Synthesis and Nonlinear Optical Properties of a New Two-photon Photopolymerization Initiator EPVPVC

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (23): 2343-2347. Previous Articles Next Articles

双光子吸收聚合引发剂EPVPVC的合成和非线性光学性质的研究

延云兴¹, 陶绪堂¹, 孙元红², 许贵宝¹, 王传奎², 杨家祥¹, 于晓强¹, 吴拥中¹, 赵显¹, 蒋民华¹

1. 山东大学晶体材料国家重点实验室, 济南, 250100;
2. 山东师范大学物理系, 济南, 250014

投稿日期:2004-03-16 修回日期:2004-06-23 发布日期:2014-02-17
通讯作者: 延云兴,E-mail:yxyan@icm.sdu.edu.cn E-mail:yxyan@icm.sdu.edu.cn
基金资助:
国家自然科学基金(Nos.50323006,50325311,10274044)资助项目.

Synthesis and Nonlinear Optical Properties of a New Two-photon Photopolymerization Initiator EPVPVC

YAN Yun-Xing¹, TAO Xu-Tang¹, SUN Yuan-Hong², XU Gui-Bao¹, WANG Chuan-Kui², YANG Jia-Xiang¹, YU Xiao-Qiang¹, WU Yong-Zhong¹, ZHAO Xian¹, JIANG Min-Hua¹

1. State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100;
2. Department of Physics, Shandong Normal University, Jinan 250014

Received:2004-03-16 Revised:2004-06-23 Published:2014-02-17

Abstract

A new two-photon free-radical photopolymerization initiator 9-ethyl-3-｛2-[4-(2-pyrid-4-yl)-vinylphenyl]-vinyl-carbazole (abbrev.EPVPVC) has been synthesized and structurally characterized by ¹H NMR spectra, ¹³C NMR spectra and elemental analyses.Linear absorption, one-photon induced fluorescence, one-photon fluorescence lifetime, one-photon fluorescence quantum yield and two-photon induced fluorescence were experimentally studied.The calculated two-photon absorption cross-section is as high as 56.6×10^-50 cm⁴·s·photon^-1.When pumped with 780 nm laser irradiation, EPVPVC exhibits strong two-photon induced fluorescence of 536 nm.A microstructure using EPVPVC as initiator has been fabricated under irradiation of 200 fs, 76 MHz Ti: sapphire femtosecond laser at 780 nm.The possible mechanism of photopolymerization was discussed based on quantum chemistry calculations.

Key words: synthesis, two-photon absorption, nonlinear optical, two-photon photopolymerization

Cite this article

YAN Yun-Xing, TAO Xu-Tang, SUN Yuan-Hong, XU Gui-Bao, WANG Chuan-Kui, YANG Jia-Xiang, YU Xiao-Qiang, WU Yong-Zhong, ZHAO Xian, JIANG Min-Hua. Synthesis and Nonlinear Optical Properties of a New Two-photon Photopolymerization Initiator EPVPVC[J]. Acta Chimica Sinica, 2004, 62(23): 2343-2347.

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双光子吸收聚合引发剂EPVPVC的合成和非线性光学性质的研究

Synthesis and Nonlinear Optical Properties of a New Two-photon Photopolymerization Initiator EPVPVC

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