Rapid Synthesis of XC-72 and Carbon Nanotubes Supported PtRu Nanoparticles by Microwave Irradiation for Methanol Electrooxidation Application

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (17): 1590-1594. Previous Articles Next Articles

XC-72碳和碳纳米管负载PtRu纳米粒子的微波快速合成及其对甲醇的电化学氧化

陈卫祥^1,2, 赵杰¹, LEE Jim-Yang^2,3,4, 刘昭林⁴

1. 浙江大学化学系, 杭州, 310027;
2. 新加坡国立大学新加坡-麻省理工学院联合体, 新加坡, 117576;
3. 新加坡国立大学化学与环境工程系, 新加坡, 119260;
4. 新加坡材料研究与工程所, 新加坡, 117602

投稿日期:2003-12-12 修回日期:2004-03-29 发布日期:2014-02-17
通讯作者: weixiangchen@css.zju.edu.cn
作者简介:陈卫祥E-mail:weixiangchen@css.zju.edu.cn
基金资助:
国家自然科学基金(Nos.50171063,20003009)、浙江省自然科学基金(No.200053)和MEBCSProgrammeofSingapore-MITAlliance资助项目.

Rapid Synthesis of XC-72 and Carbon Nanotubes Supported PtRu Nanoparticles by Microwave Irradiation for Methanol Electrooxidation Application

CHEN Wei-Xiang^1,2, ZHAO Jie¹, LEE Jim-Yang^2,3,4, LIU Zhao-Lin⁴

1. Department of Chemistry, Zhejiang University, Hangzhou 310027, China;
2. Singapore-MIT Alliance, National University of Singapore, Singapore 117576, Singapore;
3. Department of Chemical and Environmental Engineering, National University of Singapore, Singapore 119260, Singapore;
4. Institute of Materials Research and Engineering, Research Link, Singapore 117602, Singapore

Received:2003-12-12 Revised:2004-03-29 Published:2014-02-17

Abstract

XC-72 carbon and carbon nanotubes (CNTs) supported PtRu alloy nanoparticles with Pt:Ru of 1:1 were rapidly prepared by microwave assisted heating polyol process.The PtRu loading was 20%.TEM observations showed that the microwave-synthesized PtRu nanoparticles had very small diameters and a sharp particle size distribution.These nanoparticles were highly dispersed on the surface of XC-72 carbon and CNTs with average diameter of 3.30 nm and 2.81 nm, respectively.Electrochemical measurements showed that the microwave-prepared PtRu/XC-72 and PtRu/CNTs nanocatalysts exhibited higher electrocatalytic activity for methanol oxidation at room temperature than PtRu/XC-72 catalyst prepared using KBH₄ as the reducing agent by wet chemical method.

Key words: microwave synthesis, PtRu alloy nanoparticle, XC-72 carbon, carbon nanotube, methanol electrooxidation

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CHEN Wei-Xiang, ZHAO Jie, LEE Jim-Yang, LIU Zhao-Lin. Rapid Synthesis of XC-72 and Carbon Nanotubes Supported PtRu Nanoparticles by Microwave Irradiation for Methanol Electrooxidation Application[J]. Acta Chimica Sinica, 2004, 62(17): 1590-1594.

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XC-72碳和碳纳米管负载PtRu纳米粒子的微波快速合成及其对甲醇的电化学氧化

Rapid Synthesis of XC-72 and Carbon Nanotubes Supported PtRu Nanoparticles by Microwave Irradiation for Methanol Electrooxidation Application

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