Acta Chimica Sinica ›› 2022, Vol. 80 ›› Issue (7): 970-992.DOI: 10.6023/A22030123 Previous Articles     Next Articles

Review

手性有机光电功能材料及其圆偏振光发射与探测

刘丽萱a,b, 杨扬a, 魏志祥a,b,*()   

  1. a 国家纳米科学中心 中国科学院纳米科学卓越中心 中国科学院纳米系统与多级次制造重点实验室 北京 100190
    b 中国科学院大学 未来技术学院 北京 100049
  • 投稿日期:2022-03-21 发布日期:2022-05-31
  • 通讯作者: 魏志祥
  • 作者简介:

    刘丽萱, 中国科学院国家纳米科学中心在读博士生. 2017年9月进入国家纳米中心物理化学专业攻读博士研究生, 师从魏志祥研究员. 主要从事手性有机半导体材料的合成及器件制备等研究.

    杨扬, 博士, 中国科学院国家纳米科学中心特别研究助理. 2018年在国家纳米中心获得理学博士学位, 导师魏志祥研究员. 主要从事超分子手性有机导电和半导体材料自组装以及相应光电功能器件的制备及性能研究.

    魏志祥, 中国科学院国家纳米科学中心研究员、博士生导师. 主要从事有机光电材料的自组装与柔性器件. 通过研究自组装过程中非共价相互作用的作用机制, 调节多种弱相互作用协同组装的过程, 制备结构和性能可控的有机光电功能纳米材料, 阐明从分子结构到微纳米结构, 再到宏观结构中结构和性能的传递规律; 开展自组装微纳米结构在太阳能电池、储能器件和传感器件等柔性电子器件中的应用基础研究.

  • 基金资助:
    中国科学技术部(2021YFA1200303); 国家自然科学基金(21721002); 国家自然科学基金(52003065); 国家自然科学基金(51673049); 国家自然科学基金(21975059); 中国科学院(XDB36010200); 中国博士后科学基金(2019M660584)

Chiral Organic Optoelectronic Materials and Circularly Polarized Light Luminescence and Detection

Lixuan Liua,b, Yang Yanga, Zhixiang Weia,b()   

  1. a CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China
    b School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2022-03-21 Published:2022-05-31
  • Contact: Zhixiang Wei
  • Supported by:
    Ministry of Science and Technology of China(2021YFA1200303); National Natural Science Foundation of China(21721002); National Natural Science Foundation of China(52003065); National Natural Science Foundation of China(51673049); National Natural Science Foundation of China(21975059); Strategic Priority Research Program of Chinese Academy of Sciences(XDB36010200); China Postdoctoral Science Foundation(2019M660584)

Chiral organic semiconductors have stimulated extensive research interests in the field of organic optoelectronics due to their fascinating properties. The incorporation of chirality into organic semiconducting materials can not only control their aggregation states by virtue of the unique non-covalent interactions among chiral molecules to regulate electronic/ optoelectronic properties, but also facilitates the emergence and development of circularly polarized light direct luminescence and detection. The interactions between chiral materials and circularly polarized light allow them to show broad application prospects in the field of three-dimensional display, quantum communications, information storage and processing, and so forth. This review summarizes the research progress of chiral organic optoelectronic materials and devices in recent years. It mainly reviews the influence of chirality on material properties and device performance, focusing on the applications of circularly polarized light luminescence and detection using chiral organic semiconductors, and aiming to promote the development of relevant research in the field of chiral optoelectronics.

Key words: chiral optoelectronics, chiral organic semiconductor, circularly polarized light luminescence, circularly polarized light detection