Preparation of Supported Nano-gold Catalysts for Selective Hydrogenation of Maleic Anhydride

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (13): 1242-1246. Previous Articles Next Articles

金催化顺丁烯二酸酐的选择加氢反应

马宇春, 石峰, 熊海, 张庆华, 邓友全

中国科学院兰州化学物理研究所, 生态与绿色化学研究发展中心, 兰州, 730000

投稿日期:2003-07-07 修回日期:2004-03-02 发布日期:2014-02-17
通讯作者: 邓友全,E-mail:ydeng@ns.lzb.ac.cn;Fax:0931-8277088 E-mail:ydeng@ns.lzb.ac.cn
基金资助:
国家自然科学基金(No.20173068)资助项目.

Preparation of Supported Nano-gold Catalysts for Selective Hydrogenation of Maleic Anhydride

MA Yu-Chun, SHI Feng, XIONG Hai, ZHANG Qing-Hua, DENG You-Quan

Centre for Ecological and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000

Received:2003-07-07 Revised:2004-03-02 Published:2014-02-17

Abstract

A series of supported nano-gold catalysts were prepared through sol-gel method and their catalytic activities for selective hydrogenation of maleic anhydride were investigated.The effects of reaction temperature, reaction solvent, preparation conditions of the catalyst and catalyst reuse were also studied.The results showed that catalyst Au/SiO₂-O(C) exhibited the highest catalytic performance to yield succinic anhydride or diethyl succinate with a selectivity exceed 99.5%.

Key words: gold catalyst, selective hydrogenation, maleic anhydride, sol-gel method

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MA Yu-Chun, SHI Feng, XIONG Hai, ZHANG Qing-Hua, DENG You-Quan. Preparation of Supported Nano-gold Catalysts for Selective Hydrogenation of Maleic Anhydride[J]. Acta Chimica Sinica, 2004, 62(13): 1242-1246.

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金催化顺丁烯二酸酐的选择加氢反应

Preparation of Supported Nano-gold Catalysts for Selective Hydrogenation of Maleic Anhydride

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