Recent Advances in the Nacre-inspired Layered Polymer Nanocomposites by Ice Templating Technique★

doi:10.6023/A23050207

Acta Chimica Sinica ›› 2023, Vol. 81 ›› Issue (9): 1231-1239.DOI: 10.6023/A23050207 Previous Articles Next Articles

Special Issue: 庆祝《化学学报》创刊90周年合辑

Review

冰模板技术仿生构筑层状高分子纳米复合材料的研究进展^★

王华高^a, 程群峰^a^,^b^,^c^,^*()

a 北京航空航天大学化学学院仿生智能界面科学与技术教育部重点实验室北京 100191
b 中国科学技术大学化学与材料学院合肥 230026
c 中国科学技术大学苏州高等研究院苏州 215123

投稿日期:2023-05-05 发布日期:2023-06-27

作者简介:

王华高, 北京航空航天大学材料物理与化学专业在读博士研究生, 主要从事仿生层状高分子纳米复合材料研究.

程群峰, 北京航空航天大学化学学院, 教授, 博士生导师, 国家杰出青年科学基金获得者. 主要从事高分子纳米复合材料的研究工作, 发现了二维碳纳米复合材料“孔隙缺陷”的新现象, 发展了一系列消除孔隙缺陷的新技术和新策略, 创制了兼具高力学、电学和电磁屏蔽性能的碳纳米复合材料, 为碳纳米复合材料在航空航天领域的应用奠定了理论基础. 获北京市科学技术奖-杰出青年中关村奖、茅以升科学技术奖-北京青年科技奖、中国化学会青年化学奖等. 担任中国复合材料学会纳米复合材料分会常务副主任以及Chin. Chem. Lett., Biomater. Adv., Giant, 2D Materials等期刊编委; Interdiscip. Mater.学术编辑. 以通讯作者在Science, Nat. Mater., Nat. Commun., PNAS等期刊发表论文100余篇, 引用8000余次, H因子51, 授权中国发明专利35项.

^★庆祝《化学学报》创刊90周年.

基金资助:
国家重点研发计划(2021YFA0715700); 国家杰出青年科学基金(52125302); 国家自然科学基金(22075009); 111引智计划(B14009)

Recent Advances in the Nacre-inspired Layered Polymer Nanocomposites by Ice Templating Technique^★

Huagao Wang^a, Qunfeng Cheng^a^,^b^,^c()

a Key Laboratory of Bio-inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry, Beihang University, Beijing 100191
b School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026
c Suzhou Institute for Advanced Research, University of Science and Technology of China, Suzhou 215123

Received:2023-05-05 Published:2023-06-27
Contact: *E-mail: cheng@buaa.edu.cn
About author:
^★Dedicated to the 90th anniversary of Acta Chimica Sinica.
Supported by:
The National Key Research and Development Program of China(2021YFA0715700); The National Science Fund for Distinguished Young Scholars(52125302); The National Natural Science Foundation of China(22075009); The 111 Project(B14009)

Ice templating, known as directional freeze casting, is a novel technique for constructing laminar porous materials by homogeneously dispersing or dissolving the building blocks, solvents and additives and using the “liquid-solid-gas” phase transition of the solvent. Inspired by the “brick-mortar” layered structure, the lamellar scaffold prepared from ice templating can be densified to construct nacre-like composite. This work presents a timely and systematic investigation and summary of frontier progresses of layered polymer nanocomposites constructed by the ice templating technique. Firstly, the densification strategies are classified according the different thickness of “brick” into three strategies: lamellar scaffold-filled polymer, hot-pressing treatment and mineralization. And typical layered polymer nanocomposites constructed by each strategy and their properties are also presented with classical examples. Subsequently, the design and functional applications of layered polymer nanocomposites are analyzed and discussed, such as the modulation of microstructures, introduction of functional building blocks, and enhancement of interfacial interactions, which not only improve the mechanical properties of layered polymer nanocomposites, but also endow them with functional applications, such as electromagnetic shielding, thermal conductivity and self-monitoring of structural integrity. Finally, we provide an outlook on the future directions and challenges of the structural design, performance optimization and application expansion of nacre-inspired layered polymer nanocomposites constructed by the ice templating technique.

Key words: natural nacre, ice template, layered polymer nanocomposites, mechanical property, functional application

Cite this article

Huagao Wang, Qunfeng Cheng. Recent Advances in the Nacre-inspired Layered Polymer Nanocomposites by Ice Templating Technique^★[J]. Acta Chimica Sinica, 2023, 81(9): 1231-1239.

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Fig. & Tab. 9

Figure 1. Composition, hierarchical structure and properties of natural nacre (a) Calcium carbonate nanoparticles and proteins with chitin to form natural nacre; (b) Interfacial interaction between aragonite tablets: mainly including mineral bridges, surface protrusion to inhibit deformation, cohesive organic layer and plate interlocking; (c) SEM image of a natural nacre, showing a typical “brick-mortar” layered structure[1] (Copyright 2015 Springer Nature); (d) Crack resistance curves for natural nacre[7] (Copyright 2007 Springer Nature); (e) SEM image of the fracture surface of the nacre[1] (Copyright 2015 Springer Nature); (f) Toughening mechanisms during crack extension in natural nacre, showing crack deflection, crack bridge and tablets sliding[11] (Copyright 2016 AAAS)

Figure 2. Mechanisms and processes for constructing layered polymer nanocomposites by the ice templating technique (a) Preparation of slurry, solution or dispersion; (b) condensation of water by directional freezing and exclusion of building blocks between lamellar ice crystals; (c) freeze-drying to remove ice crystals and retain the lamellar scaffold; (d) densification of the lamellar scaffold to fabricate layered polymer nanocomposites[13,15]

Figure 3. Strategies for preparation of layered polymer nanocomposites by the ice templating technique (a) Filling strategy[41] (Copyright 2023 Wiley-VCH Verlag GmbH); (b) Hot-pressing strategy[35] (Copyright 2021 AAAS. http://creativecommons.org/ licenses/by /4.0/); (c) Mineralization strategy[22] (Copyright 2016 AAAS); (d) Development and representative layered polymer nanocomposites[19?????????????????????????-45]

Figure 4. Filling strategy for constructing nacre-like layered polymer nanocomposites (a) Schematic diagram of the constructing process; (b) SEM image of the nacre-like layered polymer nanocomposites (inset is an optical photograph)[24] (Copyright 2016 Wiley-VCH Verlag GmbH); (c) Comparison of the hardness of the artificial material with that of human dentin and enamel; (d) Rising crack-extension resistance curves; (e) XRT volume rendering of crack propagation initiated from a sharpened notch tip in the nacre-like layered polymer nanocomposites[36] (Copyright 2019 Wiley-VCH Verlag GmbH)

Figure 5. Nacre-like layered polymer nanocomposites (a) Micro-computed tomography (micro-CT) scans of long-range layered nanocomposites; (b) SEM image of nanocomposites with long-range align structures[43] (Copyright 2020 AAAS. http://creativecommons.org/licenses/by/ 4.0/); (c) relationship between freezing rate and layer thickness[29] (Copyright 2019 Wiley-VCH Verlag GmbH); (d) polymer nanocomposites with cross- layered conch shell-like structures[44] (Copyright 2022 Wiley-VCH Verlag GmbH)

Figure 6. Nacre-like layered polymer nanocomposites constructed with a small amount of building blocks (a) SEM image of the layered graphene scaffold; (b) SEM image of the layered graphene/epoxy nanocomposites; (c) rising crack extension resistance curve for layered graphene/epoxy nanocomposites[47] (Copyright 2019 Elsevier); (d) SEM image of the layered MXene/epoxy nanocomposites; (e) schematic diagram of the interfacial interaction of layered MXene/epoxy nanocomposites; (f) rising crack extension resistance curve for layered MXene/epoxy nanocomposites[41] (Copyright 2023 Wiley-VCH Verlag GmbH); (g) Mechanical properties of layered MMT/PDMS nanocomposites; (h) Confocal fluorescence microscopy (CFM) image of layered MMT/PDMS nanocomposites; (i) CFM image of layered MMT/PDMS nanocomposites during crack extension[34] (Copyright 2021 Springer Nature. http://creativecommons.org/licenses/by/4.0/)

Figure 7. Hot-pressing strategy for constructing nacre-like layered polymer nanocomposites (a) Schematic diagram of the preparation of silk nacre by hot pressing; (b) SEM image of the silk lamellar scaffold; (c) SEM image of the silk nacre (inset is an optical photograph); (d) bending stress-strain curve of the silk nacre[38] (Copyright 2022 AAAS. http://creativecommons.org/licenses/by/4.0/)

Figure 8. Mineralization strategy for constructing artificial nacre (a) Fabrication scheme of the artificial nacre; (b) bulk synthetic nacre; (c) SEM image of the artificial nacre[22] (Copyright 2016 AAAS); (d) high-resolution transmission electron microscope image of magnetic nanoparticles in artificial nacre; (e) crack growth resistance curves of the artificial nacre; (f) Ashby plots of the toughness amplification factor[37] (Copyright 2022 Wiley-VCH Verlag GmbH)

Figure 9. Representative applications of layered polymer nanocomposites (a) Electromagnetic shielding mechanism of layered polymer nanocomposites[28] (Copyright 2018 American Chemical Society); (b) electromagnetic shielding effectiveness of layered porous PI/MXene nanocomposites[35] (Copyright 2021 AAAS. http://creativecommons.org/licenses/by/4.0/); (c) application demonstration of the BN/PU layered nanocomposites as a thermal interface material[40] (Copyright 2022 American Chemical Society); (d) and (e) self-monitoring of the structural integrity of layered MXene/epoxy nanocomposites[41] (Copyright 2023 Wiley-VCH Verlag GmbH)

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冰模板技术仿生构筑层状高分子纳米复合材料的研究进展^★

Recent Advances in the Nacre-inspired Layered Polymer Nanocomposites by Ice Templating Technique^★

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冰模板技术仿生构筑层状高分子纳米复合材料的研究进展★

Recent Advances in the Nacre-inspired Layered Polymer Nanocomposites by Ice Templating Technique★

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References 53

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冰模板技术仿生构筑层状高分子纳米复合材料的研究进展^★

Recent Advances in the Nacre-inspired Layered Polymer Nanocomposites by Ice Templating Technique^★