Acta Chimica Sinica ›› 1965, Vol. 31 ›› Issue (6): 526-530. Previous Articles     Next Articles

悬汞电极阳极溶出伏安法——Ⅳ.纯镓中微量铟、镉、铅的测定

王曙, 張淑云, 朱皎, 程溥   

  1. 兰州大学化学系
  • 投稿日期:1964-10-06 发布日期:2013-06-03

ANODIC STRIPPING VOLTAMMETRY WITH HANGING MERCURY DROP ELECTRODE Ⅳ. DETERMINATION OF TRACE AMOUNTS OF INDIUM, CADMIUM AND LEAD IN PURE GALLIUM

WANG SHU, CHANG SHU-YUIN, CHU GIOU, CHENG PU   

  1. Department of Chemistry, Lanchow University
  • Received:1964-10-06 Published:2013-06-03

An anodic stripping voltammetric method for the simultaneous determination of traces of In, Cd, and Pb in pure gallium has been proposed. The limits of tolerance of Ga, Cu, and Bi have been studied, and the interference of Tl with In has been eliminated. When the cadmium and lead contents are not too low and thallium content is less than 2 μg in 20 ml sample solution, the procedure can be further simplified. Potassium bromide solution (2 M, pH 2) was used as supporting electrolyte. The lowest determinable concentrations of cadmium, indium and lead are 4×10-8, 1.1×10-7, and 2.5×10-8 M, respectively.