Research Progress of Rare Earth-Based Circularly Polarized Luminescent Materials

doi:10.6023/A24030071

Acta Chimica Sinica ›› 2024, Vol. 82 ›› Issue (6): 707-730.DOI: 10.6023/A24030071 Previous Articles

Review

稀土圆偏振发光材料研究进展

李小贞^a^,^b, 孙庆福^b^,^*()

a 福建师范大学海峡柔性电子实验室福州 350117
b 中国科学院福建物质结构研究所结构化学国家重点实验室福州 350002

投稿日期:2024-03-06 发布日期:2024-04-28

作者简介:

李小贞, 2018年于中国科学院福建物质结构研究所获得理学博士学位, 2018~2021年在中国科学院福建物质结构研究所从事博士后研究, 2021年~2022年在中国科学院福建物质结构研究所担任副研究员, 2022年入职福建师范大学. 主要研究方向为超分子自组装和手性稀土功能材料.

孙庆福, 中国科学院福建物质结构研究所研究员, 课题组长. 2011年获东京大学应用化学专业博士学位, 留日期间曾获日本学术振兴会青年科学家(JSPS-DC及JSPS-PD)项目及国家优秀自费留学生奖学金资助. 2012年赴美国能源部资助下的劳伦斯伯克利国家实验室及加州大学伯克利分校进行博士后研究. 2013年以国家高层次人才引进到中国科学院福建物质结构研究所独立开展研究工作. 主要研究兴趣包括大环和笼状超分子配合物的设计合成、发光及磁性调控、主客体性质及仿酶催化等, 研究成果发表在Science, Nat. Chem., Nat. Commun., J. Am. Chem. Soc.等知名期刊. 曾获得国家自然科学基金委杰出青年基金、中组部“海外高层次人才计划”、中科院“人才引进计划”、福建省“创新创业人才计划”等人才项目, 获得中国化学会青年化学奖、中科院优秀导师奖、福建省青年五四奖章标兵、福建省青年科技奖等荣誉.

基金资助:
福建省自然科学基金(2021J02016); 福建省自然科学基金(2023J01528); 国家自然科学基金(21901245)

Research Progress of Rare Earth-Based Circularly Polarized Luminescent Materials

Xiaozhen Li^a^,^b, Qingfu Sun^b,*()

a Strait Institute of Flexible Electronics, Fujian Normal University, Fuzhou 350117
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002

Received:2024-03-06 Published:2024-04-28
Contact: * E-mail: qfsun@fjirsm.ac.cn
Supported by:
Natural Science Foundation of Fujian Province(2021J02016); Natural Science Foundation of Fujian Province(2023J01528); National Natural Science Foundation of China(21901245)

As a special and important light, circularly polarized light (CPL) has shown unprecedented potentials in the applications of advanced three-dimensional (3D) displays, organic optoelectronic devices, security inks, and biological or chemical probes. Luminescence dissymmetry factor (g_lum) and quantum yields (Φ) are important factors that adopted to evaluate the magnitudes of CPL signals. Most chiral luminescent materials have low g_lum values due to the low magnetic-dipole transition moments. Attributing to the unique photophysical, optoelectronic properties and magnetic-dipole allowed transitions, chiral rare earth materials are promising candidates for circularly polarized luminescent materials possessing both large g_lum and high Φ. Herein, a comprehensive and up-to-date overview of the research progress of rare earth-based circularly polarized luminescent materials is presented, which contains: (i) the developments of visible light, near-infrared light (NIR) and two-photon circularly polarized luminescence; (ii) the effects of ligands, solvents, anions, supermolecular self-assembly, external stimulus on the circularly polarized luminescence performances; (iii) the applications in circularly polarized-organic light-emitting diodes (CP-OLED), biosensing, detection, and security devices. Finally, current challenges and future opportunities are discussed.

Key words: rare earth, chirality, circularly polarized luminescence, self-assembly, luminescence dissymmetry factor

Cite this article

Xiaozhen Li, Qingfu Sun. Research Progress of Rare Earth-Based Circularly Polarized Luminescent Materials[J]. Acta Chimica Sinica, 2024, 82(6): 707-730.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

Fig. & Tab. 10

化合物	λ_em/nm	PLQY/%	跃迁	g_lum		文献
[EuL1]³⁺		0.06/H₂O 0.3/D₂O				[45]
[Eu^RL4]³⁺	588, 593, 615, 668, 687		⁵D₀→⁷F_J	+0.02, –0.03 (ΔJ=1), 0.12, 0.4, –0.11 (ΔJ=2,3,4)		[45]
[Eu^RL5]³⁺	580, 590, 615, 650, 680		⁵D₀→⁷F_J	–0.12, +0.18 (ΔJ=1） –0.1, –0.3, –0.11 (ΔJ=2,3,4)		[46]
[Eu^SL6]³⁺	588, 595, 614	21/H₂O 27/D₂O	⁵D₀→⁷F_J	+0.18, –0.16 (ΔJ=1), –0.04 (ΔJ=2)		[47]
[Eu^SL7]^–	591, 657	14/H₂O/MeOH 47/DMSO	⁵D₀→⁷F_J	–0.18 (ΔJ=1) +0.17 (ΔJ=3)		[50]
[Eu^RL7]^–	591, 657	14.9/H₂O/MeOH 53/DMSO	⁵D₀→⁷F_J	+0.17 (ΔJ=1) +0.13 (ΔJ=3)		[50]
[Eu^SL8]^–	591, 657	11/H₂O/MeOH 0.45/DMSO	⁵D₀→⁷F_J	–0.11 (ΔJ=1) –0.12 (ΔJ=3)		[50]
[Eu^SL9]^–	591, 657	0.40/DMSO	⁵D₀→⁷F_J	+0.30 (ΔJ=1) +0.25 (ΔJ=3)		[50]
[Eu^SL10]^–	591, 653	10.2/H₂O/MeOH 44.1/DMSO	⁵D₀→⁷F_J	–0.11 (ΔJ=1) –0.10 (ΔJ=3)		[50]
[Eu^SL11]^–	588, 657	21.9/H₂O/MeOH 49.7/DMSO	⁵D₀→⁷F_J	–0.17 (ΔJ=1) –0.29 (ΔJ=3)		[50]
[Eu^RL14]⁺	596	2.3	⁵D₀→⁷F₁	+0.298		[53]
EuL15	586.6, 594.2, 543.6	7.7	⁵D₀→⁷F₁	±0.046, ±0.12, ±0.083		[54]
[Eu^RRL17]³⁺			⁵D₀→⁷F₁ ⁵D₀→⁷F₄	–0.19, –0.22		[55]
[Eu^RL18]³⁺	590		⁵D₀→⁷F₁	+0.02		[56]
[Eu^RL19-Me]²⁺	587	55		1.7×10^–3		[57]
[Eu^RL19-ⁱPr]²⁺	560	53		1.8×10^–3		[57]
[EuL20]⁺	598, 607		⁵D₀→⁷F_J	±0.2 (ΔJ=1), ±0.2 (ΔJ=2)		[58]
Eu(+L23)₃	588.2			–0.78		[59]
Eu(+L24)₃	612		⁵D₀→⁷F₂	+0.003		[15]
Cs[Eu(+L24)₄]	595, 612		⁵D₀→⁷F_J	+1.38 (ΔJ=1) –0.23 (ΔJ=2)		[15]
Cs[Eu(+L24)₄]	595, 612		⁵D₀→⁷F_J	+1.32 (ΔJ=1) –0.19 (ΔJ=2)		[15]
Na[Eu(+L24)₄]	595, 612		⁵D₀→⁷F_J	+0.06 (ΔJ=1) –0.01 (ΔJ=2)		[15]
Cs[Eu(L24)₄]	594		⁵D₀→⁷F₁	±0.15		[61]
Cs[Eu(L25)₄]	594		⁵D₀→⁷F₁	±0.15		[61]
Cs[Eu(L25)₄]	594		⁵D₀→⁷F₁	±0.82		[61]
[Eu(L27)₃]³⁺	590.5, 595.3, 615.6		⁵D₀→⁷F_J	±0.19, ±0.18 (ΔJ=1) ±0.21 (ΔJ=2)		[63]
Eu(L30)₃	600, 619			±0.13, ±0.06		[64]
[Eu(L32)₂]³⁺	593			±0.12		[65]
[Eu(L33)₂]³⁺	592.2, 616.2	17		±0.18, ±0.03		[66]
[Eu(L34)₃]³⁺		4	⁵D₀→⁷F₁	±0.028, ±0.020		[67]
Eu(L37)₂(OTf)₃	593		⁵D₀→⁷F₁	±0.120		[68]
Eu^SL62	595, 600, 658, 708, 713	11	⁵D₀→⁷F_J	+0.18, +0.33, –0.25, +0.31, –0.37		[69]
EuL63	557, 599, 655, 708	47	⁵D₀→⁷F_J	±0.19, ±0.15, ±0.19, ±0.32		[70]
[Tb^SL1]³⁺	545, 620	25	⁵D₄→⁷F_J	–0.25 (ΔJ=–1), +0.29(ΔJ=+1)		[44,45]
[Tb^RL4]³⁺		49/H₂O 81/D₂O				[45]
[Tb^SL6]³⁺	545	36/H₂O 46/D₂O	⁵D₄→⁷F₅		+0.12	[47]
[Tb^SL6']³⁺	489, 540, 583		⁵D₄→⁷F_J		+0.02, –0.13, +0.01	[48]
[Tb^SL12]^–	542.5, 551		⁵D₄→⁷F₅		0.285, 0.173	[51]
[Tb^SL13]^–	542.5, 551		⁵D₄→⁷F₅		0.241, 0.151	[51]
[Tb^RL14]⁺	543	63	⁵D₄→⁷F₅		+0.044	[53]
TbL15	545.8, 551	57	⁵D₄→⁷F₅		±0.078, ±0.051	[54]
TbL16	542.0, 545.6, 551.2	30	⁵D₄→⁷F₅		±0.14, ±0.34, ±0.40	[26]
[Tb^RRL17]³⁺			⁵D₄→⁷F₅		–0.19	[55]
[Tb^RL18]³⁺	540		⁵D₄→⁷F₅		–0.01, +0.06, –0.02	[56]
[TbL20]⁺	546		⁵D₄→⁷F₅		±0.01 (ΔJ=1)	[58]
[Tb(^RL26)₃]³⁺	542	1.2	⁵D₄→⁷F₅		0.02	[62]
[Tb(L29)₃]³⁺	546		⁵D₄→⁷F₅		±0.05	[71]
[Tb(L31)₃]³⁺	542				±0.14	[65]
[Tb(L34)₃]³⁺		0.022	⁵D₄→⁷F₅		±0.06	[67]
Tb(L35)₃Na₃(thf)₆	524	26	⁵D₄→⁷F₅		±0.32	[72]
Tb(L36)₃Na₃(thf)₆	545	84.6	⁵D₄→⁷F₅		±0.53	[73]
Tb^SL62	539, 543, 548, 620, 622	50	⁵D₄→⁷F_J		+0.16, –0.25, +0.32, +0.28, –0.32	[69]
[Dy^RL1]³⁺	657, 667		⁴F_9/2→⁶H_11/2		0.35, –0.41	[45]
[Dy^RL14]⁺	669	1.3	⁴F_9/2→⁶H_11/2		+0.013	[53]
Dy(L35)₃Na₃(thf)₆	756	17	⁴F_9/2→⁶H_9/2		±0.33	[72]
Dy(L36)₃Na₃(thf)₆	760	15.5	⁴F_9/2→⁶H_9/2		±0.53	[73]
[Sm^RL14]⁺	565, 597	0.8	⁴G_5/2→⁶H_7/2 ⁴G_5/2→⁶H_5/2		–0.027, –0.028	[53]
Cs[Sm(+L24)₄]	553, 561, 575, 588, 598, 605, 611, 617		⁴G_5/2→⁶H_J		–1.15, –0.35, +0.96 (ΔJ=0) –0.45, +1.15, –0.76, +0.24, +0.15 (ΔJ=1)	[18]
[Sm(L29)₃]³⁺	560, 600				±0.5, ±0.28	[74]
Sm(L35)₃Na₃(thf)₆	603	4	⁴G_5/2→⁶H_7/2		±0.44	[72]
Sm(L36)₃Na₃(thf)₆	610	2.8	⁴G_5/2→⁶H_7/2		±0.50	[73]
Sm(L37)₂(OTf)₃	559		⁴G_5/2→⁶H_5/2		±0.272	[68]

化合物	λ_em/nm	PLQY/%	跃迁	g_lum		文献
[EuL1]³⁺		0.06/H₂O 0.3/D₂O				[45]
[Eu^RL4]³⁺	588, 593, 615, 668, 687		⁵D₀→⁷F_J	+0.02, –0.03 (ΔJ=1), 0.12, 0.4, –0.11 (ΔJ=2,3,4)		[45]
[Eu^RL5]³⁺	580, 590, 615, 650, 680		⁵D₀→⁷F_J	–0.12, +0.18 (ΔJ=1） –0.1, –0.3, –0.11 (ΔJ=2,3,4)		[46]
[Eu^SL6]³⁺	588, 595, 614	21/H₂O 27/D₂O	⁵D₀→⁷F_J	+0.18, –0.16 (ΔJ=1), –0.04 (ΔJ=2)		[47]
[Eu^SL7]^–	591, 657	14/H₂O/MeOH 47/DMSO	⁵D₀→⁷F_J	–0.18 (ΔJ=1) +0.17 (ΔJ=3)		[50]
[Eu^RL7]^–	591, 657	14.9/H₂O/MeOH 53/DMSO	⁵D₀→⁷F_J	+0.17 (ΔJ=1) +0.13 (ΔJ=3)		[50]
[Eu^SL8]^–	591, 657	11/H₂O/MeOH 0.45/DMSO	⁵D₀→⁷F_J	–0.11 (ΔJ=1) –0.12 (ΔJ=3)		[50]
[Eu^SL9]^–	591, 657	0.40/DMSO	⁵D₀→⁷F_J	+0.30 (ΔJ=1) +0.25 (ΔJ=3)		[50]
[Eu^SL10]^–	591, 653	10.2/H₂O/MeOH 44.1/DMSO	⁵D₀→⁷F_J	–0.11 (ΔJ=1) –0.10 (ΔJ=3)		[50]
[Eu^SL11]^–	588, 657	21.9/H₂O/MeOH 49.7/DMSO	⁵D₀→⁷F_J	–0.17 (ΔJ=1) –0.29 (ΔJ=3)		[50]
[Eu^RL14]⁺	596	2.3	⁵D₀→⁷F₁	+0.298		[53]
EuL15	586.6, 594.2, 543.6	7.7	⁵D₀→⁷F₁	±0.046, ±0.12, ±0.083		[54]
[Eu^RRL17]³⁺			⁵D₀→⁷F₁ ⁵D₀→⁷F₄	–0.19, –0.22		[55]
[Eu^RL18]³⁺	590		⁵D₀→⁷F₁	+0.02		[56]
[Eu^RL19-Me]²⁺	587	55		1.7×10^–3		[57]
[Eu^RL19-ⁱPr]²⁺	560	53		1.8×10^–3		[57]
[EuL20]⁺	598, 607		⁵D₀→⁷F_J	±0.2 (ΔJ=1), ±0.2 (ΔJ=2)		[58]
Eu(+L23)₃	588.2			–0.78		[59]
Eu(+L24)₃	612		⁵D₀→⁷F₂	+0.003		[15]
Cs[Eu(+L24)₄]	595, 612		⁵D₀→⁷F_J	+1.38 (ΔJ=1) –0.23 (ΔJ=2)		[15]
Cs[Eu(+L24)₄]	595, 612		⁵D₀→⁷F_J	+1.32 (ΔJ=1) –0.19 (ΔJ=2)		[15]
Na[Eu(+L24)₄]	595, 612		⁵D₀→⁷F_J	+0.06 (ΔJ=1) –0.01 (ΔJ=2)		[15]
Cs[Eu(L24)₄]	594		⁵D₀→⁷F₁	±0.15		[61]
Cs[Eu(L25)₄]	594		⁵D₀→⁷F₁	±0.15		[61]
Cs[Eu(L25)₄]	594		⁵D₀→⁷F₁	±0.82		[61]
[Eu(L27)₃]³⁺	590.5, 595.3, 615.6		⁵D₀→⁷F_J	±0.19, ±0.18 (ΔJ=1) ±0.21 (ΔJ=2)		[63]
Eu(L30)₃	600, 619			±0.13, ±0.06		[64]
[Eu(L32)₂]³⁺	593			±0.12		[65]
[Eu(L33)₂]³⁺	592.2, 616.2	17		±0.18, ±0.03		[66]
[Eu(L34)₃]³⁺		4	⁵D₀→⁷F₁	±0.028, ±0.020		[67]
Eu(L37)₂(OTf)₃	593		⁵D₀→⁷F₁	±0.120		[68]
Eu^SL62	595, 600, 658, 708, 713	11	⁵D₀→⁷F_J	+0.18, +0.33, –0.25, +0.31, –0.37		[69]
EuL63	557, 599, 655, 708	47	⁵D₀→⁷F_J	±0.19, ±0.15, ±0.19, ±0.32		[70]
[Tb^SL1]³⁺	545, 620	25	⁵D₄→⁷F_J	–0.25 (ΔJ=–1), +0.29(ΔJ=+1)		[44,45]
[Tb^RL4]³⁺		49/H₂O 81/D₂O				[45]
[Tb^SL6]³⁺	545	36/H₂O 46/D₂O	⁵D₄→⁷F₅		+0.12	[47]
[Tb^SL6']³⁺	489, 540, 583		⁵D₄→⁷F_J		+0.02, –0.13, +0.01	[48]
[Tb^SL12]^–	542.5, 551		⁵D₄→⁷F₅		0.285, 0.173	[51]
[Tb^SL13]^–	542.5, 551		⁵D₄→⁷F₅		0.241, 0.151	[51]
[Tb^RL14]⁺	543	63	⁵D₄→⁷F₅		+0.044	[53]
TbL15	545.8, 551	57	⁵D₄→⁷F₅		±0.078, ±0.051	[54]
TbL16	542.0, 545.6, 551.2	30	⁵D₄→⁷F₅		±0.14, ±0.34, ±0.40	[26]
[Tb^RRL17]³⁺			⁵D₄→⁷F₅		–0.19	[55]
[Tb^RL18]³⁺	540		⁵D₄→⁷F₅		–0.01, +0.06, –0.02	[56]
[TbL20]⁺	546		⁵D₄→⁷F₅		±0.01 (ΔJ=1)	[58]
[Tb(^RL26)₃]³⁺	542	1.2	⁵D₄→⁷F₅		0.02	[62]
[Tb(L29)₃]³⁺	546		⁵D₄→⁷F₅		±0.05	[71]
[Tb(L31)₃]³⁺	542				±0.14	[65]
[Tb(L34)₃]³⁺		0.022	⁵D₄→⁷F₅		±0.06	[67]
Tb(L35)₃Na₃(thf)₆	524	26	⁵D₄→⁷F₅		±0.32	[72]
Tb(L36)₃Na₃(thf)₆	545	84.6	⁵D₄→⁷F₅		±0.53	[73]
Tb^SL62	539, 543, 548, 620, 622	50	⁵D₄→⁷F_J		+0.16, –0.25, +0.32, +0.28, –0.32	[69]
[Dy^RL1]³⁺	657, 667		⁴F_9/2→⁶H_11/2		0.35, –0.41	[45]
[Dy^RL14]⁺	669	1.3	⁴F_9/2→⁶H_11/2		+0.013	[53]
Dy(L35)₃Na₃(thf)₆	756	17	⁴F_9/2→⁶H_9/2		±0.33	[72]
Dy(L36)₃Na₃(thf)₆	760	15.5	⁴F_9/2→⁶H_9/2		±0.53	[73]
[Sm^RL14]⁺	565, 597	0.8	⁴G_5/2→⁶H_7/2 ⁴G_5/2→⁶H_5/2		–0.027, –0.028	[53]
Cs[Sm(+L24)₄]	553, 561, 575, 588, 598, 605, 611, 617		⁴G_5/2→⁶H_J		–1.15, –0.35, +0.96 (ΔJ=0) –0.45, +1.15, –0.76, +0.24, +0.15 (ΔJ=1)	[18]
[Sm(L29)₃]³⁺	560, 600				±0.5, ±0.28	[74]
Sm(L35)₃Na₃(thf)₆	603	4	⁴G_5/2→⁶H_7/2		±0.44	[72]
Sm(L36)₃Na₃(thf)₆	610	2.8	⁴G_5/2→⁶H_7/2		±0.50	[73]
Sm(L37)₂(OTf)₃	559		⁴G_5/2→⁶H_5/2		±0.272	[68]

Table 1. The circularly polarized luminescence of some mononuclear rare-earth complexes

Figure 2. Structures of some chiral ML mononuclear coordination complexes (only one chiral structure of the ligands is illustrated)

Figure 3. Structures of some chiral and achiral ligands that have been used to construct chiral MLn mononuclear rare-earth complexes (only one chiral structure of the ligands is illustrated)

Figure 4. Structures of some ligands that have been used to synthesis chiral rare earth-based supermolecular assemblies. (b) Synthesis of [Eu2(L41)3]6+, luminescence spectrum and CPL spectra of [Eu2(L41)3]6+.[78] Reproduced with permission from Ref. [78]. Copyright 2009, American Chemical Society. (c) Synthesis of [Eu2(L58)4]2–.[79] Reproduced with permission from Ref. [79]. Copyright 2020, American Chemical Society. (d) Synthesis of [Eu3(SL60)6]3+ and wheel-like [Eu?(Δ-Eu(SL60)2Λ-Eu(SL60)2)3]9+.[80] Reproduced with permission from Ref. [80]. Copyright 2012, American Chemical Society

Figure 5. (a) Reaction scheme of D4-symmetrical [R/SL32]8Ln8(thp)8.[1] Reproduced with permission from Ref. [1]. Copyright 2020, American Chemical Society. (b) Syntheses of the tetrahedral cages of Δ/Λ-Eu4(tdtp)4(R/SL37)4 and their CPL spectra in CHCl3.[103] Reproduced with permission from Ref. [103]. Copyright 2019, American Chemical Society. (c) Guest-driven self-assembly/transformation showing chiral induction of Eu4L4 tetrahedral cages, the chemical structures of chiral induction molecules, and the CPL spectra of chiral Eu4L4 cages.[104] Reproduced with permission from Ref. [104]. Copyright 2022, American Chemical Society.

Figure 6. (a) TEM images of the aggregates formed from M[Eu(L24)4] (M=Na, K, Rb, Cs), CD, UV-vis absorption, CPL, and emission spectra of M[Eu(L24)4] (M=Na, K, Rb, Cs).[16] Reproduced with permission from Ref. [16]. Copyright 2016, The Royal Society of Chemistry. (b) The conceptual design of a chiral Eu-based coordination polymer and the chemical structures of the chiral coordination polymers.[110] Reproduced with permission from Ref. [110]. Copyright 2023, The Royal Society of Chemistry. (c) Crystal structures of (S/RM3HQ)2RbEu(NO3)6 and the CPL spectra of the crystal and powder samples.[111] Reproduced with permission from Ref. [111]. Copyright 2022, The Royal Society of Chemistry

Figure 7. (a) Synthesis of (RBinol)3LnNa3 and normalized CPL spectra of (R/SBinol)3LnNa3 in tetrahydrofuran solutions.[19] Reproduced with permission from Ref. [19]. Copyright 2022, American Chemical Society. (b) Structure of [Er(dpe-pybox)2]3+ and NIR-CPL spectra of enantiomers of [Er(dpe-pybox)2]3+ in deuterated chloroform.[127] Reproduced with permission from Ref. [127]. Copyright 2022, Wiley-VCH. (c) Synthesis of (R/S-Spinol)3LnNa3(thf)6 and CPL spectra of (R/S-Spinol)3SmNa3(thf)6 in tetrahydrofuran solutions.[73] Reproduced with permission from Ref. [73]. Copyright 2022, American Chemical Society. (d) The structures of [Eu(pi-pybox)2]3+ and [Eu(pp-pybox)3]3+, and the two-photon excitation CPL spectra of [Eu(pp-pybox)3]3+.[128] Reproduced with permission from Ref. [128]. Copyright 2023, American Chemical Society. (e) Structures of R-Vanol and [Ln(pc)]Cl

Figure 8. (a) Structures of some chiral mononuclear rare earth complexes and chiral ligands. (b) Chemical structures, ORTEP and space-filling (bottom) views of [(Eu(R-L)(hfa)3] (L=L31, L32, L64).[129] Reproduced with permission from Ref. [129]. Copyright 2011, American Chemical Society. (c) Schematic representation of a plausible reason to explain the different extent of chiral optical intensity of [Eu4L6]12+(L=L50, L54, L56) complexes and the corresponding CD and CPL spectra. (d) Schematic diagram of chiral amplification experiment of Eu4(RRL50)n(L67)6–n(OTf)12 (n=0~6) tetrahedral cage, normalized CD (top) and normalized UV-Vis absorption spectra of Eu4(RRL50)n(L67)6–n(OTf)12 and plots of normalized CD intensities as a function of the contents of the ligands.[108] Reproduced with permission from Ref. [108]. Copyright 2017, Nature Publishing Group. (e) Process of self-assembly and chiral amplification in Eu4L4 tetrahedral cages.[130] Reproduced with permission from Ref. [130]. Copyright 2023, Wiley-VCH

Figure 9. (a) Reversible photo-switching reaction of 1(Eu)-o and 1(Eu)-c and CPL spectral changes before and after photoirradiation.[119] Reproduced with permission from Ref. [119]. Copyright 2018, American Chemical Society. (b) Optimized structures of [Eu2(L52)3]6+.[147] Reproduced with permission from Ref. [147]. Copyright 2018, The Royal Society of Chemistry. (c) Molecular structures of EuL (L=L69~L75).[148] Reproduced with permission from Ref. [148]. Copyright 2021, Wiley-VCH. (d) Molecular structures of the emitting and carrier-transporting layers of the CP-OLED device.[149] Reproduced with permission from Ref. [149]. Copyright 2015, Wiley-VCH. (e) Self-assembly of the CPL-emitting Eu4(L76)4 tetrahedral cage and structures of chiral amines and amino alcohol tested.[150] Reproduced with permission from Ref. [150]. Copyright 2022, American Chemical Society. (f) Photographs and images of the films of Eu(±L23)-tmpo(2) prepared on glasses under UV-light.[151] Reproduced with permission from Ref. [151]. Copyright 2020, Nature Publishing Group

References 176

[1]	Tan, Y. B.; Okayasu, Y.; Katao, S.; Nishikawa, Y.; Asanoma, F.; Yamada, M.; Yuasa, J.; Kawai, T. J. Am. Chem. Soc. 2020, 142, 17653.
[2]	Zhang, M.; Guo, Q.; Li, Z.; Zhou, Y.; Zhao, S.; Tong, Z.; Wang, Y.; Li, G.; Jin, S.; Zhu, M.; Zhuang, T.; Yu, S.-H. Sci. Adv. 2023, 9, eadi9944.
[3]	Luo, J.; Lin, T.; Zhang, J.; Chen, X.; Blackert, E. R.; Xu, R.; Yakobson, B. I.; Zhu, H. Science 2023, 382, 698.
[4]	Cui, Y.; Chen, B.; Qian, G. Coord. Chem. Rev. 2014, 273-274, 76.
[5]	Xu, L.-J.; Xu, G.-T.; Chen, Z.-N. Coord. Chem. Rev. 2014, 273-274, 47.
[6]	Liu, Z.; Wang, Y.-X.; Fang, Y.-H.; Qin, S.-X.; Wang, Z.-M.; Jiang, S.-D.; Gao, S. Nat. Sci. Rev. 2020, 7, 1557.
[7]	Su, P.-R.; Wang, T.; Zhou, P.-P.; Yang, X.-X.; Feng, X.-X.; Zhang, M.-N.; Liang, L.-J.; Tang, Y.; Yan, C.-H. Nat. Sci. Rev. 2021, 9, nwab016.
[8]	Hu, S.-J.; Guo, X.-Q.; Zhou, L.-P.; Cai, L.-X.; Sun, Q.-F. Chin. J. Chem. 2019, 37, 657.
[9]	Carr, R.; Evans, N. H.; Parker, D. Chem. Soc. Rev. 2012, 41, 7673.
[10]	Gong, Z.-L.; Zhu, X.; Zhou, Z.; Zhang, S.-W.; Yang, D.; Zhao, B.; Zhang, Y.-P.; Deng, J.; Cheng, Y.; Zheng, Y.-X.; Zang, S.-Q.; Kuang, H.; Duan, P.; Yuan, M.; Chen, C.-F.; Zhao, Y. S.; Zhong, Y.-W.; Tang, B. Z.; Liu, M. Sci. China Chem. 2021, 64, 2060.
[11]	Luo, X.-Y.; Pan, M. Coord. Chem. Rev. 2022, 468, 214640.
[12]	Zhong, Y.; Wu, Z.; Zhang, Y.; Dong, B.; Bai, X. InfoMat 2022, 5, e12392.
[13]	Zhang, Y.; Yu, S.; Han, B.; Zhou, Y.; Zhang, X.; Gao, X.; Tang, Z. Matter 2022, 5, 837.
[14]	Richardson, S., F. Inorg. Chem. 1980, 19, 2806.
[15]	Lunkley, J. L.; Shirotani, D.; Yamanari, K.; Kaizaki, S.; Muller, G. J. Am. Chem. Soc. 2008, 130, 13814. doi: 10.1021/ja805681w pmid: 18816117
[16]	Kumar, J.; Marydasan, B.; Nakashima, T.; Kawai, T.; Yuasa, J. Chem. Commun. 2016, 52, 9885.
[17]	Schnable, D.; Freedman, K.; Ayers, K. M.; Schley, N. D.; Kol, M.; Ung, G. Inorg. Chem. 2020, 59, 8498. doi: 10.1021/acs.inorgchem.0c00946 pmid: 32469213
[18]	Lunkley, J. L.; Shirotani, D.; Yamanari, K.; Kaizaki, S.; Muller, G. Inorg. Chem. 2011, 50, 12724. doi: 10.1021/ic201851r pmid: 22074461
[19]	Mukthar, N. F. M.; Schley, N. D.; Ung, G. J. Am. Chem. Soc. 2022, 144, 6148. doi: 10.1021/jacs.2c01134 pmid: 35377146
[20]	Arrico, L.; Di Bari, L.; Zinna, F. Chem. - Eur. J. 2021, 27, 2920.
[21]	Dee, C.; Zinna, F.; Kitzmann, W. R.; Pescitelli, G.; Heinze, K.; Di Bari, L.; Seitz, M. Chem. Commun. 2019, 55, 13078.
[22]	Piguet, C.; Bünzli, J.-C. G. In Handbook on the Physics and Chemistry of Rare Earths, Vol. 40, Elsevier, Amsterdam, The Netherlands, 2010, p. 301.
[23]	Bunzli, J.-C. G.; Piguet, C. Chem. Soc. Rev. 2005, 34, 1048.
[24]	Zhou, W.-L.; Chen, Y.; Liu, Y. Acta Chim. Sinica 2020, 78, 1164. (in Chinese)
	(周维磊, 陈湧, 刘育, 化学学报, 2020, 78, 1164.) doi: 10.6023/A20100486
[25]	Wang, J.; Li, X.; Chu, H.; He, J.; Chen, Z. Chin. J. Org. Chem. 2019, 39, 3399. (in Chinese)
	(王军, 李小成, 初红涛, 何进军, 陈志娇, 有机化学, 2019, 39, 3399.) doi: 10.6023/cjoc201904016
[26]	Seitz, M.; Do, K.; Ingram, A. J.; Moore, E. G.; Muller, G.; Raymond, K. N. Inorg. Chem. 2009, 48, 8469.
[27]	Zhu, Q.-Y.; Zhou, L.-P.; Cai, L.-X.; Li, X.-Z.; Zhou, J.; Sun, Q.-F. Chem. Commun. 2020, 56, 2861.
[28]	Ning, Y.; Ke, X.-S.; Hu, J.-Y.; Liu, Y.-W.; Ma, F.; Sun, H.-L.; Zhang, J.-L. Inorg. Chem. 2017, 56, 1897.
[29]	Zhang, M.; Zheng, W.; Liu, Y.; Huang, P.; Gong, Z.; Wei, J.; Gao, Y.; Zhou, S.; Li, X.; Chen, X. Angew. Chem., Int. Ed. 2019, 58, 9556.
[30]	Wu, Z.; Ke, J.; Liu, Y.; Sun, P.; Hong, M. Acta Chim. Sinica 2022, 80, 542. (in Chinese)
	(吴志芬, 柯建熙, 刘永升, 孙蓬明, 洪茂椿, 化学学报, 2022, 80, 542.) doi: 10.6023/A21120571
[31]	Li, X.-Z.; Tian, C.-B.; Sun, Q.-F. Chem. Rev. 2022, 122, 6374.
[32]	Yan, B. Acc. Chem. Res. 2017, 50, 2789.
[33]	Qin, Y.; Ge, Y.; Zhang, S.; Sun, H.; Jing, Y.; Li, Y.; Liu, W. RSC Adv. 2018, 8, 12641.
[34]	Yang, D.; Wang, Y.; Liu, D.; Li, Z.; Li, H. J. Mater. Chem. C 2018, 6, 1944.
[35]	Jia, J.-H.; Li, Q.-W.; Chen, Y.-C.; Liu, J.-L.; Tong, M.-L. Coord. Chem. Rev. 2019, 378, 365.
[36]	Jiang, L.; Li, J.; Xia, D.; Gao, M.; Li, W.; Fu, D.-Y.; Zhao, S.; Li, G. ACS Appl. Mater. Inter. 2021, 13, 49462.
[37]	Tang, X.; Chu, D.; Gong, W.; Cui, Y.; Liu, Y. Angew. Chem., Int. Ed. 2021, 60, 9099.
[38]	Huang, W.; Chen, W.; Bai, Q.; Zhang, Z.; Feng, M.; Zheng, Z. Angew. Chem., Int. Ed. 2022, 61, e202205385.
[39]	Zhang, P.; Luo, Q.-C.; Zhu, Z.; He, W.; Song, N.; Lv, J.; Wang, X.; Zhai, Q.-G.; Zheng, Y.-Z.; Tang, J. Angew. Chem., Int. Ed. 2023, 62, e202218540.
[40]	Liu, S.; Liu, W.; Chen, C.; Sun, Y.; Bai, S.; Liu, W. Inorg. Chem. 2024, 63, 1725.
[41]	Wang, Y.; Yan, J. Acta Chim. Sinica 2023, 81, 275. (in Chinese)
	(汪阳, 阎敬灵, 化学学报, 2023, 81, 275.) doi: 10.6023/A23010004
[42]	Guan, Y.; Chang, K.; Sun, Q.; Xu, X. Chin. J. Org. Chem. 2022, 42, 1326. (in Chinese)
	(管怡雯, 常克俭, 孙千林, 徐信, 有机化学, 2022, 42, 1326.) doi: 10.6023/cjoc202112008
[43]	Woods, M.; Kovacs, Z.; Zhang, S.; Sherry, A. D. Angew. Chem. Int. Ed. 2003, 42, 5889.
[44]	Dickins, R. S.; Howard, J. A. K.; Lehmann, C. W.; Moloney, J.; Parker, D.; Peacock, R. D. Angew. Chem., Int. Ed. 1997, 36, 521.
[45]	Dickins, R. S.; Howard, J. A. K.; Maupin, C. L.; Moloney, J. M.; Parker, D.; Riehl, J. P.; Siligardi, G.; Williams, J. A. G. Chem. Eur. J. 1999, 5, 1095.
[46]	Dickins, R. S.; Howard, J. A. K.; Moloney, J. M.; Parker, D.; Peacock, R. D.; Siligardi, G. Chem. Commun. 1997, 1747.
[47]	Poole, R. A.; Bobba, G.; Cann, M. J.; Frias, J.-C.; Parker, D.; Peacock, R. D. Org. Biomol. Chem. 2005, 3, 1013.
[48]	Montgomery, C. P.; Parker, D.; Lamarque, L. Chem. Commun. 2007, 3841.
[49]	Dai, L.; Jones, C. M.; Chan, W. T. K.; Pham, T. A.; Ling, X.; Gale, E. M.; Rotile, N. J.; Tai, W. C.-S.; Anderson, C. J.; Caravan, P.; Law, G.-L. Nat. Commun. 2018, 9, 857.
[50]	Dai, L.; Lo, W.-S.; Coates, I. D.; Pal, R.; Law, G.-L. Inorg. Chem. 2016, 55, 9065.
[51]	Dai, L.; Zhang, J.; Chen, Y.; Mackenzie, L. E.; Pal, R.; Law, G.-L. Inorg. Chem. 2019, 58, 12506.
[52]	Petoud, S.; Cohen, S. M.; Bünzli, J.-C. G.; Raymond, K. N. J. Am. Chem. Soc. 2003, 125, 13324.
[53]	Petoud, S.; Muller, G.; Moore, E. G.; Xu, J.; Sokolnicki, J.; Riehl, J. P.; Le, U. N.; Cohen, S. M.; Raymond, K. N. J. Am. Chem. Soc. 2007, 129, 77.
[54]	Seitz, M.; Moore, E. G.; Ingram, A. J.; Muller, G.; Raymond, K. N. J. Am. Chem. Soc. 2007, 129, 15468.
[55]	Tsubomura, T.; Yasaku, K.; Sato, T.; Morita, M. Inorg. Chem. 1992, 31, 447.
[56]	Gregolinski, J.; Starynowicz, P.; Hua, K. T.; Lunkley, J. L.; Muller, G.; Lisowski, J. J. Am. Chem. Soc. 2008, 130, 17761.
[57]	Qi, H.; Huo, P.; Han, B.; Zheng, J.; Wang, L.; Yan, W.; Guo, R.; Li, T.; Yu, K.; Liu, Z.; Bian, Z. Cell Rep. Phys. Sci. 2022, 3, 101107.
[58]	Leonzio, M.; Melchior, A.; Faura, G.; Tolazzi, M.; Zinna, F.; Di Bari, L.; Piccinelli, F. Inorg. Chem. 2017, 56, 4413. doi: 10.1021/acs.inorgchem.7b00430 pmid: 28388073
[59]	Brittain, H. G.; Richardson, F. S. J. Am. Chem. Soc. 1976, 98, 5858.
[60]	Di Pietro, S.; Di Bari, L. Inorg. Chem. 2012, 51, 12007.
[61]	Zinna, F.; Resta, C.; Abbate, S.; Castiglioni, E.; Longhi, G.; Mineo, P.; Di Bari, L. Chem. Commun. 2015, 51, 11903.
[62]	Muller, G.; Schmidt, B.; Jiricek, J.; Hopfgartner, G.; Riehl, J. P.; Bünzli, J.-C. G.; Piguet, C. J. Chem. Soc., Dalton Trans. 2001, 2655.
[63]	Bonsall, S. D.; Houcheime, M.; Straus, D. A.; Muller, G. Chem. Commun. 2007, 3676.
[64]	Lincheneau, C.; Destribats, C.; Barry, D. E.; Kitchen, J. A.; Peacock, R. D.; Gunnlaugsson, T. Dalton Trans. 2011, 40, 12056.
[65]	Arrico, L.; Benetti, C.; Di Bari, L. ChemPhotoChem 2021, 5, 815.
[66]	Matsumoto, K.; Suzuki, K.; Tsukuda, T.; Tsubomura, T. Inorg. Chem. 2010, 49, 4717. doi: 10.1021/ic901743q pmid: 20438091
[67]	Muller, G.; Bünzli, J.-C. G.; Riehl, J. P.; Suhr, D.; Zelewsky, A.; Mürner, H. Chem. Commun. 2002, 1522.
[68]	Cotter, D.; Dodder, S.; Klimkowski, V. J.; Hopkins, T. A. Chirality 2019, 31, 301.
[69]	Walton, J. W.; Bari, L. D.; Parker, D.; Pescitelli, G.; Puschmann, H.; Yufit, D. S. Chem. Commun. 2011, 47, 12289.
[70]	Frawley, A. T.; Pal, R.; Parker, D. Chem. Commun. 2016, 52, 13349.
[71]	Homberg, A.; Navazio, F.; Le Tellier, A.; Zinna, F.; Fürstenberg, A.; Besnard, C.; Di Bari, L.; Lacour, J. Dalton Trans. 2022, 51, 16479.
[72]	Deng, M.; Schley, N. D.; Ung, G. Chem. Commun. 2020, 56, 14813.
[73]	Willis, B.-A. N.; Schnable, D.; Schley, N. D.; Ung, G. J. Am. Chem. Soc. 2022, 144, 22421.
[74]	Leonard, J. P.; Jensen, P.; McCabe, T.; O'Brien, J. E.; Peacock, R. D.; Kruger, P. E.; Gunnlaugsson, T. J. Am. Chem. Soc. 2007, 129, 10986. pmid: 17696537
[75]	Starck, M.; MacKenzie, L. E.; Batsanov, A. S.; Parker, D.; Pal, R. Chem. Commun. 2019, 55, 14115.
[76]	Muller, G.; Bünzli, J.-C. G.; Schenk, K. J.; Piguet, C.; Hopfgartner, G. Inorg. Chem. 2001, 40, 2642. pmid: 11375674
[77]	Liu, B.; Chen, P. Acta Chim. Sinica 2022, 80, 929. (in Chinese)
	(刘斌, 陈磅宽, 化学学报, 2022, 80, 929.) doi: 10.6023/A22030122
[78]	Stomeo, F.; Lincheneau, C.; Leonard, J. P.; O’Brien, J. E.; Peacock, R. D.; McCoy, C. P.; Gunnlaugsson, T. J. Am. Chem. Soc. 2009, 131, 9636.
[79]	Zhou, Y.; Yao, Y.; Cheng, Z.; Gao, T.; Li, H.; Yan, P. Inorg. Chem. 2020, 59, 12850.
[80]	Bozoklu, G.; Gateau, C.; Imbert, D.; Pécaut, J.; Robeyns, K.; Filinchuk, Y.; Memon, F.; Muller, G.; Mazzanti, M. J. Am. Chem. Soc. 2012, 134, 8372. doi: 10.1021/ja3020814 pmid: 22548280
[81]	Harada, T.; Hasegawa, Y.; Nakano, Y.; Fujiki, M.; Naito, M.; Wada, T.; Inoue, Y.; Kawai, T. J. Alloy. Compd. 2009, 488, 599.
[82]	Harada, T.; Nakano, Y.; Fujiki, M.; Naito, M.; Kawai, T.; Hasegawa, Y. Inorg. Chem. 2009, 48, 11242.
[83]	Kono, Y.; Hara, N.; Shizuma, M.; Fujiki, M.; Imai, Y. Dalton Trans. 2017, 46, 5170.
[84]	Taniguchi, A.; Hara, N.; Shizuma, M.; Tajima, N.; Fujiki, M.; Imai, Y. Photoch. Photobio. Sci. 2019, 18, 2859.
[85]	Harada, T.; Tsumatori, H.; Nishiyama, K.; Yuasa, J.; Hasegawa, Y.; Kawai, T. Inorg. Chem. 2012, 51, 6476.
[86]	Okayasu, Y.; Yuasa, J. Molecul. Syst. Des. Eng. 2018, 3, 66.
[87]	Górecki, M.; Carpita, L.; Arrico, L.; Zinna, F.; Di Bari, L. Dalton Trans. 2018, 47, 7166. doi: 10.1039/c8dt00865e pmid: 29774898
[88]	Zinna, F.; Arrico, L.; Di Bari, L. Chem. Commun. 2019, 55, 6607.
[89]	Abhervé, A.; Mastropasqua Talamo, M.; Vanthuyne, N.; Zinna, F.; Di Bari, L.; Grasser, M.; Le Guennic, B.; Avarvari, N. Eur. J. Inorg. Chem. 2022, 2022, e202200010.
[90]	Dhbaibi, K.; Grasser, M.; Douib, H.; Dorcet, V.; Cador, O.; Vanthuyne, N.; Riobé, F.; Maury, O.; Guy, S.; Bensalah-Ledoux, A.; Baguenard, B.; Rikken, G. L. J. A.; Train, C.; Le Guennic, B.; Atzori, M.; Pointillart, F.; Crassous, J. Angew. Chem., Int. Ed. 2023, 62, e202215558.
[91]	Cavalli, E.; Nardon, C.; Willis, O. G.; Zinna, F.; Di Bari, L.; Mizzoni, S.; Ruggieri, S.; Gaglio, S. C.; Perduca, M.; Zaccone, C.; Romeo, A.; Piccinelli, F. Chem. - Eur. J. 2022, 28, e202200574.
[92]	Ruggieri, S.; Mizzoni, S.; Nardon, C.; Cavalli, E.; Sissa, C.; Anselmi, M.; Cozzi, P. G.; Gualandi, A.; Sanadar, M.; Melchior, A.; Zinna, F.; Willis, O. G.; Di Bari, L.; Piccinelli, F. Inorg. Chem. 2023, 62, 8812. doi: 10.1021/acs.inorgchem.3c00196 pmid: 37262334
[93]	Leonzio, M.; Bettinelli, M.; Arrico, L.; Monari, M.; Di Bari, L.; Piccinelli, F. Inorg. Chem. 2018, 57, 10257. doi: 10.1021/acs.inorgchem.8b01480 pmid: 30080030
[94]	Yin, S.; Li, X.; Wang, H.; Li, J.; Huang, W.; Gao, T.; Yan, P.; Zhou, Y.; Li, H. CrystEngComm 2023, 25, 1541.
[95]	Brittain, H.; Richardson, F. J. Am. Chem. Soc. 1977, 99, 65.
[96]	Yao, M.-X.; Cai, L.-Z.; Deng, X.-W.; Zhang, W.; Liu, S.-J.; Cai, X.-M. New J. Chem. 2018, 42, 17652.
[97]	Zheng, X.-Y.; Xie, J.; Kong, X.-J.; Long, L.-S.; Zheng, L.-S. Coord. Chem. Rev. 2019, 378, 222.
[98]	Sun, Q.-F.; Li, X.-Z. Chin. J. Lumin. 2020, 41, 770. (in Chinese)
	(孙庆福, 李小贞, 发光学报, 2020, 41, 770.)
[99]	Song, L.; Zhou, Y.; Gao, T.; Yan, P.; Li, H. Acta Chim. Sinica 2021, 79, 1042. (in Chinese)
	(宋龙飞, 周妍妍, 高婷, 闫鹏飞, 李洪峰, 化学学报, 2021, 79, 1042.) doi: 10.6023/A21040185
[100]	Yan, L.-L.; Tan, C.-H.; Zhang, G.-L.; Zhou, L.-P.; Bünzli, J.-C.; Sun, Q.-F. J. Am. Chem. Soc. 2015, 137, 8550.
[101]	Li, X.-Z.; Zhou, L.-P.; Yan, L.-L.; Yuan, D.-Q.; Lin, C.-S.; Sun, Q.-F. J. Am. Chem. Soc. 2017, 139, 8237.
[102]	Cantuel, M.; Bernardinelli, G.; Muller, G.; Riehl, J. P.; Piguet, C. Inorg. Chem. 2004, 43, 1840.
[103]	Zhou, Y.; Li, H.; Zhu, T.; Gao, T.; Yan, P. J. Am. Chem. Soc. 2019, 141, 19634.
[104]	Hu, S.-J.; Guo, X.-Q.; Zhou, L.-P.; Yan, D.-N.; Cheng, P.-M.; Cai, L.-X.; Li, X.-Z.; Sun, Q.-F. J. Am. Chem. Soc. 2022, 144, 4244.
[105]	Lincheneau, C.; Peacock, R. D.; Gunnlaugsson, T. Chem. - Asian J. 2010, 5, 500.
[106]	Kotova, O.; Comby, S.; Pandurangan, K.; Stomeo, F.; O'Brien, J. E.; Feeney, M.; Peacock, R. D.; McCoy, C. P.; Gunnlaugsson, T. Dalton Trans. 2018, 47, 12308. doi: 10.1039/c8dt02753f pmid: 30113616
[107]	Wang, Z.; Zhou, L.-P.; Zhao, T.-H.; Cai, L.-X.; Guo, X.-Q.; Duan, P.-F.; Sun, Q.-F. Inorg. Chem. 2018, 57, 7982.
[108]	Yeung, C.-T.; Yim, K.-H.; Wong, H.-Y.; Pal, R.; Lo, W.-S.; Yan, S.-C.; Yee-Man Wong, M.; Yufit, D.; Smiles, D. E.; McCormick, L. J.; Teat, S. J.; Shuh, D. K.; Wong, W.-T.; Law, G.-L. Nat. Commun. 2017, 8, 1128.
[109]	Han, G.; Zhou, Y.; Yao, Y.; Cheng, Z.; Gao, T.; Li, H.; Yan, P. Dalton Trans. 2020, 49, 3312.
[110]	Tsurui, M.; Kitagawa, Y.; Shoji, S.; Fushimi, K.; Hasegawa, Y. Dalton Trans. 2023, 52, 796.
[111]	Wang, C.-F.; Shi, C.; Zheng, A.; Wu, Y.; Ye, L.; Wang, N.; Ye, H.-Y.; Ju, M.-G.; Duan, P.; Wang, J.; Zhang, Y. Mater. Horiz. 2022, 9, 2450.
[112]	Niu, X.; Zeng, Z.; Wang, Z.; Lu, H.; Sun, B.; Zhang, H.-L.; Chen, Y.; Du, Y.; Long, G. Sci. China Chem. 2024, DOI: 10.1007/s11426-024-1946-7.
[113]	Mamula, O.; Lama, M.; Telfer, S. G.; Nakamura, A.; Kuroda, R.; Stoeckli-Evans, H.; Scopelitti, R. Angew. Chem., Int. Ed. 2005, 44, 2527.
[114]	Bing, T. Y.; Kawai, T.; Yuasa, J. J. Am. Chem. Soc. 2018, 140, 3683. doi: 10.1021/jacs.7b12663 pmid: 29433303
[115]	Bi, S.; Zhou, Y.; Yao, Y.; Cheng, Z.; Gao, T.; Yan, P.; Li, H. Aust. J. Chem 2021, 74, 145.
[116]	Yao, Z.; Zhou, Y.; Gao, T.; Yan, P.; Li, H. RSC Adv. 2021, 11, 10524.
[117]	Liu, D.; Zhou, Y.; Zhang, Y.; Li, H.; Chen, P.; Sun, W.; Gao, T.; Yan, P. Inorg. Chem. 2018, 57, 8332.
[118]	Wang, Y.; Zhou, Y.; Yao, Z.; Huang, W.; Gao, T.; Yan, P.; Li, H. Dalton Trans. 2022, 51, 10973.
[119]	Hashimoto, Y.; Nakashima, T.; Yamada, M.; Yuasa, J.; Rapenne, G.; Kawai, T. J. Phys. Chem. Lett. 2018, 9, 2151. doi: 10.1021/acs.jpclett.8b00690 pmid: 29641885
[120]	Hasegawa, Y.; Miura, Y.; Kitagawa, Y.; Wada, S.; Nakanishi, T.; Fushimi, K.; Seki, T.; Ito, H.; Iwasa, T.; Taketsugu, T.; Gon, M.; Tanaka, K.; Chujo, Y.; Hattori, S.; Karasawa, M.; Ishii, K. Chem. Commun. 2018, 54, 10695.
[121]	Islam, M. J.; Kitagawa, Y.; Tsurui, M.; Hasegawa, Y. Dalton Trans. 2021, 50, 5433.
[122]	Kitchen, J. A.; Barry, D. E.; Mercs, L.; Albrecht, M.; Peacock, R. D.; Gunnlaugsson, T. Angew. Chem., Int. Ed. 2012, 51, 704.
[123]	Barry, D. E.; Kitchen, J. A.; Mercs, L.; Peacock, R. D.; Albrecht, M.; Gunnlaugsson, T. Dalton Trans. 2019, 48, 11317. doi: 10.1039/c9dt02003a pmid: 31271402
[124]	Liu, X. K.; Xu, W.; Bai, S.; Jin, Y.; Wang, J.; Friend, R. H.; Gao, F. Nat. Mater. 2021, 20, 10.
[125]	Zhu, C.; Jin, J.; Wang, Z.; Xu, Z.; Folgueras, M. C.; Jiang, Y.; Uzundal, C. B.; Le, H. K. D.; Wang, F.; Zheng, X.; Yang, P. Science 2024, 383, 86.
[126]	Gao, Y.; Pan, Y.; Zhou, F.; Niu, G.; Yan, C. J. Mater. Chem. A 2021, 9, 11931.
[127]	Willis, O. G.; Petri, F.; Pescitelli, G.; Pucci, A.; Cavalli, E.; Mandoli, A.; Zinna, F.; Di Bari, L. Angew. Chem., Int. Ed. 2022, 61, e202208326.
[128]	Willis, O. G.; Petri, F.; De Rosa, D. F.; Mandoli, A.; Pal, R.; Zinna, F.; Di Bari, L. J. Am. Chem. Soc. 2023, 145, 25170.
[129]	Yuasa, J.; Ohno, T.; Miyata, K.; Tsumatori, H.; Hasegawa, Y.; Kawai, T. J. Am. Chem. Soc. 2011, 133, 9892.
[130]	Hu, S.-J.; Guo, X.-Q.; Zhou, L.-P.; Cai, L.-X.; Tian, C.-B.; Sun, Q.-F. Chin. J. Chem. 2023, 41, 797.
[131]	Goto, T.; Okazaki, Y.; Ueki, M.; Kuwahara, Y.; Takafuji, M.; Oda, R.; Ihara, H. Angew. Chem., Int. Ed. 2017, 56, 2989.
[132]	Han, J.; You, J.; Li, X.; Duan, P.; Liu, M. Adv. Mater. 2017, 29, 1606503.
[133]	Huo, S.; Duan, P.; Jiao, T.; Peng, Q.; Liu, M. Angew. Chem., Int. Ed. 2017, 56, 12174.
[134]	Zhang, C.; Li, Z.-S.; Dong, X.-Y.; Niu, Y.-Y.; Zang, S.-Q. Adv. Mater. 2022, 34, 2109496.
[135]	Sugimoto, M.; Liu, X.-L.; Tsunega, S.; Nakajima, E.; Abe, S.; Nakashima, T.; Kawai, T.; Jin, R.-H. Chem. - Eur. J. 2018, 24, 6519.
[136]	Maupin, C. L.; Parker, D.; Williams, J. A. G.; Riehl, J. P. J. Am. Chem. Soc. 1998, 120, 10563.
[137]	Maupin, C. L.; Dickins, R. S.; Govenlock, L. G.; Mathieu, C. E.; Parker, D.; Williams, J. A. G.; Riehl, J. P. J. Phys. Chem. A 2000, 104, 6709.
[138]	Willis, O. G.; Zinna, F.; Pescitelli, G.; Micheletti, C.; Di Bari, L. Dalton Trans. 2022, 51, 518.
[139]	Adewuyi, J. A.; Ung, G. J. Am. Chem. Soc. 2024, 146, 7097.
[140]	Riehl, J. P.; Richardson, F. S. Chem. Rev. 1986, 86, 1.
[141]	Adewuyi, J. A.; Schley, N. D.; Ung, G. Chem. Eur. J. 2023, 29, e202300800.
[142]	Denk, W.; Strickler, J. H.; Webb, W. W. Science 1990, 248, 73. doi: 10.1126/science.2321027 pmid: 2321027
[143]	Picot, A.; D'Aléo, A.; Baldeck, P. L.; Grichine, A.; Duperray, A.; Andraud, C.; Maury, O. J. Am. Chem. Soc. 2008, 130, 1532.
[144]	Mizzoni, S.; Ruggieri, S.; Sickinger, A.; Riobé, F.; Guy, L.; Roux, M.; Micouin, G.; Banyasz, A.; Maury, O.; Baguenard, B.; Bensalah-Ledoux, A.; Guy, S.; Grichine, A.; Nguyen, X.-N.; Cimarelli, A.; Sanadar, M.; Melchior, A.; Piccinelli, F. J. Mater. Chem. C 2023, 11, 4188.
[145]	Aspinall, H. C. Chem. Rev. 2002, 102, 1807. pmid: 12059255
[146]	Brittain, H. G.; Desreux, J. F. Inorg. Chem. 1984, 23, 4459.
[147]	Cai, L.-X.; Yan, L.-L.; Li, S.-C.; Zhou, L.-P.; Sun, Q.-F. Dalton Trans. 2018, 47, 14204. doi: 10.1039/c8dt01808a pmid: 29957816
[148]	Zhang, J.; Dai, L.; Webster, A. M.; Chan, W. T. K.; Mackenzie, L. E.; Pal, R.; Cobb, S. L.; Law, G.-L. Angew. Chem., Int. Ed. 2021, 60, 1004.
[149]	Zinna, F.; Giovanella, U.; Di Bari, L. Adv. Mater. 2015, 27, 1791. doi: 10.1002/adma.201404891
[150]	Li, W.; Zhou, Y.; Gao, T.; Li, J.; Yin, S.; Huang, W.; Li, Y.; Ma, Q.; Yao, Z.; Yan, P.; Li, H. ACS Appl. Mater. Inter. 2022, 14, 55979.
[151]	Kitagawa, Y.; Wada, S.; Islam, M. D. J.; Saita, K.; Gon, M.; Fushimi, K.; Tanaka, K.; Maeda, S.; Hasegawa, Y. Commun. Chem. 2020, 3, 119. doi: 10.1038/s42004-020-00366-1 pmid: 36703364
[152]	Yeung, C.-T.; Chan, W. T. K.; Yan, S.-C.; Yu, K.-L.; Yim, K.-H.; Wong, W.-T.; Law, G.-L. Chem. Commun. 2015, 51, 592.
[153]	Vonci, M.; Mason, K.; Suturina, E. A.; Frawley, A. T.; Worswick, S. G.; Kuprov, I.; Parker, D.; McInnes, E. J. L.; Chilton, N. F. J. Am. Chem. Soc. 2017, 139, 14166.
[154]	Fradgley, J. D.; Frawley, A. T.; Pal, R.; Parker, D. Phys. Chem. Chem. Phys. 2021, 23, 11479. doi: 10.1039/d1cp01686e pmid: 33959741
[155]	Wada, S.; Kitagawa, Y.; Nakanishi, T.; Gon, M.; Tanaka, K.; Fushimi, K.; Chujo, Y.; Hasegawa, Y. Sci. Rep. 2018, 8, 16395.
[156]	Arrico, L.; De Rosa, C.; Di Bari, L.; Melchior, A.; Piccinelli, F. Inorg. Chem. 2020, 59, 5050.
[157]	Okayasu, Y.; Wakabayashi, K.; Yuasa, J. Inorg. Chem. 2022, 61, 15108.
[158]	Liu, M.; Zhang, L.; Wang, T. Chem. Rev. 2015, 115, 7304.
[159]	Wang, Y.; Gong, J.; Wang, X.; Li, W.-J.; Wang, X.-Q.; He, X.; Wang, W.; Yang, H.-B. Angew. Chem., Int. Ed. 2022, 61, e202210542.
[160]	Liu, L.; Yang, Y.; Wei, Z. Acta Chim. Sinica 2022, 80, 970. (in Chinese)
	(刘丽萱, 杨扬, 魏志祥, 化学学报, 2022, 80, 970.) doi: 10.6023/A22030123
[161]	Zinna, F.; Pasini, M.; Galeotti, F.; Botta, C.; Di Bari, L.; Giovanella, U. Adv. Funct. Mater. 2017, 27, 1603719.
[162]	Zinna, F.; Arrico, L.; Funaioli, T.; Di Bari, L.; Pasini, M.; Botta, C.; Giovanella, U. J. Mater. Chem. C 2022, 10, 463.
[163]	Zinna, F.; Pasini, M.; Cabras, M.; Scavia, G.; Botta, C.; Di Bari, L.; Giovanella, U. Chirality 2023, 35, 270.
[164]	Shuvaev, S.; Suturina, E. A.; Mason, K.; Parker, D. Chem. Sci. 2018, 9, 2996. doi: 10.1039/c8sc00482j pmid: 29732083
[165]	Montgomery, C. P.; New, E. J.; Parker, D.; Peacock, R. D. Chem. Commun. 2008, 4261.
[166]	Moore, E. G.; Samuel, A. P.; Raymond, K. N. Acc. Chem. Res. 2009, 42, 542.
[167]	Brichtová, E.; Hudecová, J.; Vršková, N.; Šebestík, J.; Bouř, P.; Wu, T. Chem. Eur. J. 2018, 24, 8664.
[168]	Brittain, H. G. Inorg. Chem. 1981, 20, 3007.
[169]	Muller, G.; Riehl, J. P. J. Fluoresc. 2005, 15, 553.
[170]	Iwamura, M.; Kimura, Y.; Miyamoto, R.; Nozaki, K. Inorg. Chem. 2012, 51, 4094.
[171]	Okutani, K.; Nozaki, K.; Iwamura, M. Inorg. Chem. 2014, 53, 5527.
[172]	Iwamura, M.; Fujii, M.; Yamada, A.; Koike, H.; Nozaki, K. Chem. - Asian J. 2019, 14, 561.
[173]	Uchida, T.; Nozaki, K.; Iwamura, M. Chem. - Asian J. 2016, 11, 2415.
[174]	Carr, R.; Di Bari, L.; Lo Piano, S.; Parker, D.; Peacock, R. D.; Sanderson, J. M. Dalton Trans. 2012, 41, 13154.
[175]	Neil, E. R.; Fox, M. A.; Pal, R.; Parker, D. Dalton Trans. 2016, 45, 8355.
[176]	Wu, T.; Průša, J.; Kessler, J.; Dračínský, M.; Valenta, J.; Bouř, P. Anal. Chem. 2016, 88, 8878.

稀土圆偏振发光材料研究进展

Research Progress of Rare Earth-Based Circularly Polarized Luminescent Materials

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 10

References 176

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Haoning Zheng, Jinyu Liu. Research Progress on Organocatalytic Functionalization of Indole in the Carbocyclic Ring [J]. Acta Chimica Sinica, 2024, 82(6): 641-657.
[2]	Min Wang, Bangtang Chen, Qiaolin Chen, Jun Wang, Mingzhao Chen, Zhilong Jiang, Pingshan Wang. Research Progress on Metal-coordination-driven Self-assembly of 6,6"-Bis(2,6-dimethoxy-benzene)-terpyridine and Its Derivatives [J]. Acta Chimica Sinica, 2024, 82(3): 336-347.
[3]	Liwei Hu, Xianhu Liu, Chuntai Liu, Yanlin Song, Mingzhu Li. Self-assembly Fabrication and Applications of Photonic Crystal Structure Color Materials^★ [J]. Acta Chimica Sinica, 2023, 81(7): 809-819.
[4]	Huimin Chen, Long Wang, Pan Zhang, Xilin Bai, Guojun Zhou. Investigation on Photoluminescence and Mechanoluminescence of Single Tb^3＋-doped Intense Green Phosphor [J]. Acta Chimica Sinica, 2023, 81(7): 771-776.
[5]	Lanying Li, Qing Tao, Yanli Wen, Lele Wang, Ruiyan Guo, Gang Liu, Xiaolei Zuo. Poly-adenine-based DNA Probes and Their Applications in Biosensors^★ [J]. Acta Chimica Sinica, 2023, 81(6): 681-690.
[6]	Yinfeng Wang, Meng Li, Chuanfeng Chen. Chiral Triptycene-Based Red Thermally Activated Delayed Fluorescence Polymers and Their Organic Light-Emitting Diodes^★ [J]. Acta Chimica Sinica, 2023, 81(6): 588-594.
[7]	Yuewen Zhong, Xining Qian, Chao Ma, Kai Liu, Hongjie Zhang. Rare Earth Biological Manufacturing and High Value-added Material Application^★ [J]. Acta Chimica Sinica, 2023, 81(11): 1624-1632.
[8]	Xu Pu, Zejuan Li, Junqiu Shi, Yunqing Zhu, Jianzhong Du. Recent Advances in Organ-Targeting Polymeric Delivery Vectors for Nucleic Acids^★ [J]. Acta Chimica Sinica, 2023, 81(10): 1438-1446.
[9]	Bin Liu, Pangkuan Chen. Synthesis and Properties of Novel Circularly Polarized Luminescence Materials Based on Binaphthol Skeleton [J]. Acta Chimica Sinica, 2022, 80(7): 929-935.
[10]	Ling Qiu, Jiayi Liang, Zhuxia Zhang, Taishan Wang. Synthesis and Characterizations of ¹⁵N Isotope Labeling Metal Nitride Clusterfullerene [J]. Acta Chimica Sinica, 2022, 80(7): 874-878.
[11]	Jamshid Kadirkhanov, Feng Zhong, Wenjian Zhang, Chunyan Hong. Preparation of Multi-chambered Vesicles by Polymerization-induced Self-assembly and the Influence of Solvophilic Fragments in the Core-forming Blocks [J]. Acta Chimica Sinica, 2022, 80(7): 913-920.
[12]	Xicheng Feng, Liangliang Zhu, Bingbing Yue. Circularly Polarized Luminescence and Dynamic Regulation Based on the co-Assembly of L/D-Lysine Hydrochloride and Photoactivated AIE Molecules [J]. Acta Chimica Sinica, 2022, 80(5): 647-651.
[13]	Xiaoke Hu, Xiaoying Shang, Ping Huang, Wei Zheng, Xueyuan Chen. Polarized Upconversion Luminescence from a Single NaYF₄:Yb³⁺/Er³⁺ Microrod for Orientation Tracking^※ [J]. Acta Chimica Sinica, 2022, 80(3): 244-248.
[14]	Zhiqin Wang, Bo Xiang, Xiaoyu Huang, Guolin Lu. Effect of Phosphotungstic Acid on Self-seeding of Oligo(p-phenylenevinylene)-b-poly(2-vinylpyridine)^※ [J]. Acta Chimica Sinica, 2022, 80(3): 297-302.
[15]	Xiangyu Zuo, Yifei Xu, Shikao Shi. Rare Earth Ions-Activated Hybrid Assemblies Fluorescent Systems Based on the Layered Lanthanum Hydroxides [J]. Acta Chimica Sinica, 2022, 80(2): 133-140.