Acta Chimica Sinica ›› 1976, Vol. 34 ›› Issue (1): 17-29. Previous Articles     Next Articles

1,2-二苯基六氟环丁烷的结构及其热解反应

中国科学院上海有机化学研究所氟烃组   

  1. 中国科学院上海有机化学研究所氟烃组
  • 投稿日期:1979-12-02 发布日期:2013-06-03

THE STRUCTURES OF THE 1, 2-DIPHENYLHEXAFLUOROCYCLOBUTANES AND THEIR PYROLYSIS

THE PLUOROCARBON GROUP, SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY, ACADEMIA SINICA   

  1. THE PLUOROCARBON GROUP, SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY, ACADEMIA SINICA
  • Received:1979-12-02 Published:2013-06-03

The structures of the ayclodimerization products of a,β,β-trifiuorostyrene(TFS) have been investigated.The TFS cyclodimers are identical with the thermal cross-oycloadducts of tetrafluoroethylene and 1,2-difluorostilbene.Both components of TFS oyclodimers show difluorostilbene fragments(m/e216) in their mass spectra.Therefore,the structures of the cyclodimers are the 1,2-disubstituted cyclobutanes 1 and 2,i.e.products of the head-to-head oycloaddition.