Catalytic Hydroxylation of Benzene to Phenol with Hydrogen Peroxide over Cesium Salts of Keggin-type Heteropoly Acids

doi:10.6023/A12070397

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (22): 2316-2322.DOI: 10.6023/A12070397 Previous Articles Next Articles

Article

Keggin型杂多酸铯盐催化苯羟基化反应

冯素姣, 张丽, 任远航, 岳斌, 叶林, 汪玉, 陈雪莹, 贺鹤勇

复旦大学化学系上海市分子催化和功能材料重点实验室上海 200433

投稿日期:2012-07-09 发布日期:2012-09-23
通讯作者: 岳斌, 贺鹤勇 E-mail:yuebin@fudan.edu.cn; heyonghe@fudan.edu.cn
基金资助:
受国家重点基础研究发展规划项目(No. 2009CB623506), 国家自然科学基金(No. 21173050), 上海市优秀学科带头人计划(No. 10XD1400300)及上海市重点学科建设项目(B108)资助.

Catalytic Hydroxylation of Benzene to Phenol with Hydrogen Peroxide over Cesium Salts of Keggin-type Heteropoly Acids

Feng Sujiao, Zhang Li, Ren Yuanhang, Yue Bin, Ye Lin, Wang Yu, Chen Xueying, He Heyong

Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433

Received:2012-07-09 Published:2012-09-23
Supported by:
Project supported by the National Basic Research Program of China (No. 2009CB623506), the National Natural Science Foundation of China (No. 21173050), the Program of Shanghai Subject Chief Scientist (No. 10XD1400300) and Shanghai Leading Academic Discipline Project (B108).

Three series of cesium salts of Keggin-type heteropoly acids (Cs_xH₃₊_n_-_xPMo₁₂_-_nV_nO₄₀, n＝0, 1, 2, x＝0.5～3.0) prepared by a solid synthesis method have been employed in the catalytic hydroxylation of benzene to phenol with H₂O₂. The effects of vanadium substitution number and cesium content on the catalytic activity, redox ability and hydrophobicity of the catalysts were studied. Cs₂H₃PMo₁₀V₂O₄₀ exhibits high phenol yield (19.2%) and good reusability among the Cs_xH₃₊_n_-_x- PMo₁₂_-_nV_nO₄₀ catalysts.

Key words: heteropoly acid, cesium salt, benzene, hydroxylation, phenol

Cite this article

Feng Sujiao, Zhang Li, Ren Yuanhang, Yue Bin, Ye Lin, Wang Yu, Chen Xueying, He Heyong. Catalytic Hydroxylation of Benzene to Phenol with Hydrogen Peroxide over Cesium Salts of Keggin-type Heteropoly Acids[J]. Acta Chimica Sinica, 2012, 70(22): 2316-2322.

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Keggin型杂多酸铯盐催化苯羟基化反应

Catalytic Hydroxylation of Benzene to Phenol with Hydrogen Peroxide over Cesium Salts of Keggin-type Heteropoly Acids

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