Reductive Carboxylation of Unsaturated Hydrocarbons with Carbon Dioxide

doi:10.6023/A15090631

Acta Chim. Sinica ›› 2016, Vol. 74 ›› Issue (1): 17-23.DOI: 10.6023/A15090631 Previous Articles Next Articles

Special Issue: 纪念南开大学化学学科创建100周年

Perspective

二氧化碳与不饱和烃的还原羧化反应

张帅, 李雪冬, 何良年

元素有机化学国家重点实验室天津化学化工协同创新中心南开大学天津 300071

投稿日期:2015-09-26 发布日期:2015-11-13
通讯作者: 何良年 E-mail:heln@nankai.edu.cn
基金资助:
项目受国家自然科学基金(Nos. 21472103, 21421001)、教育部博士点基金(No. 20130031110013)和教育部创新团队(No. IRT13022)资助.

Reductive Carboxylation of Unsaturated Hydrocarbons with Carbon Dioxide

Zhang Shuai, Li Xuedong, He Liang-Nian

State Key Laboratory of Elemento-Organic Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071

Received:2015-09-26 Published:2015-11-13
Supported by:
Project supported by the National Natural Sciences Foundation of China (Nos. 21472103, 21421001), the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20130031110013), the MOE Innovation Team (No. IRT13022) of China.

Transition metal-catalyzed reductive carboxylation of unsaturated hydrocarbons with CO₂ is a promising and potential strategy, offering an excellent alternative access to carboxylic acids/acrylic acids. The active transition metal species could react with unsaturated hydrocarbons and CO₂ to generate the stable metallalactones or carboxylic salts. The transmetalation between reductants and metallalactones/carboxylic salts regenerates the active catalytic species. As a result, the reductive carboxylation is able to run in a catalytic mode rather than stoichiometric version. Organometal species, silanes/boranes, metal powder, methanol and hydrogens have been developed as reducing reagents in reductive carboxylation with CO₂. In this perspective, the latest advances on the transition metal-catalyzed reductive carboxylation are summarized, with particular focus on the application of reductants and related reaction mechanism at a molecular level.

Key words: reducing reagents, transition metal, unsaturated hydrocarbons, reductive carboxylation, carbon dioxide

Cite this article

Zhang Shuai, Li Xuedong, He Liang-Nian. Reductive Carboxylation of Unsaturated Hydrocarbons with Carbon Dioxide[J]. Acta Chim. Sinica, 2016, 74(1): 17-23.

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二氧化碳与不饱和烃的还原羧化反应

Reductive Carboxylation of Unsaturated Hydrocarbons with Carbon Dioxide

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