Acta Chim. Sinica ›› 2018, Vol. 76 ›› Issue (8): 585-596.DOI: 10.6023/A18040164 Previous Articles     Next Articles

Review

超高真空环境下有机分子表面化学反应的研究进展

郝振亮, 阮子林, 杨孝天, 蔡逸婷, 卢建臣, 蔡金明   

  1. 昆明理工大学 材料科学与工程学院 昆明 650000
  • 投稿日期:2018-04-21 发布日期:2018-07-12
  • 通讯作者: 卢建臣, 蔡金明 E-mail:lu.jianchen1989@gmail.com;j.cai@kmust.edu.cn
  • 作者简介:郝振亮,安徽亳州人,2015年于滨州学院材料化学专业获工学学士学位,现就读于昆明理工大学材料科学与工程学院,攻读博士学位.研究方向:利用超高真空扫描探针显微镜技术研究有机功能分子在表面上的化学反应及机理;卢建臣,男,1989年生,副教授,硕士生导师,云南省云岭青年人才.2011年吉林大学应用物理学系获理学学士学位,2017年中国科学院物理研究所获理学博士学位.2016年~2017年到德国马普学会弗里茨哈伯研究所访问学者.一直从事低维纳米材料和表面化学研究工作,在新型二维原子晶体材料的构筑、表征和电学性质的研究中取得了一系列的成果.;蔡金明,云南大理人,博士,教授,博士生导师,国家"千人计划"青年人才,云南省百名海外高层次人才,云南省中青年学术带头人预备人才,校"青蓝计划"人才.
  • 基金资助:

    项目受国家自然科学基金(Nos.11674136,11564022,51402138)、“千人计划”青年千人计划项目(No.1097816002)、云南省百名海外高层次人才(No.1097816002)、云南省中青年学术带头人预备人才(No.2017HB010)、昆明理工大学“青蓝计划”人才(No.1407840010)和昆明理工大学分析测试基金(No.2017P20163130004)资助.

Research Progress of On-surface Chemical Reaction for Organics in Ultra-High Vacuum

Hao Zhenliang, Ruan Zilin, Yang Xiaotian, Cai Yiting, Lu Jianchen, Cai Jinming   

  1. Kunming University of Science and Technology, Faculty of Materials Science and Engineering, Kunming 650000, China
  • Received:2018-04-21 Published:2018-07-12
  • Contact: 10.6023/A18040164 E-mail:lu.jianchen1989@gmail.com;j.cai@kmust.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 11674136, 11564022, 51402138), the Thousand Talents Plan-The Recruitment Program for Young Professionals (1097816002), Yunnan Province for Recruiting High-Caliber Technological Talents (No. 1097816002), reserve talents for Yunnan young and middle aged academic and technical leaders (No. 2017HB010), the Academic Qinglan project of KUST (No. 1407840010) and the Analysis and Testing Fund of KUST (No. 2017P20163130004).

On-surface chemical reactions under ultra-high vacuum play an important role in the synthesis of two-dimensional nanomaterials and have attracted more and more attention in recent years. In this review, we introduce several typical organic on-surface chemical reactions, including organic-metal coordinated reaction, dehalogenation reaction, condensation polymerization, alkyne coupling and so on. Reaction process and products are analyzed in detail by scanning tunneling microscope (STM), especially for the connection way of final products after reaction, such as organic metal coordination bonds, C-C bonds and H-bonds.

Key words: on-surface chemical reaction, STM, 2D nanostructure, coordinate bonds, covalent bonds, non-covalent bonds