Recent Advances of Two-dimensional Organic-Inorganic Hybrid Perovskite Ferroelectric Materials

doi:10.6023/A20080375

Acta Chimica Sinica ›› 2021, Vol. 79 ›› Issue (1): 23-35.DOI: 10.6023/A20080375 Previous Articles Next Articles

Review

二维有机-无机杂化钙钛矿铁电材料的研究进展

徐豪杰^a^,^b, 韩世国^a^,^b, 孙志华^a^,^*(), 罗军华^a

a 中国科学院福建物质结构研究所福州 350002)
(
b 中国科学院大学北京 101408

投稿日期:2020-08-18 发布日期:2020-10-20
通讯作者: 孙志华

作者简介:

徐豪杰, 本科毕业于湖北大学材料科学与工程学院, 获学士学位. 目前就读于中国科学院福建物质结构研究所, 主要从事新型铁电材料的探索与性能研究.

韩世国, 2018年毕业于青岛大学物理科学学院, 获硕士学位. 目前在中国科学院福建物质结构研究所攻读博士学位. 当前的研究兴趣为新型光铁电体材料与光电应用探索.

孙志华, 中国科学院福建物质结构研究所研究员, 博士生导师. 主要从事极性光电功能材料的结构设计、化学合成与性能表征, 研究兴趣包括光敏铁电体、铁电半导体及材料的光电性能耦合与调控等.

罗军华, 中国科学院福建物质结构研究所研究员, 博士生导师, 上海科技大学特聘教授, 国家杰出青年基金获得者. 当前的主要研究方向为非中心对称结构的光电功能材料.

* E-mail: sunzhihua@fjirsm.ac.cn

基金资助:
国家自然科学基金(Nos. 21875251); 国家自然科学基金(21833010); 国家自然科学基金(21525104); 国家自然科学基金(21971238); 国家自然科学基金(21975258); 国家自然科学基金(61975207); 国家自然科学基金(21921001); 中科院基础前沿项目(ZDBS-LY-SLH024); 福建省自然科学基金(2018H0047); 中科院先导项目(XDB20010200)

Recent Advances of Two-dimensional Organic-Inorganic Hybrid Perovskite Ferroelectric Materials

Haojie Xu^a^,^b, Shiguo Han^a^,^b, Zhihua Sun^a^,^*(), Junhua Luo^a

a Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China)
(
b University of Chinese Academy of Sciences, Beijing 101408, China

Received:2020-08-18 Published:2020-10-20
Contact: Zhihua Sun
Supported by:
the National Natural Science Foundation of China(Nos. 21875251); the National Natural Science Foundation of China(21833010); the National Natural Science Foundation of China(21525104); the National Natural Science Foundation of China(21971238); the National Natural Science Foundation of China(21975258); the National Natural Science Foundation of China(61975207); the National Natural Science Foundation of China(21921001); the Key Research Program of Frontier Sciences of the Chinese Academy of Sciences(ZDBS-LY-SLH024); the Natural Science Foundation of Fujian Province(2018H0047); the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20010200)

Ferroelectric materials, characterized by the reversible switching of spontaneous polarization by an applied electric field, exhibit excellent physical properties including dielectric response, pyroelectricity, piezoelectricity, electro-optics, and nonlinear optical effects, etc. All these physical properties have been widely used for diverse practical applications. In recent years, two-dimensional (2D) organic-inorganic hybrid perovskites have emerged as an important family of ferroelectrics. Benefitting from unique structural compatibility and tunability, this 2D class of ferroelectrics enable the coexistence and/or coupling of multiple functions, which become an ideal platform for the development of new multifunctional candidates. Based on the Curie symmetry principle, this work illuminates the crystallographic symmetry breaking and highlights the source of ferroelectricity in 2D hybrid perovskite ferroelectrics, as well as potential strategies to modulate their photoelectric properties. Finally, we propose the development trend and application prospects of these 2D hybrid perovskite ferroelectric materials.

Key words: ferroelectric, symmetry breaking, two-dimensional structure, hybrid perovskite, photoelectric property

Cite this article

Haojie Xu, Shiguo Han, Zhihua Sun, Junhua Luo. Recent Advances of Two-dimensional Organic-Inorganic Hybrid Perovskite Ferroelectric Materials[J]. Acta Chimica Sinica, 2021, 79(1): 23-35.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

Fig. & Tab. 17

References 58

[1]	Sun, Z.-H.; Yi, X.-F.; Tao, K.-W.; Ji, C.-M.; Liu, X.-T.; Li, L.-N.; Han, S.-G.; Zheng, A.; Hong, M.-C.; Luo, J.-H. Angew. Chem., Int. Ed. 2018, 57, 9833.
[2]	Pandey, R.; Vats, G.; Yun, J.; Bowen, C.R.; Ho-Baillie, A.W.Y.; Seidel, J.; Butler, K.T.; Seok, S.I. Adv. Mater. 2019, 31, 1807376.
[3]	Ji, C.-M.; Wang, S.-S.; Li, L.-N.; Sun, Z.-H.; Hong, M.-C.; Luo, J.-H. Adv. Funct. Mater. 2018, 29, 1805038.
[4]	Fu, D.-W.; Cai, H.-L.; Liu, Y.; Ye, Q.; Zhang, W.; Zhang, Y.; Chen, X.-Y.; Giovannetti, G.; Capone, M.; Li, J.; Xiong, R.-G. Science 2013, 339, 425.
[5]	Ye, H.-Y.; Tang, Y.-Y.; Li, P.-F.; Liao, W.-Q.; Gao, J.-X.; Hua, X.-N.; Cai, H.; Shi, P.-P.; You, Y.-M.; Xiong, R.-G. Science 2018, 361, 151.
[6]	Kundys, B.; Lappas, A.; Viret, M.; Kapustianyk, V.; Rudyk, V.; Semak, S.; Simon, C.; Bakaimi, I. Phys. Rev. B 2010, 81, 224434.
[7]	Ye, H.-Y.; Zhou, Q.; Niu, X.; Liao, W.-Q.; Fu, D.-W.; Zhang, Y.; You, Y.-M.; Wang, J.; Chen, Z.-N.; Xiong, R.-G. J. Am. Chem. Soc. 2015, 137, 13148.
[8]	Li, X.; Zhang, T.-Y.; Wang, T.; Zhao, Y.-X. Acta Chim. Sinica 2019, 77, 1075 . (in Chinese)
	李鑫, 张太阳, 王甜, 赵一新, 化学学报, 2019, 77, 1075.
[9]	Zhang, X.-Y.; Li, L.-N.; Sun, Z.-H.; Luo, J.-H. Chem. Soc. Rev. 2019, 48, 517.
[10]	Chen, X.-Y.; Xie, J.-J.; Wang, W.; Yuan, H.-H.; Xu, D.; Zhang, T.; He, Y.-L.; Shen, H.-J. Acta Chim. Sinica 2019, 77, 9 . (in Chinese)
	陈薪羽, 解俊杰, 王炜, 袁慧慧, 许頔, 张焘, 何云龙, 沈沪江, 化学学报, 2019, 77, 9.
[11]	Zhang, H.-Y.; Tang, Y.-Y.; Shi, P.-P.; Xiong, R.-G. Acc. Chem. Res. 2019, 52, 1928.
[12]	Hang, T.; Zhang, W.; Ye, H.-Y.; Xiong, R.-G. Chem. Soc. Rev. 2011, 40, 3577.
[13]	Aizu, K. Phys. Rev. B 1970, 2, 754.
[14]	Aizu, K. J. Phys. Soc. Jpn. 1969, 27, 387.
[15]	Feng, J.-G.; Gong, C.; Gao, H.-F.; Wen, W.; Gong, Y.-J.; Jiang, X.-Y.; Zhang, B.; Wu, Y.-C.; Wu, Y.-S.; Fu, H.-B.; Jiang, L.; Zhang, X. Nat. Electron. 2018, 1, 404.
[16]	Wangyang, P.-H.; Gong, C.-H.; Rao, G.-F.; Hu, K.; Wang, X.-P.; Yan, C.-Y.; Dai, L.-P.; Wu, C.-Y.; Xiong, J. Adv. Opt. Mater. 2018, 6 .
[17]	Miao, J.-L.; Zhang, F.-J. J. Mater. Chem. C 2019, 7, 1741.
[18]	Ahn, J.; Ma, S.; Kim, J.Y.; Kyhm, J.; Yang, W.; Lim, J.A.; Kotov, N.A.; Moon, J. J. Am. Chem. Soc. 2020, 142, 4206.
[19]	Xiao, J.; Zhang, H.-L. Acta Phys.-Chim. Sin. 2016, 32, 1894 . (in Chinese)
	肖娟, 张浩力, 物理化学学报, 2016, 32, 1894.
[20]	Xia, M.-L.; Yuan, J.-H.; Luo, J.-J.; Pan, W.-C.; Wu, H.-D.; Chen, Q.; Xue, K.-H.; Miao, X.-S.; Niu, G.-D.; Tang, J. J. Mater. Chem. C 2020, 8, 3814.
[21]	Mao, L.; Stoumpos, C.C.; Kanatzidis, M.G. J. Am. Chem. Soc. 2019, 141, 1171.
[22]	Saparov, B.; Mitzi, D.B. Chem. Rev. 2016, 116, 4558.
[23]	Even, J.; Pedesseau, L.; Katan, C. ChemPhysChem 2014, 15, 3733.
[24]	Shi, P.-P.; Tang, Y.-Y.; Li, P.-F.; Liao, W.-Q.; Wang, Z.-X.; Ye, Q.; Xiong, R.-G. Chem. Soc. Rev. 2016, 45, 3811.
[25]	Liao, W.-Q.; Zhang, Y.; Hu, C.-L.; Mao, J.-G.; Ye, H.-Y.; Li, P.-F.; Huang, S.D.; Xiong, R.-G. Nat. Commun. 2015, 6, 7338.
[26]	Shi, P.-P.; Lu, S.-Q.; Song, X.-J.; Chen, X.-G.; Liao, W.-Q.; Li, P.-F.; Tang, Y.-Y.; Xiong, R.-G. J. Am. Chem. Soc. 2019, 141, 18334.
[27]	Wei, W.-J.; Li, C.; Li, L.-S.; Tang, Y.-Z.; Jiang, X.-X.; Lin, Z.-S. J. Mater. Chem. C 2019, 7, 11964.
[28]	Ye, H.-Y.; Liao, W.-Q.; Hu, C.-L.; Zhang, Y.; You, Y.-M.; Mao, J.-G.; Li, P.-F.; Xiong, R.-G. Adv. Mater. 2016, 28, 2579.
[29]	Sun, Z.-H.; Liu, X.-T.; Khan, T.; Ji, C.-M.; Asghar, M.A.; Zhao, S.-G.; Li, L.-N.; Hong, M.-C.; Luo, J.-H. Angew. Chem., Int. Ed. 2016, 55, 6545.
[30]	Hu, J.; Yan, L.; You, W. Adv. Mater. 2018, 30, 1802041.
[31]	Yang, C.-K.; Chen, W.-N.; Ding, Y.-T.; Wang, J.; Rao, Y.; Liao, W.-Q.; Tang, Y.-Y.; Li, P.-F.; Wang, Z.-X.; Xiong, R.-G. Adv. Mater. 2019, 31, 1808088.
[32]	Li, L.-N.; Liu, X.-T.; Li, Y.-B.; Xu, Z.-Y.; Wu, Z.-Y.; Han, S.-G.; Tao, K.-W.; Hong, M.-C.; Luo, J.-H.; Sun, Z.-H. J. Am. Chem. Soc. 2019, 141, 2623.
[33]	Li, L.-N.; Shang, X.-Y.; Wang, S.-S.; Dong, N.-N.; Ji, C.-M.; Chen, X.-Y.; Zhao, S.-G.; Wang, J.; Sun, Z.-H.; Hong, M.-C.; Luo, J.-H. J. Am. Chem. Soc. 2018, 140, 6806.
[34]	Lin, J.; Lai, M.; Dou, L.; Kley, C.S.; Chen, H.; Peng, F.; Sun, J.; Lu, D.; Hawks, S.A.; Xie, C.; Cui, F.; Alivisatos, A.P.; Limmer, D.T.; Yang, P. Nat. Mater. 2018, 17, 261.
[35]	Wu, Z.-Y.; Ji, C.-M.; Li, L.-N.; Kong, J.-T.; Sun, Z.-H.; Zhao, S.-G.; Wang, S.-S.; Hong, M.-C.; Luo, J.-H. Angew. Chem., Int. Ed. 2018, 57, 8140.
[36]	Stoumpos, C.C.; Cao, D.H.; Clark, D.J.; Young, J.; Rondinelli, J.M.; Jang, J.I.; Hupp, J.T.; Kanatzidis, M.G. Chem. Mater. 2016, 28, 2852.
[37]	Li, L.-N.; Sun, Z.-H.; Wang, P.; Hu, W.-D.; Wang, S.-S.; Ji, C.-M.; Hong, M.-C.; Luo, J.-H. Angew. Chem., Int. Ed. 2017, 56, 12150.
[38]	Liu, X.-T.; Wang, S.-S.; Long, P.-Q.; Li, L.-N.; Peng, Y.; Xu, Z.-Y.; Han, S.-G.; Sun, Z.-H.; Hong, M.-C.; Luo, J.-H. Angew. Chem., Int. Ed. 2019, 58, 14504.
[39]	Spanopoulos, I.; Hadar, I.; Ke, W.; Tu, Q.; Chen, M.; Tsai, H.; He, Y.; Shekhawat, G.; Dravid, V.P.; Wasielewski, M.R.; Mohite, A.D.; Stoumpos, C.C.; Kanatzidis, M.G. J. Am. Chem. Soc. 2019, 141, 5518.
[40]	Kieslich, G.; Sun, S.; Cheetham, A.K. Chem. Sci. 2014, 5, 4712.
[41]	Wang, S.-S.; Liu, X.-T.; Li, L.-N.; Ji, C.-M.; Sun, Z.-H.; Wu, Z.-Y.; Hong, M.-C.; Luo, J.-H. J. Am. Chem. Soc. 2019, 141, 7693.
[42]	Han, S.-G.; Liu, X.-T.; Liu, Y.; Xu, Z.-Y.; Li, Y.-B.; Hong, M.-C.; Luo, J.-H.; Sun, Z.-H. J. Am. Chem. Soc. 2019, 141, 12470.
[43]	Gao, Y.; Wei, Z.-T.; Yoo, P.; Shi, E.; Zeller, M.; Zhu, C.-H.; Liao, P.-L.; Dou, L.-T. J. Am. Chem. Soc. 2019, 141, 15577.
[44]	Li, L.-N.; Liu, X.-T.; He, C.; Wang, S.-S.; Ji, C.-M.; Zhang, X.-Y.; Sun, Z.-H.; Zhao, S.-G.; Hong, M.-C.; Luo, J.-H. J. Am. Chem. Soc. 2020, 142, 1159.
[45]	Mao, L.-L.; Ke, W.-J.; Pedesseau, L.; Wu, Y.-L.; Katan, C.; Even, J.; Wasielewski, M.R.; Stoumpos, C.C.; Kanatzidis, M.G. J. Am. Chem. Soc. 2018, 140, 3775.
[46]	Connor, B.A.; Leppert, L.; Smith, M.D.; Neaton, J.B.; Karunadasa, H.I. J. Am. Chem. Soc. 2018, 140, 5235.
[47]	Park, I.-H.; Zhang, Q.; Kwon, K.C.; Zhu, Z.; Yu, W.; Leng, K.; Giovanni, D.; Choi, H.S.; Abdelwahab, I.; Xu, Q.-H.; Sum, T.C.; Loh, K.P. J. Am. Chem. Soc. 2019, 141, 15972.
[48]	Guo, W.-Q.; Liu, X.-T.; Han, S.-G.; Liu, Y.; Xu, Z.-Y.; Hong, M.-C.; Luo, J.-H.; Sun, Z.-H. Angew. Chem., Int. Ed. 2020, 59, 2.
[49]	Sha, T.-T.; Xiong, Y.-A.; Pan, Q.; Chen, X.-G.; Song, X.-J.; Yao, J.; Miao, S.-R.; Jing, Z.-Y.; Feng, Z.-J.; You, Y.-M.; Xiong, R.-G. Adv. Mater. 2019, 31, 1901843.
[50]	Chen, X.-G.; Song, X.-J.; Zhang, Z.-X.; Li, P.-F.; Ge, J.-Z.; Tang, Y.-Y.; Gao, J.-X.; Zhang, W.-Y.; Fu, D.-W.; You, Y.-M.; Xiong, R.-G. J. Am. Chem. Soc. 2020, 142, 1077.
[51]	Zhang, H.-Y.; Song, X.-J.; Chen, X.-G.; Zhang, Z.-X.; You, Y.-M.; Tang, Y.-Y.; Xiong, R.-G. J. Am. Chem. Soc. 2020, 142, 4925.
[52]	Chen, X.-G.; Song, X.-J.; Zhang, Z.-X.; Zhang, H.-Y.; Pan, Q.; Yao, J.; You, Y.-M.; Xiong, R.-G. J. Am. Chem. Soc. 2020, 142,10212.
[53]	Wu, Z.-Y.; Liu, X.-T.; Ji, C.-M.; Li, L.-N.; Wang, S.-S.; Peng, Y.; Tao, K.-W.; Sun, Z.-H.; Hong, M.-C.; Luo, J.-H. J. Am. Chem. Soc. 2019, 141, 3812.
[54]	Wang, S.-S.; Li, L.-N.; Weng, W.; Ji, C.-M.; Liu, X.-T.; Sun, Z.-H.; Lin, W.-X.; Hong, M.-C.; Luo, J.-H. J. Am. Chem. Soc. 2019, 142, 55.
[55]	Ji, C.-M.; Wang, S.-S.; Wang, Y.-X.; Chen, H.-X.; Li, L.-N.; Sun, Z.-H.; Sui, Y.; Wang, S.-S.; Luo, J.-H. Adv. Funct. Mater. 2019, 30 .
[56]	Peng, Y.; Liu, X.-T.; Sun, Z.-H.; Ji, C.-M.; Li, L.-N.; Wu, Z.-Y.; Wang, S.-S.; Yao, Y.-P.; Hong, M.-C.; Luo, J.-H. Angew. Chem., Int. Ed. 2020, 59, 3933.
[57]	Shi, C.; Ye, L.; Gong, Z.-X.; Ma, J.-J.; Wang, Q.-W.; Jiang, J.-Y.; Hua, M.-M.; Wang, C.-F.; Yu, H.; Zhang, Y.; Ye, H.-Y. J. Am. Chem. Soc. 2019, 142, 545.
[58]	Zhang, W.-C.; Hong, M.-C.; Luo, J.-H. Angew. Chem., Int. Ed. 2020, 59, 9305.

三斜晶系	F1 (1)
单斜晶系	2 F1 (2/2); mF1 (2/2); 2/ mF1 (2); 2/ mFm (1); 2/ mF2 (1)
正交晶系	222 F1 (4/2); 222 F2 (1); mm2 F1 (4/2); mm2 Fm (2/2); mmmF1 (4); mmmFm (2); mmmFmm2 (1)
四方晶系	4 F1 (4/2); F1 (4/2); F2 (1); 4/ mF1 (4); 4/ mFm (2); 4/ mF4 (1); 422 F1 (8/2); 422 F2( s) (2); 422 F4 (1); 4 mmF1 (8/2); 4 mmFm (4/2); 2 mF1 (8/2); 2 mF2( s) (2); 2 mFm (4/2); 2 mFmm2 (1); 4/ mmmF1 (8); 4/ mmmFm( s) (4); 4/ mmmFm( p) (4); 4/ mmmFmm2( s) (2); 4/ mmmF4 mm (1)
三方晶系	3 F1 (3/2); F1 (3); F3 (1); 32 F1 (6/2); 32 F2 (3/2); 32 F3 (1); 3 mF1 (6/2); 3 mFm (3/2); mF1 (6); mF2 (3); mFm (3); mF3 m (1)
六方晶系	6 F1 (6/2); F1 (6/2); Fm (3/2); F3 (1); 6/ mF1 (6); 6/ mFm (3); 6/ mF6 (1); 622 F1 (12/2); 622 F2( s) (3); 622 F6 (1); 6 mmF1 (12/2); 6 mmFm (6/2); m2 F1 (12/2); m2 Fm( s) (6/2); m2 Fm( p) (6/2); m2 Fmm2 (3/2); m2 F3 m (1); 6/ mmmF1 (12); 6/ mmmFm( s) (6); 6/ mmmFm( p) (6); 6/ mmmFmm2( s) (3); 6/ mmmF6 mm (1)
立方晶系	23 F1 (12/2); 23 F2 (3); 23 F3 (4/2); mF1 (12); mFm (6); mFmm2 (3); mF3 (4); 432 F1 (24/2); 432 F2( s) (6); 432 F4 (3); 432 F3 (4); 3 mF1 (24/2); 3 mFm (12/2); 3 mFmm2 (3); 3 mF3 m (4/2); mmF1 (24); mmFm( s) (12); mmFm( p) (12); mmFmm2 (6); mmF4 mm (3); mmF3 m (4)

三斜晶系	F1 (1)
单斜晶系	2 F1 (2/2); mF1 (2/2); 2/ mF1 (2); 2/ mFm (1); 2/ mF2 (1)
正交晶系	222 F1 (4/2); 222 F2 (1); mm2 F1 (4/2); mm2 Fm (2/2); mmmF1 (4); mmmFm (2); mmmFmm2 (1)
四方晶系	4 F1 (4/2); F1 (4/2); F2 (1); 4/ mF1 (4); 4/ mFm (2); 4/ mF4 (1); 422 F1 (8/2); 422 F2( s) (2); 422 F4 (1); 4 mmF1 (8/2); 4 mmFm (4/2); 2 mF1 (8/2); 2 mF2( s) (2); 2 mFm (4/2); 2 mFmm2 (1); 4/ mmmF1 (8); 4/ mmmFm( s) (4); 4/ mmmFm( p) (4); 4/ mmmFmm2( s) (2); 4/ mmmF4 mm (1)
三方晶系	3 F1 (3/2); F1 (3); F3 (1); 32 F1 (6/2); 32 F2 (3/2); 32 F3 (1); 3 mF1 (6/2); 3 mFm (3/2); mF1 (6); mF2 (3); mFm (3); mF3 m (1)
六方晶系	6 F1 (6/2); F1 (6/2); Fm (3/2); F3 (1); 6/ mF1 (6); 6/ mFm (3); 6/ mF6 (1); 622 F1 (12/2); 622 F2( s) (3); 622 F6 (1); 6 mmF1 (12/2); 6 mmFm (6/2); m2 F1 (12/2); m2 Fm( s) (6/2); m2 Fm( p) (6/2); m2 Fmm2 (3/2); m2 F3 m (1); 6/ mmmF1 (12); 6/ mmmFm( s) (6); 6/ mmmFm( p) (6); 6/ mmmFmm2( s) (3); 6/ mmmF6 mm (1)
立方晶系	23 F1 (12/2); 23 F2 (3); 23 F3 (4/2); mF1 (12); mFm (6); mFmm2 (3); mF3 (4); 432 F1 (24/2); 432 F2( s) (6); 432 F4 (3); 432 F3 (4); 3 mF1 (24/2); 3 mFm (12/2); 3 mFmm2 (3); 3 mF3 m (4/2); mmF1 (24); mmFm( s) (12); mmFm( p) (12); mmFmm2 (6); mmF4 mm (3); mmF3 m (4)

分类	材料组分		铁电相变类型	P _s/ (μC•cm ^–2)	E _g/eV	Ref.
A' ₂ MX ₄	(benzylammonium) ₂PbCl ₄	438	mmmFmm2	13	3.65	[25]
	(cyclohexylaminium) ₂ PbBr ₄	364	mmmFmm2	6.8	2.95	[28, 29]
	( n-butylammonium) ₂PbCl ₄	328	mmmFmm2	2.1		[3]
	[2-fluorobenzylammonium] ₂PbCl ₄	448	4/ mmmFmm2	5.35	3.62	[26]
	[ R-1-(4-chlorophenyl)ethylammonium] ₂PbI ₄ [ S-1-(4-chlorophenyl)ethylammonium] ₂PbI ₄	487 473.2	422 F1		2.34	[31]
	(4,4-difluorocyclohexylammonium) ₂PbI ₄	377	mmmFmm2	ca.4.5	2.38	[49]
	(4-aminotetrahydropyran) ₂PbBr ₄	503		5.36	3.12	[50]
	(4,4-difluoropiperidinium) ₂PbI ₄	428.5	4/ mmmFmm2	10.0	2.24	[51]
	(4,4-difluorohexahydroazepine) ₂PbI ₄	454	4?2 mF2	1.1	2.32	[52]
A' ₂ AM ₂ X ₇	( n-butylammonium) ₂CsPb ₂Br ₇	412	mmmFmm2	4.2	2.7	[35]
	( n-butylammonium) ₂(formamidinium)Pb ₂Br ₇	322	mmmFmm2	3.8	2.35	[33]
	( n-butylammonium) ₂(methylammonium)Pb ₂Br ₇	352	mmmFmm2	3.6	2.55	[32]
	(isobutylammonium) ₂CsPb ₂Br ₇	353	反铁电	ca.6.3		[53]
A' ₂ A ₂ M ₃ X ₁₀	( n-butylammonium) ₂(methylammonium) ₂Pb ₃Br ₁₀	315	mmmFmm2	2.9	2.41	[37]
	(ethylammonium) ₂(methylammonium) ₂Pb ₃Br ₁₀	375	4/ mmmFmm2	3.7	2.7	[38]
	(ethylammonium) ₄Pb ₃Cl ₁₀	415	4/ mmmFmm2	4.5	3.39	[54]
	( n-butylammonium ) ₂EA ₂Pb ₃Br ₁₀	380	4/ mmmFmm2	5	2.55	[55]
	(ethylammonium) ₄Pb ₃Br ₁₀	384	4/ mmmFmm2	3.5/5.9	2.7	[41]
	( n-butylammonium) ₂(ethylammonium) ₂Pb ₃I ₁₀	363	4/ mmmFmm2	5.6	1.9	[42]
	(allyammonium) ₂(ethylammonium) ₂Pb ₃Br ₁₀	378	4/ mmmFmm2		2.71	[56]
	( n-butylammonium) ₂(methylammonium) ₂Sn ₃Br ₁₀	318	mmmFmm2		2.22	[44]
其他	(4-(aminomethyl)piperidinium)PbI ₄	352	2/ mFm	9.8	2.38	[47]
	( R/ S-3-hydroxylquinuclidinium) ₄KCe(NO ₃) ₈	320	222 F2	4.1		[57]
	( n-propylammonium) ₂CsAgBiBr ₇	222	2/ mF2	1.5	2.25	[58]
	(chloropropylammonium) ₄AgBiBr ₈	305	mmmFm	3.2	2.69	[48]

分类	材料组分		铁电相变类型	P _s/ (μC•cm ^–2)	E _g/eV	Ref.
A' ₂ MX ₄	(benzylammonium) ₂PbCl ₄	438	mmmFmm2	13	3.65	[25]
	(cyclohexylaminium) ₂ PbBr ₄	364	mmmFmm2	6.8	2.95	[28, 29]
	( n-butylammonium) ₂PbCl ₄	328	mmmFmm2	2.1		[3]
	[2-fluorobenzylammonium] ₂PbCl ₄	448	4/ mmmFmm2	5.35	3.62	[26]
	[ R-1-(4-chlorophenyl)ethylammonium] ₂PbI ₄ [ S-1-(4-chlorophenyl)ethylammonium] ₂PbI ₄	487 473.2	422 F1		2.34	[31]
	(4,4-difluorocyclohexylammonium) ₂PbI ₄	377	mmmFmm2	ca.4.5	2.38	[49]
	(4-aminotetrahydropyran) ₂PbBr ₄	503		5.36	3.12	[50]
	(4,4-difluoropiperidinium) ₂PbI ₄	428.5	4/ mmmFmm2	10.0	2.24	[51]
	(4,4-difluorohexahydroazepine) ₂PbI ₄	454	4?2 mF2	1.1	2.32	[52]
A' ₂ AM ₂ X ₇	( n-butylammonium) ₂CsPb ₂Br ₇	412	mmmFmm2	4.2	2.7	[35]
	( n-butylammonium) ₂(formamidinium)Pb ₂Br ₇	322	mmmFmm2	3.8	2.35	[33]
	( n-butylammonium) ₂(methylammonium)Pb ₂Br ₇	352	mmmFmm2	3.6	2.55	[32]
	(isobutylammonium) ₂CsPb ₂Br ₇	353	反铁电	ca.6.3		[53]
A' ₂ A ₂ M ₃ X ₁₀	( n-butylammonium) ₂(methylammonium) ₂Pb ₃Br ₁₀	315	mmmFmm2	2.9	2.41	[37]
	(ethylammonium) ₂(methylammonium) ₂Pb ₃Br ₁₀	375	4/ mmmFmm2	3.7	2.7	[38]
	(ethylammonium) ₄Pb ₃Cl ₁₀	415	4/ mmmFmm2	4.5	3.39	[54]
	( n-butylammonium ) ₂EA ₂Pb ₃Br ₁₀	380	4/ mmmFmm2	5	2.55	[55]
	(ethylammonium) ₄Pb ₃Br ₁₀	384	4/ mmmFmm2	3.5/5.9	2.7	[41]
	( n-butylammonium) ₂(ethylammonium) ₂Pb ₃I ₁₀	363	4/ mmmFmm2	5.6	1.9	[42]
	(allyammonium) ₂(ethylammonium) ₂Pb ₃Br ₁₀	378	4/ mmmFmm2		2.71	[56]
	( n-butylammonium) ₂(methylammonium) ₂Sn ₃Br ₁₀	318	mmmFmm2		2.22	[44]
其他	(4-(aminomethyl)piperidinium)PbI ₄	352	2/ mFm	9.8	2.38	[47]
	( R/ S-3-hydroxylquinuclidinium) ₄KCe(NO ₃) ₈	320	222 F2	4.1		[57]
	( n-propylammonium) ₂CsAgBiBr ₇	222	2/ mF2	1.5	2.25	[58]
	(chloropropylammonium) ₄AgBiBr ₈	305	mmmFm	3.2	2.69	[48]

二维有机-无机杂化钙钛矿铁电材料的研究进展

Recent Advances of Two-dimensional Organic-Inorganic Hybrid Perovskite Ferroelectric Materials

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 17

References 58

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Fen Zhang, Xiaoqi Li, Shiguo Han, Fafa Wu, Xitao Liu, Zhihua Sun, Junhua Luo. Bulk Single Crystal Growth of a Two-Dimensional Halide Perovskite Ferroelectric for Highly Polarized-Sensitive Photodetection^※ [J]. Acta Chimica Sinica, 2022, 80(3): 237-243.
[2]	Yumiao Lu, Wei Chen, Yanlei Wang, Feng Huo, Yihui Dong, Li Wei, Hongyan He. Research Progress on the Preparation and Properties of Two Dimensional Structure of Ionic Liquids [J]. Acta Chimica Sinica, 2021, 79(4): 443-458.
[3]	Zhang Hao, Huang Long, Li Tao, Liu Bin, Bai Zeming, Li Xiaona, Lu Dan. Quantitative Structure-property Relationship of Polyfluorene Conjugated Polymers Condensed State from Solution to Film [J]. Acta Chim. Sinica, 2019, 77(5): 397-405.
[4]	Kong Xiangkai, Chen Qianwang. Experimental and Theoretical Investigations on the Ferroelectricity of Graphene Oxides [J]. Acta Chimica Sinica, 2013, 71(03): 381-386.
[5]	ZOU Xu, FAN Ya, ZHUANG Min-Yang, PENG Jing, GAO Li-Hua, WANG Ke-Zhi. Three Electrostatically Self-assembled Multilayer Films Prepared from Bipolar Hemicyanines and WO₃ Colloidal Particles [J]. Acta Chimica Sinica, 2010, 68(21): 2250-2252.
[6]	LIN Li-Rong, HU Wang-Xia, MA Jie, ZHANG Hui, HUANG Rong-Ban, ZHENG Lan-Sun. Spontaneous Chiral Symmetry Breaking of (Thio)semicarbazide Compounds [J]. Acta Chimica Sinica, 2010, 68(07): 703-706.
[7]	BO Ru-Xiu, TONG Bin, QI Dun-Ge, DIAO Wei, SHEN Jin-Bei, DAN Jian-Bing, DONG Yu-Beng. Full-conjugated Layer-by-Layer self-assembly Ultrathin Functional Films Fabricted from Terpyridine and Transition Metal Ions based on Coordinate Interaction [J]. Acta Chimica Sinica, 2009, 67(24): 2779-2784.
[8]	FU Yao; CAO Wang-He*; TIAN Ying. Study on Transport Properties of Photo-generated Carriers in Nanocrystalline TiO₂ Film Electrode [J]. Acta Chimica Sinica, 2006, 64(17): 1761-1764.
[9]	XIAO Zheng-Quan^1,3, MIAO Qiang^,1, LUO Hao-Su². Ab initio* Molecular Dynamics Study on Polarization Property of Selected Perovskite Structure Crystals [J]. Acta Chimica Sinica, 2006, 64(12): 1209-1212.
[10]	XIE Ying^{1, 2}, QIANG Liang-Sheng, ZHONG Hua^1,2, YU Hai-Tao²,FU Hong-Gang*^,1,2. A DFT Investigation of Vibrational Nature and Ferroelectric Phase Transition of BaTiO₃ and PbTiO₃ [J]. Acta Chimica Sinica, 2005, 63(6): 455-459.
[11]	ZHANG Dong-Jie*, YAO Xi². Structural Fluctuation and Relaxation of Perovskite Relaxor Ferroelectrics [J]. Acta Chimica Sinica, 2005, 63(12): 1095-1099.
[12]	Wang Yuanxu;Zhao Minglei;Wang Chunlei. First Principles Study on Electronic Structure of KTa_(0.5)Nb_(0.5) O_3 [J]. Acta Chimica Sinica, 2003, 61(9): 1500-1502.
[13]	Fang Bijun;LUO HAO ;Wu Yongjun;Xu Haiqing;Yin Zhiwen. Study on crystal growth and electrical properties of relaxor-based ferroelectric single crystal 0.91Pb(Zn1/3Nb2/3)O3-0.09PbTiO3 [J]. Acta Chimica Sinica, 2001, 59(9): 1430-1434.
[14]	Xu Guisheng;LUO HAO;Zhong Weizhao;Yin Zhiwen;Liu Ke. Growth units and growth mechanism of lead-based complex perovskite relaxor ferroelectric single crystals: I. The surface morphology, negative crystal structure and assembling or unlinking of growth units in PMNT crystals [J]. Acta Chimica Sinica, 2000, 58(2): 172-177.
[15]	Xu Guisheng;LUO HAO;Zhong Weizhao;Yin Zhiwen;Liu Ke. Growth units and growth mechanism of lead-based complex perovskite relaxor ferroelectric single crystals: II. Splitting and assembling of the same type of growth units related to the fluctuation in composition nad structure [J]. Acta Chimica Sinica, 2000, 58(2): 178-183.