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Acta Chimica Sinica ›› 1958, Vol. 24 ›› Issue (2): 170-173. Previous Articles Next Articles
于同隐, 徐凌云, 吴世晖
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YU TUNG-YIN, HSU LIN-YUEN, WU SHIH-HUEI
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The following tetraarylsilanes,which contain two different kinds of radicals,have been synthesized by means of Wurtz reaction.They are triphenyl-ρ-tolylsilane,diphenyldi-ρ-tolylsilane and 2,7-dimethyl-9,9-diphenylsilicoxanthene,and the last one is a new heterocyclic compound containing silicon and oxygen as the hetero-atoms.When Wurtz reaction was applied to the synthesis of tetraarylsilanes with ortho-substituent in the aryl groups,only triarylchlorosilanes were obtained in low yield even at a higher reaction temperature.
YU TUNG-YIN, HSU LIN-YUEN, WU SHIH-HUEI. ORGANOSILICON COMPOUNDS Ⅰ. THE APPLICATION OF WURTZ REACTION TO THE SYNTHESES OF TETRAARYLSILANES[J]. Acta Chimica Sinica, 1958, 24(2): 170-173.
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