Investigation on the Luminescent Property and Application of In2BP3O12:Cr3+ Broadband Near-Infrared Phosphor※

doi:10.6023/A21120598

Acta Chimica Sinica ›› 2022, Vol. 80 ›› Issue (4): 453-459.DOI: 10.6023/A21120598 Previous Articles Next Articles

Special Issue: 中国科学院青年创新促进会合辑

Article

In₂BP₃O₁₂:Cr³⁺宽带近红外荧光粉的发光性能及应用研究^※

张景荣^a^,^b^,^c, 黄得财^b^,^c^,^*(), 黄聪聪^b^,^c, 梁思思^b^,^c, 朱浩淼^a^,^b^,^c^,^d^,^*()

a 福建师范大学化学与材料学院福州 350003
b 中国科学院福建物质结构研究所中国科学院功能纳米结构设计与组装重点实验室福建省纳米材料重点实验室福州 350002
c 厦门稀土材料研究所厦门市稀土光电功能材料重点实验室厦门 361021
d 中国科学院赣江创新研究院赣州 341000

投稿日期:2021-12-30 发布日期:2022-04-28
通讯作者: 黄得财, 朱浩淼
作者简介:
^※ 庆祝中国科学院青年创新促进会十年华诞.
基金资助:
国家重点研发计划项目(2021YFB3500400); 国家自然科学基金(11904363); 以及中科院重点部署项目(ZDRW-CN-2021-3)

Investigation on the Luminescent Property and Application of In₂BP₃O₁₂:Cr³⁺ Broadband Near-Infrared Phosphor^※

Jingrong Zhang^a^,^b^,^c, Decai Huang^b^,^c(), Congcong Huang^b^,^c, Sisi Liang^b^,^c, Haomiao Zhu^a^,^b^,^c^,^d()

a College of Chemistry and Materials, Fujian Normal University, Fuzhou 350003, China
b CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on The Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Xiamen 361021, China
d Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341000, China

Received:2021-12-30 Published:2022-04-28
Contact: Decai Huang, Haomiao Zhu
About author:
^※ Dedicated to the 10th anniversary of the Youth Innovation Promotion Association, CAS.
Supported by:
National Key R&D Program of China(2021YFB3500400); National Natural Science Foundation of China(11904363); Key Research Program of the Chinese Academy of Sciences(ZDRW-CN-2021-3)

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Abstract

Near-infrared (NIR) spectroscopy technique plays an important role in night-vision surveillance, food analysis, bioimaging and agriculture fields, and the development of compact and efficient NIR light source is a precondition for their massive commercial applications. Phosphor-converted light emitting diodes (pc-LED) have the advantages of compactness, low-cost, and long operating lifetime, thus have attracted considerable attentions in recent years. The key point is to exploit high performance NIR phosphors which can be excited efficiently by blue diode chips. A number of Cr³⁺-activated phosphors have been investigated aiming at NIR pc-LED applications. Nevertheless, most of the NIR phosphors show relatively short peak wavelength and narrow full width at half maximum (FWHM), resulting in spectral deficiency in the range 900~1100 nm. The phosphors with ultrabroad bandwidth are more desirable for spectroscopic applications. In this work, a novel broadband NIR light emitting phosphor In₂BP₃O₁₂:Cr³⁺ is synthesized by solid state reaction method. The structure, concentration and temperature dependent luminescence properties, electron-phonon coupling as well as the NIR LED performances and applications of the In₂BP₃O₁₂:Cr³⁺ have been investigated. Upon 480 nm excitation, the In₂BP₃O₁₂:Cr³⁺ phosphor shows a broad emission band peaked at 950 nm and covering 750~1350 nm (bandwidth of ~210 nm), which is owing to the ⁴T₂ → ⁴A₂ transition of Cr³⁺ ions. It is found that the emission intensity of the phosphor at 373 K keep 40% of that at room temperature. A NIR pc-LED is packaged by combining the In₂BP₃O₁₂:Cr³⁺ phosphor and a commercial blue InGaN chip, which generates broad NIR light emissions with an output power of ~5 mW at 60 mA drive current. When this NIR pc-LED is used to illuminate the human palm, the blood vessels in the palm are clearly imaged by a NIR charge coupled device (CCD) camera. These results suggest that the In₂BP₃O₁₂:Cr³⁺ is a promising phosphor for fabricating NIR pc-LEDs, which are potential for non-destructive analysis in the fields of biology and medicine.

Key words: near infrared phosphor, In₂BP₃O₁₂, LEDs, luminescent materials, broadband emission

Cite this article

Jingrong Zhang, Decai Huang, Congcong Huang, Sisi Liang, Haomiao Zhu. Investigation on the Luminescent Property and Application of In₂BP₃O₁₂:Cr³⁺ Broadband Near-Infrared Phosphor^※[J]. Acta Chimica Sinica, 2022, 80(4): 453-459.

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Fig. & Tab. 4

Figure 1. (a) Crystal structure of In2BP3O12 crystal. (b) XRD patterns of In2BP3O12:xCr3+ (x=2%~12%) samples. (c) Rietveld refinement of the XRD pattern for In2BP3O12:10%Cr3+ sample. (d) Scanning electron microscope (SEM) and elemental mapping images of In2BP3O12:10%Cr3+ sample

Figure 2. (a) Diffuse reflection spectra of In2BP3O12:xCr3+ (x=0%~12%) samples. (b) Excitation and emission spectra of the In2BP3O12:10%Cr3+ sample. (c) Energy level diagram for Cr3+ (3d3) ions in an octahedral crystal field. (d) Emission spectra of In2BP3O12:xCr3+(x=2%~12%) samples. (e) Normalized emission spectra of In2BP3O12:xCr3+ (x=2%~12%) samples. (f) PL decay curves of In2BP3O12:xCr3+ (x=4%~12%) samples

Figure 3. (a) PL/temperature correlation map of the In2BP3O12:10%Cr3+ sample. (b) The integrated PL intensity of the In2BP3O12:10%Cr3+ as a function of temperature at 298~523 K. (c) PL decay curves of the In2BP3O12:10%Cr3+ sample at 298~473 K. (d) The linear relationship of In[(I0/IT)–1] versus 1/kT for the In2BP3O12:10%Cr3+ sample

Figure 4. (a) Electroluminescence spectra of the pc-LED fabricated with the In2BP3O12:10%Cr3+ phosphor and a blue diode chip (the inset is the photograph of the fabricated pc-LED). (b) Image of the palm under the illumination of the fabricated NIR pc-LED

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In₂BP₃O₁₂:Cr³⁺宽带近红外荧光粉的发光性能及应用研究^※

Investigation on the Luminescent Property and Application of In₂BP₃O₁₂:Cr³⁺ Broadband Near-Infrared Phosphor^※

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In2BP3O12:Cr3+宽带近红外荧光粉的发光性能及应用研究※