Recent advances in Host-Guest Chemistry of Aluminum-Based Metal-Organic Framework Materials

doi:10.6023/A26020059

Abstract

Due to the high natural abundance of host metal, exploration of aluminum-based metal-organic frameworks (Al-MOFs) provides a new approach to construct economical-friendly functional materials. However, compared with other metal-based MOFs, the fast hydrolysis kinetic of Al³⁺ leads to great difficulty in crystallization, limiting their investigations in structure and host-guest chemistry. As the understanding towards the hydrolysis of Al³⁺ deepens, recently the development of Al-MOFs boomed, thus an up-to-date summary of this area is of great importance. Based on this, this review provided a detailed summary of the synthetic methods, structural diversity, and applications in host-guest chemistry of Al-MOFs. Regarding synthetic methods, in addition to the traditional solvothermal method, the emerging microwave-assisted synthesis and electrochemical synthesis were included as well. In terms of structural diversity, all secondary building units (SBUs) reported in Al-MOFs to date are classified and summarized. Starting from these SBUs, the derived Al-MOF structures reported after 2023 were discussed in detail. Moreover, the host-guest chemistry of Al-MOFs was highlighted. By categorizing the guest molecules, this review summarized the corresponding absorption mechanism and binding sites. Finally, this review provided a perspective on the host-guest chemistry of Al-MOFs.

Key words: Aluminum-based metal-organic framework, Aluminum-based secondary building units, Host-guest chemistry

Cite this article

Wu Jia-Yue, Wang Wen-Bo, Xie Yu-Long, Fang Wei-Hui. Recent advances in Host-Guest Chemistry of Aluminum-Based Metal-Organic Framework Materials[J]. Acta Chimica Sinica, doi: 10.6023/A26020059.

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References

[1] Feng D.; Liu T.-F.; Su J.; Bosch M.; Wei Z.; Wan W.; Yuan D.; Chen Y.-P.; Wang X.; Wang K.; Lian X.; Gu Z.-Y.; Park J.; Zou X.; Zhou H.-C.Nat. Commun. 2015,6, 5979.
[2] Cho K. H.; Borges D. D.; Lee J. S.; Park J.; Cho S. J.; Jo D.; Lee U. H.; Maurin G.; Chang J.-S.ACS Sustainable Chem. Eng. 2022,10, 7010.
[3] Hu L.; Zhang M.; Wang W.; Hu J.; Wu W.; Lin D.; Yang K.Adv. Funct. Mater. 2025,35, 2425429.
[4] Yue X.; Zhou Z.; Li M.; Jie M.; Xu B.; Bai Y.Food Chem. 2022,367, 130763.
[5] Pang H.; Zhang S.; Gao C.Acta Chimica Sinica. 2025,83, 962.
[6] Férey G.; Latroche M.; Serre C.; Millange F.; Loiseau T.; Percheron-Guégan, A.Chem. Commun. 2003, 24, 2976.
[7] Fan W.; Wang K.-Y.; Welton C.; Feng L.; Wang X.; Liu X.; Li Y.; Kang Z.; Zhou H.-C.; Wang R.; Sun D.Coord. Chem. Rev. 2023,489, 215175.
[8] Hua Y.; Ahmadi Y.; Kim K.-H.Hazard. Mater. 2023,444, 130422.
[9] Li L.; Zou J.; Han Y.; Liao Z.; Lu P.; Nezamzadeh-Ejhieh, A.; Liu, J.; Peng, Y.New J. Chem. 2022, 46, 19577.
[10] Liu X. T.; Qian B. B.; Zhang D. S.; Yu M. H.; Chang Z.; Bu X. H.Coord. Chem. Rev. 2023,476, 214921.
[11] Loiseau T.; Volkringer C.; Haouas M.; Taulelle F.; Férey G.Comptes Rendus. Chimie. 2015,18, 1350.
[12] Samokhvalov, A. Coord. Chem. Rev. 2018, 374, 236.
[13] Steenhaut T.; Filinchuk Y.; Hermans S.J. Mater. Chem. A. 2021,9, 21483.
[14] Tran T. V.; Jalil A. A.; Nguyen D. T.C.; Alhassan, M.; Nabgan, W.; Cao, A. N. T.; Nguyen, T. M.; Vo, D.-V. N. Environ. Res. 2023, 216, 114422.
[15] Fu J.;Wu, Y. n.Chem. Eur. J. 2021, 27, 9967.
[16] Reinsch H.; Krüger M.; Marrot J.; Stock N.Inorg. Chem. 2013,52, 1854.
[17] Thierry L.; Ludovic L.; Christophe V.; Jeŕôme M.; Geŕard, F. r.; Mohamed, H.; Francis, T.; Sandrine, B.; Philip L., L.; Michel, L.J. Am. Chem. Soc.2006,128, 10223.
[18] Volkringer C.; Popov D.; Loiseau T.; Guillou N.; Ferey G.; Haouas M.; Taulelle F.; Mellot-Draznieks, C.; Burghammer, M.; Riekel, C.Nat. Mater. 2007, 6, 760.
[19] Farhad F.; Markus J. K.; Eugene A. K.; Peter J. W.; Jingjing Y.; Omar M. Y. Sci. Adv.2018, 4, eaat3198.
[20] Głowniak S.; Szczęśniak B.; Choma J.; Jaroniec M.Adv. Mater.2021, 33, 2103477.
[21] Kumar A.; Kuang Y.; Liang Z.; Sun X.Mater. Today Nano. 2020,11, 100076.
[22] García Márquez, A.; Demessence, A.; Platero‐Prats, A. E.; Heurtaux, D.; Horcajada, P.; Serre, C.; Chang, J. S.; Férey, G.; de la Peña‐O'Shea, V. A.; Boissière, C.; Grosso, D.; Sanchez, C.Eur. J. Inorg. Chem. 2012, 2012, 5165.
[23] Khan N. A.; Lee J. S.; Jeon J.; Jun C.-H.; Jhung S. H.Microporous and Mesoporous Mater. 2012,152, 235.
[24] Levin E. E.; Grebenkemper J. H.; Pollock T. M.; Seshadri R.Chem. Mater. 2019,31, 7151.
[25] Bétard A.; Fischer R. A.Chem. Rev. 2011,112, 1055.
[26] Worrall S. D.; Bissett M. A.; Attfield M. P.; Dryfe R. A.W.Cryst. Eng. Comm. 2018, 20, 4421.
[27] Antonio A. M.; Naskar A.; Hoq J.; Bloch, E. D. Cryst. Growth Des.2025, 25, 5123.
[28] Sachdeva S.; Venkatesh M. R.; Mansouri B. E.; Wei J.; Bossche A.; Kapteijn F.; Zhang G. Q.; Gascon J.; de Smet, L. C. P. M.; Sudhölter, E. J. R.Small. 2017, 13, 1604150.
[29] Ameloot R.; Stappers L.; Fransaer J.; Alaerts L.; Sels B. F.; De Vos, D. E.Chem. Mater. 2009, 21, 2580.
[30] Martinez Joaristi, A.; Juan-Alcañiz, J.; Serra-Crespo, P.; Kapteijn, F.; Gascon, J.Cryst. Growth Des. 2012, 12, 3489.
[31] Yang S.; Sun J.; Ramirez-Cuesta, A. J.; Callear, S. K.; David, W. I. F.; Anderson, D. P.; Newby, R.; Blake, A. J.; Parker, J. E.; Tang, C. C.; Schröder, M.Nat. Chem. 2012, 4, 887.
[32] Wang Z. W.; Chen M.; Liu C. S.; Wang X.; Zhao H.; Du, M. Chem. Eur. J.2015, 21, 17215.
[33] Fan W.; Wang X.; Xu B.; Wang Y.; Liu D.; Zhang M.; Shang Y.; Dai F.; Zhang L.; Sun, D. J. Mater. Chem. A.2018, 6, 24486.
[34] Yan Z.; Gong Y.; Yang C.-T.; Wu X.; Liu B.; Liu Q.; Xiong S.; Peng S.Cryst. Growth Des. 2020,20, 8039.
[35] Reinsch H.; Van Der Veen, M. A.; Gil B.; Marszalek B.; Verbiest T.; De Vos D.; Stock N. Chem. Mater.2013, 25, 17.
[36] Wu X.; Wei W.; Jiang J.; Caro J.; Huang A.Angew. Chem. Int. Ed. 2018,57, 15354.
[37] Guo Y.; Zhang J.; Dong L. Z.; Xu Y.; Han W.; Fang M.; Liu H. K.; Wu Y.; Lan, Y. Q. Chem. Eur. J.2017, 23, 15518.
[38] Li H.; Feng X.; Ma D.; Zhang M.; Zhang Y.; Liu Y.; Zhang J.; Wang, B. ACS Appl. Mater. Interfaces.2018, 10, 3160.
[39] Liu C. H.; Fang W. H.; Sun Y.; Yao S.; Wang S. T.; Lu D.; Zhang, J. Angew. Chem. Int. Ed.2021, 60, 21426.
[40] Reinsch H.; Feyand M.; Ahnfeldt T.; Stock N.Dalton Dalton Trans. 2012,41, 4164.
[41] Wang B.; Zhang X.; Huang H.; Zhang Z.; Et., A.Nano Res. 2020, 20, 12274.
[42] Fan W.; Yuan S.; Wang W.; Feng L.; Liu X.; Zhang X.; Wang X.; Kang Z.; Dai F.; Yuan D.; Sun D.; Zhou, H.-C. Journal of the J. Am. Chem. Soc.2020, 142, 8728.
[43] Li S.; Zhou X.; Yu L.; Mao S.; Gao M.; Li J.; Wang H.ACS Mater. Lett. 2025,7, 2390.
[44] Reinsch H.; Marszałek B.; Wack J.; Senker J.; Gil B.; Stock N.Chem. Commun. 2012,48, 9486.
[45] Zhang C. Y.; Wu Z.; Han G.; Wu D. S.; Chi L.; Niu J. Y.; Zhao C.; Fang W. H.; Zhang J.Angew. Chem.Int. Ed. 2025, 64, e20241484.
[46] Xu H.; Wu Y.; Yang L.; Rao Y.; Wang J.; Peng S.; Li Q.Angew. Chem. Int. Ed. 2023,62, e202217864.
[47] Hu L.; Wu W.; Hu M.; Jiang L.; Lin D.; Wu J.; Yang K.Nat. Commun. 2024,15, 3204.
[48] Wang Z.-S.; Zhou M.-Y.; Hu D.-Y.; Chen X.-X.; Chen J.-X.; Zhang X.-W.; Zhou D.-D.; Zhang J.-P.; Chen X.-M.J. Am. Chem. Soc. 2025,147, 47977.
[49] Li S.; Yu L.; Zhou X.; Zhou K.; Yin L.; Gao M.; Wang H.Chin. J. Chem. 2025,43, 2637.
[50] Wegner L.;Morelli Venturi, D.; Ikonnikova, E.; Hetze, K.; Theissen, J.; Derveaux, E.; Oschatz, M.; Willhammar, T.; Stock, N.Inorg. Chem. 2025, 64, 20254.
[51] Wang W.; Chen Y.; Bu X.; Feng P.J. Am. Chem. Soc. 2025,147, 15146.
[52] Luo D.; Liu C. H.; Chen Y. B.; Wang S. T.; Fang W. H.; Zhang J.Adv. Sci. 2023, 2305833.
[53] Geng L.; Wang D.; Chen R.-Q.; Wang S.-T.; Zheng C.; Fang W.-H.; Zhang J.Inorg Chem Front. 2024,11, 8770.
[54] Lv W.; Sui S.-Y.; Xue Z.; Guo L.-L.; Li X.-Y.; Wang G.-M.Cryst. Growth Des. 2024,24, 8544.
[55] Al Azzi, P.; El Kurdi, R.; Patra, D.ACS Omega. 2024, 9, 50561.
[56] Wang Z.-Q.; Deng C.-H.; Liu X.; Wang W.-M. Dalton Trans.2023, 52, 11163.
[57] Aghazadeh Asl, E.; Pooresmaeil, M.; Namazi, H.Mater. Chem. Phys. 2023, 293, 126933.
[58] Zhang Z.; Guo J.; Fang Z.; Zheng Y.; Zhang L.; Liang X.; Liu R.; Zhao J.; He W.; Lu L.; Chen W.Electrochim. Acta.2024, 482, 143989.
[59] Li L.; Li J.; Chen Y.; Zhang L.; Wu Z.Acta Chimica Sinica. 2025,83, 917.
[60] Shi W.; Liu Z.; Yu J.; Wang L.Acta Chimica Sinica. 2025,83, 401.
[61] Chen Z.; Li P.; Anderson R.; Wang X.; Zhang X.; Robison L.; Redfern L. R.; Moribe S.; Islamoglu T.; Gómez-Gualdrón, D. A.; Yildirim, T.; Stoddart, J. F.; Farha, O. K.Sci. 2020, 368, 297.
[62] Volkringer C.; Loiseau T.; Haouas M.; Taulelle F.; Popov D.; Burghammer M.; Riekel C.; Zlotea C.; Cuevas F.; Latroche M.; Phanon D.; Knöfelv C.; Llewellyn P. L.; Férey G.Chem. Mater. 2009,21, 5783.
[63] Gándara F.; Furukawa H.; Lee S.; Yaghi O. M.J. Am. Chem. Soc. 2014,136, 5271.
[64] Yu L.; He M.; Yao J.; Xia Q.; Yang S.; Li J.; Wang H.Chem. Sci. 2024,15, 8530.
[65] Du K.; Lin Y.; Xu M.; Jiang Y.; Ma R.; Lin H.Acta Chimica Sinica. 2024,82, 62.
[66] Luo D.; Wang F.; Liu C. H.; Wang S. T.; Sun Y. Y.; Fang W. H.; Zhang J.Inorg. Chem. Front. 2022,9, 4506.
[67] Hanikel N.; Pei X.; Chheda S.; Lyu H.; Jeong W.; Sauer J.; Gagliardi L.; Yaghi O. M.Sci. 2021,374, 454.
[68] Xu H.; Wu Y.; Yang L.; Rao Y.; Wang J.; Peng S.; Li Q.Angew. Chem. Inter. Ed. 2022,62, e202217864.
[69] Yoon S.; Park J.; Police A. K.R.; Choe, J. K.; Bae, S. J. Hazard. Mater. 2025, 483, 136687.
[70] Ahmadijokani F.; Tajahmadi S.; Rezakazemi M.; Sehat A. A.; Molavi H.; Aminabhavi T. M.; Arjmand, M. J. Environ. Sci. Manage.2021, 277, 111448.

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