Synthesis, Structure and Fluorescence of {[NaCu(BTC)(H2O)4]·2H2O}n, a Double-sheet Coordination Polymer with 2D Network

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (23): 2323-2328. Previous Articles Next Articles

具双层结构的二维配位聚合物{[NaCu(BTC)(H₂O)₄]·2H₂O}_n的合成、结构及荧光性质

陈建新^1,2, 刘世雄¹

1. 福州大学中心实验室, 福州, 350002;福建师范大学化学与材料学院, 福州, 350007;
2. 福州大学中心实验室, 福州, 350002

投稿日期:2004-04-05 修回日期:2004-08-05 发布日期:2014-02-17
通讯作者: 刘世雄,E-mail:sxliu@fzu.edu.cn E-mail:sxliu@fzu.edu.cn
基金资助:
国家自然科学基金(No.20171012)和福建省自然科学基金(No.E0110010)资助项目.

Synthesis, Structure and Fluorescence of {[NaCu(BTC)(H₂O)₄]·2H₂O}_n, a Double-sheet Coordination Polymer with 2D Network

CHEN Jian-Xin^1,2, LIU Shi-Xiong¹

1. Central Laboratory, Fuzhou University, Fuzhou 350002;
2. College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007

Received:2004-04-05 Revised:2004-08-05 Published:2014-02-17

Abstract

The title complex {[NaCu(BTC)(H₂O)₄]·2H₂O}_n (H₃-BTC=1,3,5-benzenetricarboxylic acid) has been synthesized by the reaction of Cu(acac)₂ (acac=acetylacetone) and Na₃BTC in the mixed solvent of methanol and water.The compound was characterized by single-crystal X-ray diffraction analysis, infrared spectrum, fluorescent spectrum and TGA.The crystal structure is of monoclinic, space group C2/c with a=2.1657(1) nm, b= 1.12155(5) nm, c=1.35291(7) nm, β=122.379(1)°, V=2.7752(2) nm³, M_r=401.74, D_c= 1.923 Mg·m^-3, Z=8, μ(MoKα)=1.672 mm^-1, F(000)=1640, GOF=1.014.A total of 13298 reflections were collected of which 3339 were unique.The structure was refined to R=0.0276 and wR=0.0766 for 3176 observed reflections with I2σ(I).The crystal structure forms two-dimensional double-sheet network by the extension of copper(Ⅱ )/sodium(I) trimesate and bridging aqua ligands.There is an obvious interaction between metal ions Cu(Ⅱ ) and Na(I) in the compound, which gives an infinite one-dimensional quasi-metal string complex.Moreover, the complex gives a strong fluorescent emission band at 420 nm (λ_ex=314 nm) in the solid state at room temperature.

Key words: coordination polymer, 1,3,5-benzenetricarboxylic acid, copper complex, fluorescent spectrum, quasimetal string

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CHEN Jian-Xin, LIU Shi-Xiong. Synthesis, Structure and Fluorescence of {[NaCu(BTC)(H₂O)₄]·2H₂O}_n, a Double-sheet Coordination Polymer with 2D Network[J]. Acta Chimica Sinica, 2004, 62(23): 2323-2328.

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[1] Liang, Y.-C.; Cao, R.; Su, W.-P.; Hong, M.-C. Angew. Chem., Int. Ed. 2000, 39, 3304.
[2] Chen, B.; Eddaoudi, M.; Hyde, S.-T. Science 2001, 291, 1021.
[3] Li, X.-Y.; Guo, H.-Y.; Wang, R.-J.; Huang, M.-Z. Acta Chim. Sinica 2002, 60, 964 (in Chinese).(李秀艳, 郭洪猷, 王如骥, 黄明智, 化学学报, 2002, 60, 964.)
[4] Fang, Q.-R.; Shi, X.; Wu, G.; Tian, G.; Zhu, G.-S.; Li, Y.-F.; Wang, L.-F.; Wang, C.-L.; Chen, Y.; Zhang, Z.-D.; Guo, Z.; Shang, T.-C.; Cai, X.-H.; Qiu, S.-L. Acta Chim. Sinica 2002, 60, 2087 (in Chinese).(方千荣, 石鑫, 吴刚, 田歌, 朱广山, 李亚峰, 王立锋, 王春雷, 陈悦, 张震东, 郭卓, 商铁存, 蔡晓慧, 裘式纶, 化学学报, 2002, 60, 2087.)
[5] Fujita, M.; Kwon, Y.-J.; Ashizu, S.-W. J. Am. Chem. Soc. 1994, 116, 1151.
[6] Fujita, M.; Ogura, K. Bull. Chem. Soc. Jpn. 1996, 69, 1471.
[7] Fujita, M.; Kwon, Y.-J.; Sasaki, Y.-O. J. Am. Chem. Soc. 1995, 117, 7287.
[8] Carlucci, L.; Cani, G.; Proserpio, D. M. J. Chem. Soc., Chem. Commun. 1994, 2755.
[9] MacGillivray, L.-R.; Subramanian, S.; Zaworotko, M.-J. J. Chem. Soc., Chem. Commun. 1994, 1325.
[10] Gable, R.-W.; Hoskins, B.-F.; Robson, R. J. Chem. Soc., Chem. Commun. 1990, 1677.
[11] Yaghi, O.-M.; Li, H.; Groy, T.-L. J. Am. Chem. Soc. 1996, 118, 9096.
[12] Yaghi, O.-M.; Davis, C.-E.; Li, G. J. Am. Chem. Soc. 1997, 119, 2861.
[13] Eddaoudi, M.; Moler, D.-B.; Li, H.-L. Acc. Chem. Res. 2001, 34, 319.
[14] Kim, J.; Chen, B.; Reineke, T.-M. J. Am. Chem. Soc. 2001, 123, 8239.
[15] Eddaoudi, M.; Kim, J.; Rosi, N. Science 2002, 295, 469.
[16] Plater, M.-J.; Foreman, M.-R.-S.-J.; Coronado, E. J. Chem. Soc., Dalton Trans. 1999, 4209.
[17] Plater, M.-J.; Foreman, M.-R.-S.-J.; Howie, R.-A. Inorg. Chim. Acta 2001, 319, 159.
[18] Wang, L.; Shi, Z.; Li, G.-H.; Fan, Y.; Fu, W.-S.; Feng, S.-H. Solid State Sci. 2004, 85.
[19] Lu, Z.-L.; Chen, W.; Xu, J.-Q.; Zhang, L.-J.; Pan, C.-L.; Wang, T.-G. Inorg. Chem. Commun. 2003, 244.
[20] Chen, J.-X.; Liu, S.-X.; Gao, E.-Q. Polyhedron 2004, 23, 1877.
[21] Fang, Q.-R.; Zhu, G.-S.; Xin, M.-H.; Zhang, D.-L.; Shi, X.; Wu, G.; Tian, G.; Tang, L.-L.; Xie, M.; Qiu, S.-L. Chem. J. Chin. Univ. 2004, 25, 1016 (in Chinese).(方千荣, 朱广山, 辛明红, 张大梁, 石鑫, 吴刚, 田歌, 唐璐璐, 薛铭, 裘式纶, 高等学校化学学报, 2004, 25, 1016.)
[22] Zhu, H.-F.; Sun, W.-Y.; Okamura, T.; Ueyama, N. Inorg. Chem. Commun. 2003, 168.
[23] Lai, S.-Y.; Lin, T.-W.; Chen, Y.-H.; Wang, C.-C.; Lee, G.-H.; Yang, M.-H.; Leung, M.-K.; Peng, S.-M. J. Am. Chem. Soc. 1999, 121, 250.
[24] Sheldrick, G.-M. SHELXS-97, Program for X-ray Crystal Structure Solution, University of Gttingen, Gttingen, Germany, 1997.
[25] Sheldrick, G.-M. SHELXL-97, Program for X-ray Crystal Structure Refinement, University of Gttingen, Gttingen, Germany, 1997.
[26] Bellamy, L.-J. The Infrared Spectra of Complex Molecules, Wiley, New York, 1958.
[27] Zhang, H.-H.; Zheng, W. Spectroscopy, Xiamen University Press, Xiamen, 1998 (in Chinese).(张汉辉, 郑威, 波谱学, 厦门出版社, 厦门1998.)

具双层结构的二维配位聚合物{[NaCu(BTC)(H₂O)₄]·2H₂O}_n的合成、结构及荧光性质

Synthesis, Structure and Fluorescence of {[NaCu(BTC)(H₂O)₄]·2H₂O}_n, a Double-sheet Coordination Polymer with 2D Network

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具双层结构的二维配位聚合物{[NaCu(BTC)(H2O)4]·2H2O}n的合成、结构及荧光性质