Advances in Electrochemical Reductive Removal of Oxyanions in Water★

doi:10.6023/A23040133

Acta Chimica Sinica ›› 2023, Vol. 81 ›› Issue (8): 979-989.DOI: 10.6023/A23040133 Previous Articles Next Articles

Special Issue: 庆祝《化学学报》创刊90周年合辑

Review

电化学还原去除水中含氧酸根离子研究进展^★

侯威, 么艳彩^*(), 张礼知^*()

上海交通大学环境科学与工程学院上海 200240

投稿日期:2023-04-13 发布日期:2023-09-14

作者简介:

侯威, 上海交通大学环境科学与工程学院2021级硕士研究生, 研究方向为电催化还原含氧酸根阴离子及其机制研究.

么艳彩, 上海交通大学环境科学与工程学院长聘教轨副教授, 研究方向为电催化、单原子催化剂在环境、能源领域的应用. 以第一作者/通讯作者身份在Nat. Catal., J. Am. Chem. Soc., Angew. Chem., Int. Ed. (2篇)、Sci. Bull.等期刊发表多篇论文, 共3篇入选ESI高被引论文, 截至2023年4月发表论文累计被引用1200余次. 申请发明专利6项, 成果转化1项. 撰写英文专著1部. 曾获中科院“百篇优博论文”和中科院院长优秀奖. 先后获得国家自然科学基金、上海市科委面上项目、科技部重点研发计划项目子课题、博后站前特别资助及博士后面上资助等7项省部级项目资助. 现任Colloid and Surface Science编委.

张礼知, 华中师范大学化学学院教授、上海交通大学特聘教授、博士生导师. 主要研究领域为污染控制化学、光催化及环境催化材料设计合成. 在Chem、Nat. Commun., J. Am. Chem. Soc., Angew. Chem., Int. Ed., Adv. Mater., Environ. Sci. Technol.等学术期刊发表论文360多篇, 其中29篇入选ESI高被引论文. 2011年获湖北省青年科技奖, 并入选湖北省自主创新“双百计划”, 2012年入选湖北省高端人才引领培养计划和湖北省高层次人才工程, 2014年起连续入选Elsevier发布“化学领域中国高被引学者榜单”, 2015年获教育部高等学校科学研究优秀成果奖(科学技术)自然科学二等奖(第一完成人), 2018年起连续入选Clarivate交叉领域全球高被引科学家榜单, 2019年获湖北省自然科学一等奖(第一完成人).

^★庆祝《化学学报》创刊90周年.

基金资助:
项目受国家自然科学基金(22102100); 项目受国家自然科学基金(21936003); 上海市自然科学基金(22ZR1431700); 国家重点研发计划(2021YFA1201701); 国家重点研发计划(2018YFC1800801)

Advances in Electrochemical Reductive Removal of Oxyanions in Water^★

Wei Hou, Yancai Yao(), Lizhi Zhang()

School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240

Received:2023-04-13 Published:2023-09-14
Contact: *E-mail: yyancai@sjtu.edu.cn; zhanglizhi@sjtu.edu.cn
About author:
^★Dedicated to the 90th anniversary of Acta Chimica Sinica.
Supported by:
National Natural Science Foundation of China(22102100); National Natural Science Foundation of China(21936003); Natural Science Foundation of Shanghai(22ZR1431700); National Key Research and Development Program of China(2021YFA1201701); National Key Research and Development Program of China(2018YFC1800801)

The excessive discharge of oxyanions (i.e., nitrate, bromate, perchlorate) into water has caused more and more serious environmental pollution problems. Oxyanions are generally persistent, refractory, teratogenic and carcinogenic, posing a great threat to ecosystems and human health. Therefore, they have increasingly attracted widespread attention. Electrochemical reduction is regarded as one of the most promising water treatment technology, because it could employ either electrons or strong reductive species (atomic H*) generated by dissociating water molecules to realize the efficient, green and safe removal of toxic oxyanions. Herein, the electrochemical reduction mechanism for removing pollutants is briefly introduced, the advancements of electrochemical reduction of nitrate, bromate and perchlorate are summarized and their possible reaction pathways are discussed, the effect of catalysts (i.e., structure, types) on the performance of electrochemical reduction is further analyzed. Finally, the possible challenges of electrochemical reduction technology to remove oxyanions are deeply discussed and prospected.

Key words: electrochemical reduction, oxyanion, water treatment, atomic hydrogen, detoxification

Cite this article

Wei Hou, Yancai Yao, Lizhi Zhang. Advances in Electrochemical Reductive Removal of Oxyanions in Water^★[J]. Acta Chimica Sinica, 2023, 81(8): 979-989.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

Fig. & Tab. 9

污染物	浓度限值/(mg•L^－1)	潜在的健康风险
硝酸盐	10.0(以N计)	高铁血红蛋白血症; 致癌物
亚硝酸盐	1.0(以N计)	高铁血红蛋白血症; 致癌物
氯酸盐	0.7	肾衰竭; 甲状腺功能障碍
高氯酸盐	0.07	甲状腺功能障碍
溴酸盐	0.01	致癌物

Table 1. Concentration limit and health effect of toxic oxyanions[10]

Figure 1. Electron-transfer mechanism of nitrate electroreduction

Figure 2. (a) Schematic illustration of in situ DEMS measurements[21], (b) mass spectrometry signals of in situ DEMS measurements[21], (c) magnification of selected mass spectrometry signals in (b)[21], (d) in situ Raman spectra of a-RuO2 at different applied potentials[54], (e) in situ DEMS[54] and (f) in situ FTIR spectra of a-RuO2 during nitrate electroreduction[54]

Figure 3. (a) Schematic diagram of electrocatalytic NO3RR for Pd/NF[60], (b) illustration of NO3RR on Cu(I)-N3C1[67], (c) NH3 FE of Fe SAC at each given potential (red dot is FE estimated by three independent NMR tests)[68], (d) NH3 yield rate at 3 h and faradaic efficiency (FE) of all Pd catalysts[62] and (e) illustration of NO3RR on Pd cuboctahedron[62]

电极材料	最佳电位/电流密度	活性(performance)	能耗(Energy consumption)	参考文献
Bi₁Pd	－0.6 V (vs. RHE)	产氨速率为33.8 mg•h^－1•cm^－2, FE约为100%	N/A	[63]
Pd-Cu/γAl₂O₃	10 mA/cm²	氮气的选择性约为80.37%	N/A	[64]
Ir_nanotube	0.06 V (vs. RHE)	产氨速率为921 μg•h^－1•mg_cat^－1, FE为84.7%	N/A	[65]
Strained Ru Nanoclusters	－0.20 V (vs. RHE)	产氨速率为5.56 mol•g_cat^－1•h^－1, FE为100%	N/A	[50]
Cu Nanosheets	－0.15 V (vs. RHE)	产氨速率为390.1 g•mg_Cu^－1•h^－1, FE为99.7%	N/A	[66]
Cu(I)-N₃C₁	－0.64 V (vs. RHE)	硝酸盐去除率94.8%	0.149 kWh/g-N	[67]
Fe single atom catalyst	－0.66 V (vs. RHE)	产氨速率为0.46 mmol•h^－1•cm^－2, FE为75%	N/A	[68]
Co-CuO_x	－1.1 V (vs. Ag/AgCl)	硝酸盐去除率95.2%, N₂选择性为96.0%	0.60 kWh•m^－3	[69]
Co Nanoarray	－0.24 V (vs. RHE)	产氨速率为10.4 mmol•h^－1•cm^－2, FE≥96%	N/A	[70]

Table 2. Materials for electrochemical nitrate reduction and their properties

电极材料	电化学活性/ (mmol•g_cat^－1•h^－1)	能耗/ (kWh•mmol^－1)	参考文献
nZVI/ACF	0.7×10^－3	6.42	[23]
Pd/rGO/CFP	0.31	N/A	[83]
Pd/NLSBC-800	2.4×10^－3	1.998	[84]
Pd-In/Al₂O₃	1.14×10^－3	N/A	[85]
RuCu/CNT	15.12	N/A	[25]
NG-Cu foam	N/A	N/A	[79]

Table 3. Materials for electrochemical bromate reduction and their properties

Figure 4. (a) Proposed mechanism of electrocatalytic bromate reduction on RuCu/CNT[25], (b) Gibbs free-energy diagram for H* transformation on the Pd-based catalysts[90], (c) schematic mechanism of enhanced bromate reduction performance on Pd2In3[90], (d) atomic structure diagram of H* and H2 adsorbed on the NG and G surfaces[79] and (e) energy diagram for H2 formation on the NG and G surfaces[79]

电极材料	ClO₄^－去除效率	能耗/(kWh•mmol^－1)	参考文献
Ni	N/A	N/A	[105]
Ti	N/A	N/A	[111]
Rh	N/A	N/A	[112]
Pd/Pt-ACF	53%	17.9	[6]
Pd/Pt-NACF	81%	9.9	[6]
Rh/Cu	78%	N/A	[109]
Rh/Ru	60%	N/A	[109]

Table 4. Materials for electrochemical perchlorate reduction and their properties

Figure 5. (a) Electrochemical reduction of perchlorate on all selected catalysis[109], (b) proposed electro-reduction mechanism of perchlorate by Re-Pd/BC[110], (c) schematic representation of the synergistic integration process on N-doped activated carbon fiber (Pd/Pt-NACF) electrode[6] and (d) schematic of the reactor and experimental setup on Re/REM[117]

References 123

[1]	Howarth A. J.; Liu Y.; Hupp J. T.; Farha O. K. CrystEngComm 2015, 17, 7245. doi: 10.1039/C5CE01428J
[2]	Chaplin B. P.; Reinhard M.; Schneider W. F.; Schuth C.; Shapley J. R.; Strathmann T. J.; Werth C. J. Environ. Sci. Technol. 2012, 46, 3655. doi: 10.1021/es204087q
[3]	Fan K.; Xie W.; Li J.; Sun Y.; Xu P.; Tang Y.; Li Z.; Shao M. Nat. Commun. 2022, 13, 7958. doi: 10.1038/s41467-022-35664-w
[4]	Heck K. N.; Garcia-Segura S.; Westerhoff P.; Wong M. S. Acc. Chem. Res. 2019, 52, 906. doi: 10.1021/acs.accounts.8b00642
[5]	Xiao Q.; Yu S.; Li L.; Zhang Y.; Yi P. Water Res. 2019, 150, 310. doi: 10.1016/j.watres.2018.11.067
[6]	Yao F.; Zhong Y.; Yang Q.; Wang D.; Chen F.; Zhao J.; Xie T.; Jiang C.; An H.; Zeng G.; Li X. J. Hazard. Mater. 2017, 323, 602. doi: 10.1016/j.jhazmat.2016.08.052
[7]	Shen J.; Yao F. B.; Chen S. J.; Yang L. Chin. J. Environ. Eng. 2022, 16, 12. (in Chinese)
	( 申剑, 姚福兵, 陈圣杰, 杨麒, 环境工程学报, 2022, 16, 12.)
[8]	Chen X.; Huo X.; Liu J.; Wang Y.; Werth C. J.; Strathmann T. J. Chem. Eng. J. 2017, 313, 745. doi: 10.1016/j.cej.2016.12.058
[9]	Montes-Hernandez G.; Concha-Lozano N.; Renard F.; Quirico E. J. Hazard. Mater. 2009, 166, 788. doi: 10.1016/j.jhazmat.2008.11.120
[10]	Yin Y. B.; Guo S.; Heck K. N.; Clark C. A.; Conrad C. L.; Wong M. S. ACS Sustainable Chem. Eng. 2018, 6, 11160. doi: 10.1021/acssuschemeng.8b02070
[11]	Caswell T.; Dlamini M. W.; Miedziak P. J.; Pattisson S.; Davies P. R.; Taylor S. H.; Hutchings G. J. Catal. Sci. Technol. 2020, 10, 2082. doi: 10.1039/C9CY02473E
[12]	Yao F.; Yang Q.; Zhong Y.; Shu X.; Chen F.; Sun J.; Ma Y.; Fu Z.; Wang D.; Li X. Water Res. 2019, 157, 191. doi: 10.1016/j.watres.2019.03.078
[13]	Alsewaileh A. S.; Usman A. R.; Al-Wabel M. I. J. Environ. Manage. 2019, 237, 289. doi: 10.1016/j.jenvman.2019.02.045
[14]	Matos C. T.; Fortunato R.; Velizarov S.; Reis M. A.; Crespo J. G. Water Res. 2008, 42, 1785. doi: 10.1016/j.watres.2007.11.006
[15]	Sadyrbaeva T. Z. Chem. Eng. Process. 2016, 99, 183. doi: 10.1016/j.cep.2015.07.011
[16]	Viglašová E.; Galamboš M.; Danková Z.; Krivosudský L.; Lengauer C. L.; Hood-Nowotny R.; Soja G.; Rompel A.; Matík M.; Briančin J. Waste Manage. 2018, 79, 385. doi: 10.1016/j.wasman.2018.08.005
[17]	Barrabés N.; Sá J. Appl. Catal., B 2011, 104, 1.
[18]	Liu G.; You S.; Zhang Y.; Huang H.; Spanjers H. J. Colloid Interface Sci. 2019, 553, 666. doi: 10.1016/j.jcis.2019.06.072
[19]	Sheldon R. A. Angew. Chem., Int. Ed. 2020, 60, 538. doi: 10.1002/anie.v60.2
[20]	Lei C.; Liang F.; Li J.; Chen W.; Huang B. Chem. Eng. J. 2019, 358, 1054. doi: 10.1016/j.cej.2018.10.105
[21]	Xu B.; Chen Z.; Zhang G. Environ. Sci. Technol. 2022, 56, 614. doi: 10.1021/acs.est.1c06091
[22]	Fan Z.; Zhao H.; Wang K.; Ran W.; Sun J. F.; Liu J.; Liu R. Environ. Sci. Technol. 2023, 57, 1499. doi: 10.1021/acs.est.2c07462
[23]	Yao F.; Yang Q.; Sun J.; Chen F.; Zhong Y.; Yin H.; He L.; Tao Z.; Pi Z.; Wang D.; Li X. Chem. Eng. J. 2020, 389, 123588. doi: 10.1016/j.cej.2019.123588
[24]	Zhang H. Environ. Sci. Pollut. Res. Int. 2019, 26, 10457. doi: 10.1007/s11356-019-04533-3
[25]	Wu T.; Hu J.; Wan Y.; Qu X.; Zheng S. J. Hazard. Mater. 2022, 438, 129551. doi: 10.1016/j.jhazmat.2022.129551
[26]	Liu C.; Zhang G.; Li Y.; Qu J.; Liu H. Small 2018, 14, 1800421.
[27]	Li Y.; Ren L.; Wang T.; Wu Z.; Wang Z. J. Hazard. Mater. 2023, 446, 130688. doi: 10.1016/j.jhazmat.2022.130688
[28]	Guo Y.; Li Y.; Wang Z. Water Res. 2023, 234, 119810. doi: 10.1016/j.watres.2023.119810
[29]	Canfield D. E.; Glazer A. N.; Falkowski P. G. Science 2010, 330, 192. doi: 10.1126/science.1186120
[30]	Zhu T.; Chen Q.; Liao P.; Duan W.; Liang S.; Yan Z.; Feng C. Small 2020, 16, 2004526.
[31]	Lim J.; Chen Y.; Cullen D. A.; Lee S. W.; Senftle T. P.; Hatzell M. C. ACS Catal. 2022, 13, 87. doi: 10.1021/acscatal.2c04841
[32]	Sun T.; Li Y. B.; Zhang R. S.; Mao R.; Wang K. F.; Liu X. B.; Guo C. H.; Zhao X. Chin. J. Environ. Eng. 2021, 41, 8. (in Chinese)
	( 孙拓, 李一兵, 张汝山, 冒冉, 王开丰, 刘新兵, 郭聪慧, 赵旭, 环境科学学报, 2021, 41, 8.)
[33]	Wang Y.; Wang C.; Li M.; Yu Y.; Zhang B. Chem. Soc. Rev. 2021, 50, 6720. doi: 10.1039/D1CS00116G
[34]	Theerthagiri J.; Park J.; Das H. T.; Rahamathulla N.; Cardoso E. S. F.; Murthy A. P.; Maia G.; Vo D. V. N.; Choi M. Y. Environ. Chem. Lett. 2022, 20, 2929. doi: 10.1007/s10311-022-01469-y
[35]	Yao Y.; Zhang L. Sci. Bull. 2022, 67, 1194. doi: 10.1016/j.scib.2022.05.004
[36]	Min B.; Gao Q.; Yan Z.; Han X.; Hosmer K.; Campbell A.; Zhu H. Ind. Eng. Chem. Res. 2021, 60, 14635. doi: 10.1021/acs.iecr.1c03072
[37]	Groot M.; Koper M. J. Electroanal. Chem. 2004, 562, 81. doi: 10.1016/j.jelechem.2003.08.011
[38]	Sicsic D.; Balbaud-Clrier F.; Tribollet B. Eur. J. Inorg. Chem. 2014, 17, 6174.
[39]	Xu H.; Ma Y.; Chen J.; Zhang W. X.; Yang J. Chem. Soc. Rev. 2022, 51, 2710. doi: 10.1039/D1CS00857A
[40]	Zeng Y.; Priest C.; Wang G.; Wu G. Small Methods 2020, 4, 2000672.
[41]	Zhang X.; Wang Y.; Liu C.; Yu Y.; Lu S.; Zhang B. Chem. Eng. J. 2021, 403, 126269. doi: 10.1016/j.cej.2020.126269
[42]	Bae S. E.; Stewart K. L.; Gewirth A. A. J. Am. Chem. Soc. 2007, 129, 10171. doi: 10.1021/ja071330n
[43]	Meng S.; Ling Y.; Yang M.; Zhao X.; Osman A. I.; Al-Muhtaseb A. H.; Rooney D. W.; Yap P.-S. J. Environ. Chem. Eng. 2023, 11, 109418. doi: 10.1016/j.jece.2023.109418
[44]	Garcia-Segura S.; Lanzarini-Lopes M.; Hristovski K.; Westerhoff P. Appl. Catal., B 2018, 236, 546. doi: 10.1016/j.apcatb.2018.05.041
[45]	Wang Z.; Young S. D.; Goldsmith B. R.; Singh N. J. Catal. 2021, 395, 143. doi: 10.1016/j.jcat.2020.12.031
[46]	Katsounaros I.; Kyriacou G. Electrochim. Acta 2008, 53, 5477. doi: 10.1016/j.electacta.2008.03.018
[47]	Vooys A.; Beltramo G. L.; Riet B. V.; Veen J.; Koper M. Electrochim. Acta 2004, 49, 1307. doi: 10.1016/j.electacta.2003.07.020
[48]	Yoshioka T.; Iwase K.; Nakanishi S.; Hashimoto K.; Kamiya K. J. Phys. Chem. C 2016, 120, 15729. doi: 10.1021/acs.jpcc.5b10962
[49]	Duca M.; Cucarella M. O.; Rodriguez P.; Koper M. J. Am. Chem. Soc. 2010, 132, 18042. doi: 10.1021/ja1092503
[50]	Li J.; Zhan G.; Yang J.; Quan F.; Mao C.; Liu Y.; Wang B.; Lei F.; Li L.; Chan A. W. M.; Xu L.; Shi Y.; Du Y.; Hao W.; Wong P. K.; Wang J.; Dou S. X.; Zhang L.; Yu J. C. J. Am. Chem. Soc. 2020, 142, 7036. doi: 10.1021/jacs.0c00418
[51]	Li T.; Tang C.; Guo H.; Wu H.; Duan C.; Wang H.; Zhang F.; Cao Y.; Yang G.; Zhou Y. ACS Appl. Mater. Interfaces 2022, 14, 49765. doi: 10.1021/acsami.2c14215
[52]	Perez-Gallent E.; Figueiredo M.; Katsounaros I.; Koper; M. T. Electrochim. Acta 2017, 227, 77. doi: 10.1016/j.electacta.2016.12.147
[53]	Xu Y.-T.; Xie M.-Y.; Zhong H.; Cao Y. ACS Catal. 2022, 12, 8698. doi: 10.1021/acscatal.2c02033
[54]	Wang Y.; Li H.; Zhou W.; Zhang X.; Zhang B.; Yu Y. Angew. Chem., Int. Ed. 2022, 61, e202202604.
[55]	Aristizábal A.; Contreras S.; Barrabés N.; Llorca J.; Tichit D.; Medina F. Appl. Catal., B 2011, 110, 58. doi: 10.1016/j.apcatb.2011.08.024
[56]	Yao Y.; Zhao L.; Dai J.; Wang J.; Fang C.; Zhan G.; Zheng Q.; Hou W.; Zhang L. Angew. Chem., Int. Ed. 2022, 61, e202208215.
[57]	Yin H.; Peng Y.; Li J. Environ. Sci. Technol. 2023, 57, 3134. doi: 10.1021/acs.est.2c07968
[58]	Liu H.; Lang X.; Zhu C.; Timoshenko J.; Bai L.; Guijarro N.; Yin H.; Peng Y.; Li J.; Liu Z. Angew. Chem., Int. Ed. 2022, 61, e202202556.
[59]	Dima G. E.; Vooys A. D.; Koper M. J. Electroanal. Chem. 2003, 554, 15.
[60]	Guo H.; Li M.; Yang Y.; Luo R.; Liu W.; Zhang F.; Tang C.; Yang G.; Zhou Y. Small 2023, 19, 2207743.
[61]	Jr D. B.; Gewirth A. A. Nano Energy 2016, 29, 457. doi: 10.1016/j.nanoen.2016.06.024
[62]	Lim J.; Liu C.-Y.; Park J.; Liu Y.-H.; Senftle T. P.; Lee S. W.; Hatzell M. C. ACS Catal. 2021, 11, 7568. doi: 10.1021/acscatal.1c01413
[63]	Chen K.; Ma Z.; Li X.; Kang J.; Ma D.; Chu K. Adv. Funct. Mater. 2023, 33, 2209890.
[64]	Zhang Z.; Xu Y.; Shi W.; Wang W.; Zhang R.; Bao X.; Zhang B.; Li L.; Cui F. Chem. Eng. J. 2016, 290, 201. doi: 10.1016/j.cej.2016.01.063
[65]	Zhu J. Y.; Xue Q.; Xue Y. Y.; Ding Y.; Li F. M.; Jin P.; Chen P.; Chen Y. ACS Appl. Mater. Interfaces 2020, 12, 14064. doi: 10.1021/acsami.0c01937
[66]	Fu X.; Zhao X.; Hu X.; He K.; Yu Y.; Li T.; Tu Q.; Qian X.; Yue Q.; Wasielewski M. R.; Kang Y. Appl. Mater. Today 2020, 19, 100620.
[67]	Xue Y.; Yu Q.; Ma Q.; Chen Y.; Zhang C.; Teng W.; Fan J.; Zhang W. X. Environ. Sci. Technol. 2022, 56, 14797. doi: 10.1021/acs.est.2c04456
[68]	Wu Z. Y.; Karamad M.; Yong X.; Huang Q.; Cullen D. A.; Zhu P.; Xia C.; Xiao Q.; Shakouri M.; Chen F. Y.; Kim J. Y. T.; Xia Y.; Heck K.; Hu Y.; Wong M. S.; Li Q.; Gates I.; Siahrostami S.; Wang H. Nat. Commun. 2021, 12, 2870. doi: 10.1038/s41467-021-23115-x
[69]	Li Y.; Ma J.; Wu Z. Environ. Sci. Technol. 2022, 56, 8673. doi: 10.1021/acs.est.1c05841
[70]	Deng X.; Yang Y.; Wang L.; Fu X.; Luo J. Adv. Sci. 2021, 8, 2004523.
[71]	Zheng W. X.; Zhu L. Y.; Yan Z.; Lin Z. C.; Lei Z. C.; Zhang Y. F.; Xu H. L.; Dang Z.; Wei C. H.; Feng C. H. Environ. Sci. Technol. 2021, 55, 13231.
[72]	Soltermann F.; Abegglen C.; Tschui M.; Stahel S.; Gunten U. V. Water Res. 2017, 116, 76. doi: 10.1016/j.watres.2017.02.026
[73]	Li A. Z.; Mao R.; Zhao X. Chin. Sci. China: Chem. 2014, 10, 7. (in Chinese)
	( 李昂臻, 冒冉, 赵旭, 中国科学: 化学, 2014, 10, 7.)
[74]	Richardson S. D.; Plewa M. J.; Wagner E. D.; Schoeny R.; Demarini D. M. Mutat. Res.,Rev. Mutat. Res. 2007, 636, 178. doi: 10.1016/j.mrrev.2007.09.001
[75]	Lu Z.; Yang Q.; Hu T. Chem. Eng. J. 2022, 446, 137356. doi: 10.1016/j.cej.2022.137356
[76]	Liang D.; Qin L.; Cui H.; Tang R.; Hui X.; Xie X.; Zhai J. Electrochim. Acta 2010, 55, 8471. doi: 10.1016/j.electacta.2010.07.062
[77]	Zhao X.; Liu H.; Li A.; Shen Y.; Qu J. Electrochim. Acta 2012, 62, 181. doi: 10.1016/j.electacta.2011.12.013
[78]	Townshend A. Anal. Chim. Acta 1987, 198, 333. doi: 10.1016/S0003-2670(00)85044-8
[79]	Mao R.; Yan L.; Zhao X.; Djellabi R.; Wang K.; Hu K.; Zhu H. Chem. Eng. J. 2022, 429, 132139. doi: 10.1016/j.cej.2021.132139
[80]	Kishimoto N.; Matsuda N. Environ. Sci. Technol. 2009, 43, 2054. doi: 10.1021/es803144w
[81]	Zhou D.; Ding L.; Cui H.; An H.; Zhai J.; Li Q. Chem. Eng. J. 2012, 200-202, 32.
[82]	Cuentas-Gallegos A. K.; Miranda-Hernández M.; Vargas-Ocampo A. Electrochim. Acta 2009, 54, 4378. doi: 10.1016/j.electacta.2009.03.010
[83]	Mao R.; Zhao X.; Lan H.; Liu H.; Qu J. Appl. Catal., B 2014, 160-161, 179.
[84]	Yao F.; Yang Q.; Yan M.; Li X.; Li X. J. Hazard. Mater. 2019, 386, 121651. doi: 10.1016/j.jhazmat.2019.121651
[85]	Lan H.; Mao R.; Tong Y.; Liu Y.; Liu H.; An X.; Liu R. Environ. Sci. Technol. 2016, 50, 11872. doi: 10.1021/acs.est.6b02822
[86]	Conner W. C.; Falconer J. L. Chem. Rev. 1995, 95, 123.
[87]	Nutt M.; Hughes J.; Wong M. Environ. Sci. Technol. 2005, 39, 1346. doi: 10.1021/es048560b
[88]	Figueras C. F. J. Mol. Catal. A: Chem. 2001, 173, 117. doi: 10.1016/S1381-1169(01)00148-0
[89]	Witonska I. A.; Walock M. J.; Dziugan P.; Karski S.; Stanishevsky A. V. Appl. Surf. Sci. 2013, 273, 330. doi: 10.1016/j.apsusc.2013.02.039
[90]	Zhou Y.; Zhang G.; Ji Q.; Zhang W.; Zhang J.; Liu H.; Qu J. Environ. Sci. Technol. 2019, 53, 11383. doi: 10.1021/acs.est.9b03111
[91]	Yao Q.; Zhou X.; Xiao S.; Chen J.; Zhang Y. Water Res. 2019, 165, 114930. doi: 10.1016/j.watres.2019.114930
[92]	Gao J. N.; Jiang B.; Ni C. C.; Qi Y. F.; Zhang Y. Q.; Oturan N.; Oturan M. A. Appl. Catal., B 2019, 254, 391. doi: 10.1016/j.apcatb.2019.05.016
[93]	Cao F.; Jaunat J.; Sturchio N.; Cances B.; Morvan X.; Devos A.; Barbin V.; Ollivier P. Sci. Total Environ. 2019, 661, 737. doi: 10.1016/j.scitotenv.2019.01.107
[94]	Li H.; Zhou L.; Lin H.; Zhang W.; Xia S. Sci. Total Environ. 2019, 694, 133564. doi: 10.1016/j.scitotenv.2019.07.370
[95]	Fang Q. L.; Chen B. L. Chin. J. Environ. Eng. 2011, 31, 1569. (in Chinese)
	( 方齐乐, 陈宝梁, 环境科学学报, 2011, 31, 1569.)
[96]	Ren C.; Yang P.; Sun J.; Bi E. Y.; Gao J.; Palmer J.; Zhu M.; Wu Y.; Liu J. J. Am. Chem. Soc. 2021, 143, 7891. doi: 10.1021/jacs.1c00595
[97]	Scheytt T. J.; Freywald J.; Ptacek C. J. Grundwasser 2011, 16, 37. doi: 10.1007/s00767-010-0159-0
[98]	Greer M. A.; Goodman G.; Pleus R. C.; Greer S. E. Environ. Health Perspect. 2005, 113, A 732.
[99]	Cartier T.; Baert A.; Cabillic P. J.; Casellas C.; Joyeux M. Environnement, Risques & Sante 2012, 11, 316.
[100]	Yang Q.; Yao F.; Zhong Y.; Wang D.; Chen F.; Sun J.; Hua S.; Li S.; Li X.; Zeng G. Chem. Eng. J. 2016, 306, 1081. doi: 10.1016/j.cej.2016.08.041
[101]	Wasberg M.; Horányi G. J. Electroanal. Chem. 1995, 381, 151. doi: 10.1016/0022-0728(94)03667-R
[102]	Láng G. G.; Horányi G. J. Electroanal. Chem. 2003, 552, 197. doi: 10.1016/S0022-0728(02)01302-5
[103]	Láng G. G.; Sas N. S.; Ujvári M.; Horányi G. Electrochim. Acta 2008, 53, 7436. doi: 10.1016/j.electacta.2007.12.007
[104]	Mahmudov R.; Shu Y.; Rykov S.; Chen J.; Huang C. P. Appl. Catal., B 2008, 81, 78. doi: 10.1016/j.apcatb.2007.11.039
[105]	Rusanova M. Y.; PolasKova P.; Muzika M.; Fawcett W. R. Electrochim. Acta 2006, 51, 3097. doi: 10.1016/j.electacta.2005.08.044
[106]	Wang D.; Huang C.; Chen J.; Lin H.; Shah S. Sep. Purif. Technol. 2007, 58, 129. doi: 10.1016/j.seppur.2007.07.028
[107]	Wang D. M.; Lin H. Y.; Shah S. I.; Ni C. Y.; Huang C. P. Sep. Purif. Technol. 2009, 67, 127. doi: 10.1016/j.seppur.2009.03.008
[108]	Hurley K. D.; Shapley J. R. Environ. Sci. Technol. 2007, 41, 2044. doi: 10.1021/es0624218
[109]	Wang P.-Y.; Chen C.-L.; Huang C. P. J. Environ. Eng. 2019, 145, 04019046.
[110]	Xu B.; Zhai Y.; Chen W.; Wang B.; Wang T.; Zhang C.; Li C.; Zeng G. Chem. Eng. J. 2018, 348, 765. doi: 10.1016/j.cej.2018.05.052
[111]	Wang D. M.; Lin H. Y.; Shah S. I.; Ni C. Y.; Huang C. P. Sep. Purif. Technol. 2009, 67, 127. doi: 10.1016/j.seppur.2009.03.008
[112]	Láng G. G.; Sas N. S.; Ujvári M.; Horányi G. Electrochim. Acta 2008, 53, 7436. doi: 10.1016/j.electacta.2007.12.007
[113]	Kim Y.-N.; Lee Y.-C.; Choi M. Carbon 2013, 65, 315. doi: 10.1016/j.carbon.2013.08.031
[114]	Ge L.; Rabiee H.; Li M. Chem 2022, 8, 663. doi: 10.1016/j.chempr.2021.12.002
[115]	Ma J.; Wei W.; Qin G.; Xiao T.; Tang W.; Zhao S.; Jiang L.; Liu S. Water Res. 2022, 208, 117862. doi: 10.1016/j.watres.2021.117862
[116]	Misal S. N.; Lin M. H.; Mehraeen S.; Chaplin B. P. J. Hazard. Mater. 2022, 384, 121420. doi: 10.1016/j.jhazmat.2019.121420
[117]	Almassi S.; Ren C.; Liu J.; Chaplin B. P. Environ. Sci. Technol. 2022, 56, 3267. doi: 10.1021/acs.est.1c08220
[118]	Seibert D.; Zorzo C. F.; Borba F. H.; De Souza R. M.; Quesada H. B.; Bergamasco R.; Baptista A. T.; Inticher J. J. Sci. Total Environ. 2020, 748, 141527. doi: 10.1016/j.scitotenv.2020.141527
[119]	Zhang Y.; Guo L.; Tao L.; Lu Y.; Wang S. Small Methods 2018, 3, 1800406.
[120]	Hu X.; Hu G.; Li X.; Zhao X.; Zhou Y.; Hu J.; Zhang H. Appl. Surf. Sci. 2022, 584, 152556. doi: 10.1016/j.apsusc.2022.152556
[121]	Meng N.; Huang Y.; Liu Y.; Yu Y.; Zhang B. Cell Rep. Phys. Sci. 2021, 2, 100378.
[122]	Qin J.; Liu N.; Chen L.; Wu K.; Zhao Q.; Liu B.; Ye Z. ACS Sustainable Chem. Eng. 2022, 10, 15869. doi: 10.1021/acssuschemeng.2c05110
[123]	Pei S.; Shi H.; Zhang J.; Wang S.; Ren N.; You S. J. Hazard. Mater. 2021, 419, 126434. doi: 10.1016/j.jhazmat.2021.126434

电化学还原去除水中含氧酸根离子研究进展^★

Advances in Electrochemical Reductive Removal of Oxyanions in Water^★

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 9

References 123

Related Articles 12

Recommended Articles

Metrics

Comments

[1]	Huiying Zhang, Shuyan Yu, Congju Li. Electrocatalytic Degradation of Wastewater by Polymer-based Carbon Nanomembranes and Mechanism [J]. Acta Chimica Sinica, 2023, 81(4): 420-430.
[2]	Jiang Chenghao, Feng Xiao, Wang Bo. Preparation of Covalent Organic Framework Membranes and Their Applications in Seawater Desalination and Water Treatment [J]. Acta Chimica Sinica, 2020, 78(6): 466-477.
[3]	Zhao Weiwei, Wang Yilin. Development of Surfactant Application in Wastewater Treatment [J]. Acta Chim. Sinica, 2019, 77(8): 717-728.
[4]	GE Hong-Hua, WEI Cheng-Jun, GONG Xiao-Ming, XU Xue-Min, TAO Jie-Ting, YAO Xiu-Ping. Effect of Electromagnetic Treatment on Sedimentation and Adhesion Behavior of Calcium Carbonate Particles Formed in Aqueous Solution [J]. Acta Chimica Sinica, 2011, 69(19): 2313-2318.
[5]	YUAN Yuan, ZHANG Ming-Zu, ZHANG Hu, NI Pei-Hong. Synthesis and Properties of pH-Responsive Fluorinated Amphiphilic Triblock Copolymers [J]. Acta Chimica Sinica, 2010, 68(15): 1537-1544.
[6]	GUO Yu-Liang*^,1,2; ZHENG Xiang-Long²; HU Xi-En²; ZHU Quan. Reduction Performance of 4-Nitropyridine-1-oxide on the Electrodes of Platinum and Copper [J]. Acta Chimica Sinica, 2007, 65(23): 2680-2686.
[7]	ZHANG Fang*, LI Guang-Ming, SHENG Yi, HU Hui-Kang, WANG Hua. Preparation of Mn-Sn-Sb/γ-Al₂O₃ Particle-electrodes for Electrocatalytic Oxidation of Phenol Wastewater [J]. Acta Chimica Sinica, 2006, 64(3): 235-239.
[8]	WANG Jian-Bing*, ZHU Wan-Peng, YANG Shao-Xia, ZHOU Yun-Rui. Study on Catalytic Wet Air Oxidation of Acetic Acid by Zr_xCe_1－xO₂ Catalyst [J]. Acta Chimica Sinica, 2006, 64(15): 1537-1542.
[9]	JIA Zhi-Feng, CHEN Hao, YAN De-Yue*. Synthesis of Hyperbranched Poly(2-hydroxypropyl methacrylate) by Self-condensing Vinyl Oxyanionic Polymerization [J]. Acta Chimica Sinica, 2005, 63(20): 1861-1865.
[10]	Chen Jinyuan;Peng Tuzhi;Xiao Yanfeng. Preparation of Titanium Dioxide/Bentonite Composite Material with HIgh Activity and Study on Its Photo-catalysis [J]. Acta Chimica Sinica, 2003, 61(8): 1311-1315.
[11]	Song Xiuqin;Zhang Xuehong;Wang Xin;Wang Lanxia;Zhang Ping;Wei Yu. Layer-by-layer Self-assembly of Nanostructural TiO_2/SiO_2 [J]. Acta Chimica Sinica, 2003, 61(5): 780-784.
[12]	BAO CHANGNIAN;LI DEWEN;XIA QUAN;JIN YINGHUA. The studies of the extraction of phenol with tributyl phosphate [J]. Acta Chimica Sinica, 1988, 46(2): 184-186.

电化学还原去除水中含氧酸根离子研究进展★

Advances in Electrochemical Reductive Removal of Oxyanions in Water★

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 9

References 123

Related Articles 12

Recommended Articles

Metrics

Comments

电化学还原去除水中含氧酸根离子研究进展^★

Advances in Electrochemical Reductive Removal of Oxyanions in Water^★