Study of Host-Guest Complexation between β-Cyclodextrin and 3-Alkoxyl-2-hydroxypropyl Trimethyl Ammonium Bromides in Aqueous Solutions with Microcalorimetry

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (13): 1247-1251. Previous Articles Next Articles

微量热法研究β-环糊精与3-烷氧基-2-羟丙基三甲基溴化铵的相互作用

孙得志, 王世兵, 魏西莲, 尹宝霖, 李林尉

聊城大学化学化工学院, 聊城, 252059

投稿日期:2003-06-06 修回日期:2004-01-02 发布日期:2014-02-17
通讯作者: 孙得志,E-mail:sundezhisdz@163.com;dzsun@eyou.com;Fax:0635-8239121. E-mail:sundezhisdz@163.com

Study of Host-Guest Complexation between β-Cyclodextrin and 3-Alkoxyl-2-hydroxypropyl Trimethyl Ammonium Bromides in Aqueous Solutions with Microcalorimetry

SUN De-Zhi, WANG Shi-Bing, WEI Xi-Lian, YIN Bao-Lin, LI Lin-Wei

Department of Chemistry, Liaocheng University, Liaocheng 252059

Received:2003-06-06 Revised:2004-01-02 Published:2014-02-17

Abstract

Interactions between β-cyclodextrin (β-CD) and 3-alkoxyl-2-hydroxypropyl trimethyl ammonium bromides (C_nNBr), a new kind of surfactants synthesized in this laboratory, in aqueous solutions were investigated with titration microcalorimetry at 298.15 K.The results were discussed in the light of hydrophobic interaction of β-CD with C_nNBr and the iceberg structure made up of water molecules around hydrophobic tail of the surfactant.Stoichiometry of the host-guest complex changes from 1:1 to 2:1 as the number of carbon atoms (n) in hydrophobic chain, C_nH_2n+1O, increases from 8 to 14.All the complexes are quite stable with the apparent experiential stability constants being β₁=1.08×10³ dm 3·mol^-1, β₁=28.66×10³ dm³·mol^-1 and β₂=141.9×10³ dm 6·mol^-2, respectively for n=8, 12, 14.All the complexation processes are proved to be both enthalpy and entropy beneficial, and the standard thermal effect increases, while standard entropy change decreases, with the hydrophobic chain becoming longer.

Key words: β-cyclodextrin, 3-alkoxyl-2-hydroxypropyl, microcalorimetry, host-guest complex

Cite this article

SUN De-Zhi, WANG Shi-Bing, WEI Xi-Lian, YIN Bao-Lin, LI Lin-Wei. Study of Host-Guest Complexation between β-Cyclodextrin and 3-Alkoxyl-2-hydroxypropyl Trimethyl Ammonium Bromides in Aqueous Solutions with Microcalorimetry[J]. Acta Chimica Sinica, 2004, 62(13): 1247-1251.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Lehn, J.-M. Angew. Chem., Int. Ed. Engl. 1988, 27, 89.
[2] Rudiger, V.; Eliseev, A.; Simova, S.; Schneider, H.-J.; Blandamer, M. J.; Cullis, P. M.; Meyer, A. J. Chem. Soc., Perk. Trans. 2 1996, 2, 2119.
[3] Du, X.-Z.; Zhang, Y.; Jiang, Y.-B.; Lin, L.-R.; Huang, X.-Z.; Chen, G.-Z. Acta Chim. Sinica 1998, 56, 453 (in Chinese).(杜新贞, 张勇, 江云宝, 林丽榕, 黄贤智, 陈国珍, 化学学报, 1998, 56, 453.)
[4] García-Río, L.; Leis, J. R.; Mejuto, J. C.; Pérez-Juste, J. J. Phys. Chem. B 1997, 101, 7383.
[5] Topchieva, I.; Kartezin, K. J. Colloid Interface Sci. 1999, 29, 213.
[6] Cunha-Silva, L.; Teixeia-Dias, J. J. C. J. Phys. Chem. B 2002, 106, 3323.
[7] Jiang, X.-K.; Ji, G.-Z. Chemistry 2003, (3), 147 (in Chinese).(蒋锡夔, 计国桢, 化学通报, 2003, (3), 147.)
[8] Lisi, R. D.; Milioto, S.; Muratore, N. J. Phys. Chem. B 2002, 106, 8944.
[9] Rekharsky, M. V.; Inoue, Y. Chem. Rev. 1998, 98, 1875.
[10] Hedges, A. R. Chem. Rev. 1998, 98, 2035.
[11] Bai, G.; Wang, Y.; Yan, H. J. Phys. Chem. B 2002, 106, 2153.
[12] Xie, C.-L.; Tang, H.-K.; Song, Z.-H.; Qu, S.-S. Thermochim. Acta 1988, 123, 33.
[13] Xie, C.-L.; Xu, G.-D.; Qu, S.-S. Acta Phys.-Chim. Sin. 1986, 2, 362.(谢昌礼, 徐桂端, 屈松生, 物理化学学报, 1986, 2, 362.)
[14] Yin, B.-L.; Wei, X.-L.; Sun, D.-Z. China Surfactant Detergent & Cosmetics 2002, 32, 1 (in Chinese).(尹宝霖, 魏西莲, 孙得志, 日用化学工业, 2002, 32, 1.)
[15] Jacobson, A. M.; Casassa, Z. J. Colloid Interface Sci. 1991, 142, 489.
[16] Kiraly, Z.; Dekany, I. J. Colloid Interface Sci. 2001, 242, 214.
[17] Gómez-Oreíllana, I.; Hallén, D. Thermochim. Acta 1993, 221, 183.
[18] Betzel, C.; Saenger, W.; Hingerty, B. E.; Brown, G. M. J. Am. Chem. Soc. 1984, 106, 7545.
[19] Zabel, V.; Saenger, W.; Mason, S. A. J. Am. Chem. Soc. 1986, 108, 3664.
[20] Frank, H. S.; Evans, M. W. J. Chem. Phys. 1945, 13, 507.
[21] Rekharsky, M. V.; Inoue, Y. Chem. Rev. 1998, 98, 1875.

微量热法研究β-环糊精与3-烷氧基-2-羟丙基三甲基溴化铵的相互作用

Study of Host-Guest Complexation between β-Cyclodextrin and 3-Alkoxyl-2-hydroxypropyl Trimethyl Ammonium Bromides in Aqueous Solutions with Microcalorimetry

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Li Yuesheng, Li Benqiang, Sun Shaofa. Microcalorimetric and Microscopic Studies on the Antibacterial Activities of CdTe(QDs)/TiO₂ Nanocomposites and the Mechanism of Cell Damage on Escherichia coli [J]. Acta Chimica Sinica, 2013, 71(12): 1656-1662.
[2]	Huang Xu, Han Yuchun, Wang Yilin. Thermodynamic Investigation on Micellization of Cationic Gemini Surfactants with Nitrophenoxy Groups in Hydrophobic Chains [J]. Acta Chimica Sinica, 2013, 71(06): 897-905.
[3]	Fan Gaochao, Huang Zaiyin, Chen Jie, Ma Yujie. Impact of Size Effects on the Thermodynamic Properties of Zinc Oxide Micro/nano System [J]. Acta Chimica Sinica, 2012, 70(07): 938-942.
[4]	WANG Lu-De, WANG Teng-Hui, GUO Yun-Xiao, HUANG Zai-Yin. Preparation and Standard Molar Enthalpy of Formation for the Octahedron BaMoO₄ Nanostructures [J]. Acta Chimica Sinica, 2011, 69(21): 2637-2640.
[5]	YANG Chu-Juan, KONG Chang-Jing, ZHANG Ge, BI Gong-Yan, LI Jing, ZHANG Hong-Lin. Study on Enzymatic Degradation of Cellulose in Diisooctyl Succinate Sodium Sulfonate (AOT)/Triton X-100 Mixed Reverse Micellar System [J]. Acta Chimica Sinica, 2010, 68(9): 839-844.
[6]	ZHANG Shao-Feng, YAN Dan, TANG Hui-Ying, FENG Xue, HAN Yu-Mei, YANG Ming, WANG Yue-Sheng, XIAO Xiao-He. Microcalorimetric Investigation on Physiological Activity of Red Blood Cells Affected by Excipient of Polysorbate 80 [J]. Acta Chimica Sinica, 2010, 68(20): 2119-2124.
[7]	DAI Chun-Mei, WANG Ga-Ba, KONG Wei-Jun, XIAO Xiao-He, BANG Cheng, DIAO Yan-Ling, JIN Cheng. Investigation on the Antibacterial Activity of Coptis chinensis Franch and Its Components Compatibility by Microcalorimetry [J]. Acta Chimica Sinica, 2010, 68(10): 936-940.
[8]	TANG Hui-Yang, HAN Yu-Mei, YAN Dan, ZHANG Shao-Feng, LUO Yun, XIAO Xiao-He, LIU Rong-Hua, BANG Cheng. Microcalorimetric Investigation of Toxic Effects of Diester Diterpenoid Alkaloids from Aconiti Class on Tetrahymena thermophila BF5 Growth [J]. Acta Chimica Sinica, 2010, 68(03): 205-210.
[9]	JUE Chi-Qing, LIN Rui-Sen, FANG Wen-Jun. Disturbance of Environmental Atmosphere on the Growth Rate Constants of E. coli Determined by Microcalorimetry Ampoule Method [J]. Acta Chimica Sinica, 2010, 68(01): 50-54.
[10]	. Selective Oxidation of p-Methoxybenzaldehyde in the Presence of β-Cyclodextrin [J]. Acta Chimica Sinica, 2009, 67(9): 910-916.
[11]	. Influences of Composition of Mobile Phase and Temperature on the Enantioseparation of Four Kinds of Secondary Alcohols on Derived β-Cyclodextrin Bonded Stationary Phase [J]. Acta Chimica Sinica, 2009, 67(3): 219-224.
[12]	JUE Chi-Qing, LIN Rui-Sen, FANG Wen-Jun. Microcalorimetry investigation on active position of Vitex negundo Linn against E. coli [J]. Acta Chimica Sinica, 2009, 67(23): 2692-2696.
[13]	KONG Wei-Jun, DIAO Yan-Ling, WANG Ga-Ba, XIAO Xiao-He. Investigation on the Anti-Candida albicans Effect of Palmatine Hydrochloride Based on Microcalorimetry and Principal Component Analysis [J]. Acta Chimica Sinica, 2009, 67(21): 2511-2516.
[14]	WANG En-Ju, CHEN Guang-Yang, HAN Chang-Ri. A Novel Inclusion Complex of 8-Hydroxyquinoline Sandwiched Between Two β-Cyclodextrins [J]. Acta Chimica Sinica, 2009, 67(21): 2527-2530.
[15]	. Molecular Dynamics Simulation on β-Cyclodextrin and Steroids [J]. Acta Chimica Sinica, 2009, 67(12): 1318-1324.