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About the Cover:Carbolong chemistry represents the chemistry of metal bridgehead polycyclic frameworks featuring a long carbon chain (nC≥7) coordinated to a metal atom via at least three metal-carbon bonds. The facile and efficient one-pot reaction between multiyne chains and metal precursors enables the direct synthesis of osmium, ruthenium, and rhodium carbolong complexes. In this work, we develop this strategy to synthesize the iridium carbolong complexes for the first time. [Xia, Haiping et al. on page 71-80.]
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