Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (19): 1901-1906. Previous Articles     Next Articles

三(2,4-戊二酮)合铱(Ⅲ)的热分解行为

闫革新1, 刘伟平1, 高文桂1, 胡昌义2, 余巍1, 梁广1   

  1. 1. 昆明贵金属研究所, 昆明, 650221;
    2. 贵研铂业股份有限公司, 昆明, 650221
  • 投稿日期:2003-11-10 修回日期:2004-05-25 发布日期:2014-02-17
  • 通讯作者: 刘伟平,E-mail:yaninno_cn@sina.com E-mail:yaninno_cn@sina.com
  • 基金资助:
    2002年云南省科技厅科研课题预研基金、2003年云南省科研院所专项基金(No.2003KFZX-15)资助项目.

Thermal Decomposition Behavior of Tris(2,4-pentanedionato-O, O') Iridium(Ⅲ)

YAN Ge-Xin1, LIU Wei-Ping1, GAO Wen-Gui1, HU Chang-Yi2, YU Wei1, LIANG Guang1   

  1. 1. Kunming Institute of Precious Metals, Kunming 650221;
    2. Sino-Platinum Metals Company, Ltd., Kunming 650221
  • Received:2003-11-10 Revised:2004-05-25 Published:2014-02-17

The thermal decomposition behavior of tris(2,4-pentanedionato-O,O') iridium(III) (1) has been studied with TG-DTA and GC-MS. The results show that compound 1 combusts, decomposes, sublimates and loses weight simultaneously at 258℃ in oxygen, and the heat emitting from the combustion is far greater than that absorbed by sublimation. Compound 1 decomposes, producing Ir, 2,4-pentanedione, carbon dioxide and 3-acetyl-2,5-dimethyl furan etc. in oxygen. Compound 1 absorbs a great deal of heat to sublimate and loses weight sharply from 239℃ in inert argon. Compound 1 can not combust with the increase of temperature in argon but sublimation is accelerated. When heated above 300℃, compound 1 decomposes, forming Ir, 2,4-pentanedione, 3-butene-2-one and 2,5-dimethyl furan etc. in argon. When compound 1 decomposed in oxygen, fewer kind of thermolytic products can be obtained. However, CVD experiments indicate that better Ir coatings on Re base can be prepared by adopting an inert gas with the addition of oxygen in appropriate amount (e.g. Ar flow of 50 mL·min-1, O2 flow of 1 mL·min-1) as carrier gas flow, for oxygen can prevent carbon from co-depositing with Ir on base. The forming mechanisms of thermolytic products were also proposed on the basis of the recombination of free radicals and oxidation of the organic ligands.

Key words: tris(2,4-pentanedionato-O,O)iridium(Ⅲ), thermal decomposition behavior, chemical vapor deposition, free-radical reaction