-F.; Marin, G. B. J. Mol. Catal. A: Chem. 2007, 277, 1.

6 Bordoloi, A.;. Devassy, B. M.; Niphadkar, P. S.; Joshi, P. N.; Halligudi, S. B. J. Mol. Catal. A: Chem. 2006, 253, 239.

7 Corte′s-Ja′come, M. A.; Angeles-Chavez, C.; Lo′pez- Salinas, E.; Navarrete, J.; Toribio, P.; Toledo, J. A. Appl. Catal. A 2007, 318, 178.

8 Zhang, J. J.; Song, Y. Q.; Zhang, Y. F.; Zhou, X. L.; Jin, Y. Q.; Xu, L. Y. Chin. J. Catal. 2010, 31, 374.

9 Gao, Z.; Chen, J.-M.; Yao, Y.-L. Chem. J. Chin. Univ. 1995, 16, 111 (in Chinese). (高滋, 陈建民, 姚宇宁, 高等学校化学学报, 1995, 16, 111.)

10 Mao, D.-S.; Lu, G.-Z.; Chen, Q.-L.; Lu, W. K. Chemistry 2001, 5, 278 (in Chinese). (毛冬森, 卢冠忠, 陈庆龄, 卢文奎, 化学通报, 2001, 5, 278.)

11 Cui, X.-Y.; Wang, L.; Shen, J. Chem. Res. 2010, 21(3), 92 (in Chinese). (崔晓燕, 王雷, 沈健, 化学研究, 2010, 21(3), 92.)

12 Liu, H. Y.; Ma, Z.; Chu, Y.; Sun, W. D. Colloids Surf. A: Physicochem. Eng. 2006, 287, 10.

13 Zhang, X.; He, D. H.; Zhang, Q. J.; Ye, Q.; Xu, B. Q.; Zhu, Q. M. Appl. Catal. A 2003, 249, 107.

14 Santiesteban, J. G.; Vartuli, J. C.; Han, S.; Bastian, R. D.; Chang, C. D. J. Catal. 2007, 168, 431.

15 Chen, H.-R.; Gu, J.-L.; Shi, J.-L.; Liu, Z.-C.; Gao, J.-H.; Ruan, M.-L.; Yan, D. S. Adv. Mater. 2005, 17, 2010.

16 Katrib, A.; Hemming, F.; Wehrer, P.; Hilaire, L.; Maire, G. J. Electron Spectrosc. Relat. Phenom. 1995, 76, 195.

17 Yang, B.; Lei, J.-R.; Wang, D.-Z.; Huang, N.-K. Chin. J. Atom. Mol. Phys. 2001, 19(1), 41 (in Chinese). (杨斌, 雷家荣, 汪德志, 黄宁康, 原子与分子物理学报, 2001, 19(1), 41.)

18 Asim, N.; Radiman, S.; bin Yarmo, M. A. Mater. Lett. 2007, 61, 2652.

19 Tian, Z.; Qin, Z.-F.; Wang, G.-F.; Dong, M.; Wang, J.-G. J. Fuel Chem. Technol. 2006, 34(5), 612 (in Chinese). (田震, 秦张峰, 王国富, 董梅, 王建国, 燃料化学学报, 2006, 34(5), 612.)

20 Chen, C.-C.; Chen, H.-R.; Yu, J.-C.; Ye, Z.-Q.; Shi, J.-L. Chin. J. Catal. 2011, 32(4), 647 (in Chinese). (陈崇城, 陈航榕, 俞建长, 叶争青, 施剑林, 催化学报, 2011, 32(4), 647.)

[1]	Yaning Li, Xiaoyan Wang, Yong Tang. The Regulation of Stereoselectivity in Radical Polymerization^★ [J]. Acta Chimica Sinica, 2024, 82(2): 213-225.
[2]	Cheng-Qiang Wang, Chao Feng. Applications of Nucleophilic Fluorine Sources in the Selective Fluorofunctionalization of Unsaturated Carbon-Carbon Bonds [J]. Acta Chimica Sinica, 2024, 82(2): 160-170.
[3]	Xianting Huang, Hongliang Han, Jing Xiao, Fan Wang, Zhong-Quan Liu. An I₂O₅/KSCN-Mediated Iodothiocyanation of Alkynes [J]. Acta Chimica Sinica, 2024, 82(1): 5-8.
[4]	Yuhan Wu, Dongdong Zhang, Hongyu Yin, Zhengnan Chen, Wen Zhao, Yuhua Chi. Density Functional Theory Study of Janus In₂S₂X Photocatalytic Reduction of CO₂ under “Double Carbon” Target [J]. Acta Chimica Sinica, 2023, 81(9): 1148-1156.
[5]	Rongjie Yang, Lin Zhou, Bin Su. Selective Detection of Vitamins A and C based on Covalent Organic Framework Modified Electrodes^★ [J]. Acta Chimica Sinica, 2023, 81(8): 920-927.
[6]	Yandong Zhang, Shoufei Zhu. Perspective for Phosphine Ligands with Cyclopropane Backbone^★ [J]. Acta Chimica Sinica, 2023, 81(7): 777-783.
[7]	Yating Zhao, Fan Liu, Qiuan Wang, Wujiong Xia. Visible-Light-Promoted N-Alkylation Reactions of (aza)Aromatic Amines with Ethyl Diazoacetate [J]. Acta Chimica Sinica, 2023, 81(2): 111-115.
[8]	Yeqiang Han, Bingfeng Shi. Palladium(II)-Catalyzed Enantioselective Functionalization of C(sp³)—H Bonds^★ [J]. Acta Chimica Sinica, 2023, 81(11): 1522-1540.
[9]	Xiaomao Tian, Yuequn Lin, Han Zhu, Chao Huang, Bixue Zhu. Enantiomers Identification of Penicillamine by Chiral Mono-Schiff Base Macrocycles [J]. Acta Chimica Sinica, 2023, 81(1): 20-28.
[10]	Yang Zeng, Lan Jiang, Xiaoxin Zhang, Songhai Xie, Yan Pei, Minghua Qiao, Zhen-Hua Li, Hualong Xu, Kangnian Fan, Baoning Zong. W-doped Hierarchically Porous Silica Nanosphere Supported Platinum for Catalytic Glycerol Hydrogenolysis to 1,3-Propanediol [J]. Acta Chimica Sinica, 2022, 80(7): 903-912.
[11]	Tiantian Lü, Wen Ma, Dongsun Zhan, Yanmin Zou, Jilong Li, Meiling Feng, Xiaoying Huang. Two New Three-Dimensional Lanthanide Metal-organic Frameworks for the Highly Efficient Removal of Cs⁺ Ions^※ [J]. Acta Chimica Sinica, 2022, 80(5): 640-646.
[12]	Jun Luo, Lichao Jia, Dong Yan, Jian Li. Performance and Improvement of Ni-based Catalysts for Ethane Dehydrogenation [J]. Acta Chimica Sinica, 2022, 80(3): 317-326.
[13]	Jingpeng Li, Qi Yang, Zhou Zhang, Guiyun Zeng, Teng Liu, Chao Huang. Highly Selective Synthesis of (Z)-N-vinyl Ring N,O-Acetal Derivatives by Multi-component Continuous Flow [J]. Acta Chimica Sinica, 2022, 80(11): 1463-1468.
[14]	Yunfang Xu, Yang Li, Zitong Fu, Shaoyan Lin, Jie Zhu, Lei Wu. Palladium-catalyzed Stereoselective Synthesis of (Z)-[3]Dendralenes [J]. Acta Chimica Sinica, 2022, 80(10): 1369-1375.
[15]	Pusu Yang, Chen-Xu Liu, Wen-Wen Zhang, Shu-Li You. Ir-Catalyzed Enantioselective Friedel-Crafts Type Allylic Substitution of Indolizines [J]. Acta Chimica Sinica, 2021, 79(6): 742-746.

多级孔结构WO₃/ZrO₂ 固体酸催化剂的烷基化催化性能研究

Alkylation Catalysis over the WO₃/ZrO₂ Solid Acid Catalyst with Hierarchically Porous Structure

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

多级孔结构WO3/ZrO2 固体酸催化剂的烷基化催化性能研究