Synthesis, Structural Feature and Intercluster Interaction of a Series of Compounds Containing Binuclear Molybdenum(Tungsten) Cluster Anion

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (3): 253-261. Previous Articles Next Articles

系列含二核钼(钨)簇阴离子化合物的合成、结构特征和簇间相互作用

卢绍芳, 朱永宝, 梁玉仓, 余荣民, 黄小荥, 孙福侠, 吴锵金, 黄子祥

中国科学院福建物质结构研究所, 结构化学国家重点实验室, 福州, 350002

投稿日期:2003-08-25 修回日期:2003-11-07 发布日期:2014-01-26
通讯作者: 卢绍芳,E-mail:lsf@ms.fjirsm.ac.cn E-mail:lsf@ms.fjirsm.ac.cn
基金资助:
国家自然科学基金(Nos.29673046,29733090)、福建省自然科学基金(No.B96018)和结构化学国家重点实验室基金资助项目.

Synthesis, Structural Feature and Intercluster Interaction of a Series of Compounds Containing Binuclear Molybdenum(Tungsten) Cluster Anion

LU Shao-Fang, ZHU Yong-Bao, LIANG Yu-Cang, YU Rong-Min, HUANG Xiao-Ying, SUN Fu-Xia, WU Qiang-Jin, HUANG Zi-Xiang

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002

Received:2003-08-25 Revised:2003-11-07 Published:2014-01-26

Abstract

The syntheses, crystal structures and bonding features of a series of nine cluster compounds with [(M₂O_nS_4-n)(i-mnt)₂]^2- (M=Mo, W; i-mnt=S₂CC(CN)₂^2-; n=0, 1, 2) as the cluster anion and some organic groups such as R₄N (R=alkyl), protonated 4,4'-bpy etc., or alkali metals Cs, K, or Ni(Ⅱ), Mn(Ⅱ)-centered complexes as the cation are systematically described. These compounds possess a dimeric, chain-like, layer-like or clathrate packing structure linked by S…S, S…Cl, Cl…Cl supramolecular interaction and interionic hydrogen bond. Their band structures are calculated by using tight-bind method within the extended Hückle scheme. The results show that it is the intercluster or interionic interaction that produces the possibility of the charge transfer between the clusters. The measurement of the temperature-change specific conductivity gives the evidence that these cluster compounds possess electroconductivity of semiconductor.

Key words: binuclear molybdenum(tungsten)-sulfur cluster compound, ligand i-mnt, synthesis, crystal structure, intercluster or interionic interaction, energy band analysis, conductivity

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LU Shao-Fang, ZHU Yong-Bao, LIANG Yu-Cang, YU Rong-Min, HUANG Xiao-Ying, SUN Fu-Xia, WU Qiang-Jin, HUANG Zi-Xiang. Synthesis, Structural Feature and Intercluster Interaction of a Series of Compounds Containing Binuclear Molybdenum(Tungsten) Cluster Anion[J]. Acta Chimica Sinica, 2004, 62(3): 253-261.

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系列含二核钼(钨)簇阴离子化合物的合成、结构特征和簇间相互作用

Synthesis, Structural Feature and Intercluster Interaction of a Series of Compounds Containing Binuclear Molybdenum(Tungsten) Cluster Anion

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