Recent Advances in Host-Guest Chemistry of Aluminum-Based Metal-Organic Framework Materials★

doi:10.6023/A26020059

Acta Chimica Sinica ›› 2026, Vol. 84 ›› Issue (5): 697-708.DOI: 10.6023/A26020059 Previous Articles Next Articles

Review

铝基金属有机框架材料的主客体化学研究进展^★

邬佳悦^a, 王文伯^a, 谢玉龙^b, 方伟慧^a^,^b^,^*()

^a 福州大学化学学院福州 350108
^b 中国科学院福建物质结构研究所结构化学全国重点实验室福州 350002

投稿日期:2026-02-14 发布日期:2026-04-14
通讯作者: 方伟慧
作者简介:
★ “框架材料化学”专辑
基金资助:
国家自然科学基金(22371278)

Recent Advances in Host-Guest Chemistry of Aluminum-Based Metal-Organic Framework Materials^★

Jiayue Wu^a, Wenbo Wang^a, Yulong Xie^b, Weihui Fang^a^,^b^,^*()

^a School of Chemistry, Fuzhou University, Fuzhou 350108, China
^b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received:2026-02-14 Published:2026-04-14
Contact: Weihui Fang

About author:

Wu, Jiayue, postgraduate of Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, mainly focuses on the design and synthesis of crystalline metal-oxo clusters.

Wang, Wenbo, postgraduate of Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, mainly focuses on the design and synthesis of crystalline metal-oxo clusters.

Xie, Yulong, Ph.D. candidate of Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, mainly focuses on the design and synthesis of crystalline metal-oxo clusters.

Prof. Dr. Fang Weihui is a researcher, doctoral supervisor, and group leader from Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences. She dedicates to the chemical research of metal-oxo cluster synthesis, including rare earth-oxo clusters, transition metal-oxo clusters, and main group metal-oxo clusters, with a recent focus on precise structural assembly and performance research of aluminum oxygen clusters. She has presided over and completed the cultivation project of “Major Research Plan on Cluster Structure, Function and Multi level Evolution of the National Natural Science Foundation of China”, and the Youth and General Project of the National Natural Science Foundation of China. She is selected as a distinguished youth of Fujian Province, “Star of Innovation”, an outstanding member of the Youth Innovation Promotion Association of the Chinese Academy of Sciences, and serves as a young editorial board member of Structural Chemistry, POM, and Chin. Chem. Lett.

★ For the VSI “Chemistry of Framework Materials”.

Supported by:
National Natural Science Foundation of China(22371278)

Due to the high natural abundance of host metal, exploration of aluminum-based metal-organic frameworks (Al-MOFs) provides a new approach to construct economical-friendly functional materials. However, compared with other metal-based MOFs, the fast hydrolysis kinetic of Al^3＋ leads to great difficulty in crystallization, limiting their investigations in structure and host-guest chemistry. As the understanding towards the hydrolysis of Al^3＋ deepens, recently the development of Al-MOFs boomed, thus an up-to-date summary of this area is of great importance. Based on this, this review provides a detailed summary of the synthetic methods, structural diversity, and applications in host-guest chemistry of Al-MOFs. Regarding synthetic methods, in addition to the traditional solvothermal method, the emerging microwave-assisted synthesis and electrochemical synthesis are included as well. In terms of structural diversity, all secondary building units (SBUs) reported in Al-MOFs to date are classified and summarized. Starting from these SBUs, the derived Al-MOF structures reported after 2023 are discussed in detail. Moreover, the host-guest chemistry of Al-MOFs is highlighted. By categorizing the guest molecules, this review summarizes the corresponding absorption mechanism and binding sites. Finally, this review provides a perspective on the host-guest chemistry of Al-MOFs.

Key words: aluminum-based metal-organic framework, aluminum-based secondary building unit, host-guest chemistry

Cite this article

Jiayue Wu, Wenbo Wang, Yulong Xie, Weihui Fang. Recent Advances in Host-Guest Chemistry of Aluminum-Based Metal-Organic Framework Materials^★[J]. Acta Chimica Sinica, 2026, 84(5): 697-708.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

Fig. & Tab. 7

References 69

[1]	Feng, D.; Liu, T.-F.; Su, J.; Bosch, M.; Wei, Z.; Wan, W.; Yuan, D.; Chen, Y.-P.; Wang, X.; Wang, K.; Lian, X.; Gu, Z.-Y.; Park, J.; Zou, X.; Zhou, H.-C. Nat. Commun. 2015, 6, 5979. doi: 10.1038/ncomms6979
[2]	Cho, K. H.; Borges, D. D.; Lee, J. S.; Park, J.; Cho, S. J.; Jo, D.; Lee, U. H.; Maurin, G.; Chang, J.-S. ACS Sustainable Chem. Eng. 2022, 10, 7010. doi: 10.1021/acssuschemeng.2c00536
[3]	Hu, L.; Zhang, M.; Wang, W.; Hu, J.; Wu, W.; Lin, D.; Yang, K. Adv. Funct. Mater. 2025, 35, 2425429. doi: 10.1002/adfm.v35.28
[4]	Yue, X.; Zhou, Z.; Li, M.; Jie, M.; Xu, B.; Bai, Y. Food Chem. 2022, 367, 130763. doi: 10.1016/j.foodchem.2021.130763
[5]	Gao, C.; Zhang, S.; Pang, H. Acta Chim. Sinica 2025, 83, 962 (in Chinese). doi: 10.6023/A25040117
	(高春, 张松涛, 庞欢, 化学学报, 2025, 83, 962.) doi: 10.6023/A25040117
[6]	Férey, G.; Latroche, M.; Serre, C.; Millange, F.; Loiseau, T.; Percheron-Guégan, A. Chem. Commun. 2003, 24, 2976.
[7]	Fan, W.; Wang, K.-Y.; Welton, C.; Feng, L.; Wang, X.; Liu, X.; Li, Y.; Kang, Z.; Zhou, H.-C.; Wang, R.; Sun, D. Coord. Chem. Rev. 2023, 489, 215175. doi: 10.1016/j.ccr.2023.215175
[8]	Hua, Y.; Ahmadi, Y.; Kim, K.-H. Hazard. Mater. 2023, 444, 130422. doi: 10.1016/j.jhazmat.2022.130422
[9]	Li, L.; Zou, J.; Han, Y.; Liao, Z.; Lu, P.; Nezamzadeh-Ejhieh, A.; Liu, J.; Peng, Y. New J. Chem. 2022, 46, 19577. doi: 10.1039/D2NJ03419K
[10]	Liu, X. T.; Qian, B. B.; Zhang, D. S.; Yu, M. H.; Chang, Z.; Bu, X. H. Coord. Chem. Rev. 2023, 476, 214921. doi: 10.1016/j.ccr.2022.214921
[11]	Loiseau, T.; Volkringer, C.; Haouas, M.; Taulelle, F.; Férey, G. C. R. Chim. 2015, 18, 1350. doi: 10.1016/j.crci.2015.08.006
[12]	Samokhvalov, A. Coord. Chem. Rev. 2018, 374, 236. doi: 10.1016/j.ccr.2018.06.011
[13]	Steenhaut, T.; Filinchuk, Y.; Hermans, S. J. Mater. Chem. A 2021, 9, 21483. doi: 10.1039/D1TA04444C
[14]	Tran, T. V.; Jalil, A. A.; Nguyen, D. T. C.; Alhassan, M.; Nabgan, W.; Cao, A. N. T.; Nguyen, T. M.; Vo, D.-V. N. Environ. Res. 2023, 216, 114422. doi: 10.1016/j.envres.2022.114422
[15]	Fu, J.; Wu, Y. N. Chem.-Eur. J. 2021, 27, 9967. doi: 10.1002/chem.v27.39
[16]	Reinsch, H.; Krüger, M.; Marrot, J.; Stock, N. Inorg. Chem. 2013, 52, 1854. doi: 10.1021/ic301961q pmid: 23356350
[17]	Thierry, L.; Ludovic, L.; Christophe, V.; Jérôme, M.; Gérard, F. R.; Mohamed, H.; Francis, T.; Sandrine, B.; Philip, L. L.; Michel, L. J. Am. Chem. Soc. 2006, 128, 10223. pmid: 16881652
[18]	Volkringer, C.; Popov, D.; Loiseau, T.; Guillou, N.; Ferey, G.; Haouas, M.; Taulelle, F.; Mellot-Draznieks, C.; Burghammer, M.; Riekel, C. Nat. Mater. 2007, 6, 760. doi: 10.1038/nmat1991
[19]	Farhad, F.; Markus, J. K.; Eugene, A. K.; Peter, J. W.; Jingjing, Y.; Omar, M. Y. Sci. Adv. 2018, 4, eaat3198. doi: 10.1126/sciadv.aat3198
[20]	Głowniak, S.; Szczęśniak, B.; Choma, J.; Jaroniec, M. Adv. Mater. 2021, 33, 2103477. doi: 10.1002/adma.v33.48
[21]	Kumar, A.; Kuang, Y.; Liang, Z.; Sun, X. Mater. Today Nano. 2020, 11, 100076.
[22]	García Márquez, A.; Demessence, A.; Platero‐Prats, A. E.; Heurtaux, D.; Horcajada, P.; Serre, C.; Chang, J. S.; Férey, G.; de la Peña‐O'Shea, V. A.; Boissière, C.; Grosso, D.; Sanchez, C. Eur. J. Inorg. Chem. 2012, 2012, 5165. doi: 10.1002/ejic.v2012.32
[23]	Khan, N. A.; Lee, J. S.; Jeon, J.; Jun, C.-H.; Jhung, S. H. Microporous Mesoporous Mater. 2012, 152, 235. doi: 10.1016/j.micromeso.2011.11.025
[24]	Levin, E. E.; Grebenkemper, J. H.; Pollock, T. M.; Seshadri, R. Chem. Mater. 2019, 31, 7151. doi: 10.1021/acs.chemmater.9b02594
[25]	Bétard, A.; Fischer, R. A. Chem. Rev. 2011, 112, 1055. doi: 10.1021/cr200167v
[26]	Worrall, S. D.; Bissett, M. A.; Attfield, M. P.; Dryfe, R. A. W. CrystEngComm 2018, 20, 4421. doi: 10.1039/C8CE00761F
[27]	Antonio, A. M.; Naskar, A.; Hoq, J.; Bloch, E. D. Cryst. Growth Des. 2025, 25, 5123. doi: 10.1021/acs.cgd.4c01561
[28]	Sachdeva, S.; Venkatesh, M. R.; Mansouri, B. E.; Wei, J.; Bossche, A.; Kapteijn, F.; Zhang, G. Q.; Gascon, J.; de Smet, L. C. P. M.; Sudhölter, E. J. R. Small 2017, 13, 1604150. doi: 10.1002/smll.v13.29
[29]	Ameloot, R.; Stappers, L.; Fransaer, J.; Alaerts, L.; Sels, B. F.; De Vos, D. E. Chem. Mater. 2009, 21, 2580. doi: 10.1021/cm900069f
[30]	Martinez Joaristi, A.; Juan-Alcañiz, J.; Serra-Crespo, P.; Kapteijn, F.; Gascon, J. Cryst. Growth Des. 2012, 12, 3489. doi: 10.1021/cg300552w
[31]	Yang, S.; Sun, J.; Ramirez-Cuesta, A. J.; Callear, S. K.; David, W. I. F.; Anderson, D. P.; Newby, R.; Blake, A. J.; Parker, J. E.; Tang, C. C.; Schröder, M. Nat. Chem. 2012, 4, 887. doi: 10.1038/nchem.1457
[32]	Wang, Z. W.; Chen, M.; Liu, C. S.; Wang, X.; Zhao, H.; Du, M. Chem.-Eur. J. 2015, 21, 17215. doi: 10.1002/chem.v21.48
[33]	Fan, W.; Wang, X.; Xu, B.; Wang, Y.; Liu, D.; Zhang, M.; Shang, Y.; Dai, F.; Zhang, L.; Sun, D. J. Mater. Chem. A 2018, 6, 24486. doi: 10.1039/C8TA07839D
[34]	Yan, Z.; Gong, Y.; Yang, C.-T.; Wu, X.; Liu, B.; Liu, Q.; Xiong, S.; Peng, S. Cryst. Growth Des. 2020, 20, 8039. doi: 10.1021/acs.cgd.0c01283
[35]	Reinsch, H.; Van Der Veen, M. A.; Gil, B.; Marszalek, B.; Verbiest, T.; De Vos, D.; Stock, N. Chem. Mater. 2013, 25, 17. doi: 10.1021/cm3025445
[36]	Wu, X.; Wei, W.; Jiang, J.; Caro, J.; Huang, A. Angew. Chem., Int. Ed. 2018, 57, 15354. doi: 10.1002/anie.v57.47
[37]	Guo, Y.; Zhang, J.; Dong, L. Z.; Xu, Y.; Han, W.; Fang, M.; Liu, H. K.; Wu, Y.; Lan, Y. Q. Chem.-Eur. J. 2017, 23, 15518. doi: 10.1002/chem.v23.61
[38]	Li, H.; Feng, X.; Ma, D.; Zhang, M.; Zhang, Y.; Liu, Y.; Zhang, J.; Wang, B. ACS Appl. Mater. Interfaces 2018, 10, 3160. doi: 10.1021/acsami.7b17026
[39]	Liu, C. H.; Fang, W. H.; Sun, Y.; Yao, S.; Wang, S. T.; Lu, D.; Zhang, J. Angew. Chem., Int. Ed. 2021, 60, 21426. doi: 10.1002/anie.v60.39
[40]	Reinsch, H.; Feyand, M.; Ahnfeldt, T.; Stock, N. Dalton Trans. 2012, 41, 4164. doi: 10.1039/c2dt12005d pmid: 22286397
[41]	Wang, B.; Zhang, X.; Huang, H.; Zhang, Z.; Yildirim, T.; Zhou, W.; Xiang, S. C.; Chen, B. L. Nano Res. 2020, 20, 12274.
[42]	Fan, W.; Yuan, S.; Wang, W.; Feng, L.; Liu, X.; Zhang, X.; Wang, X.; Kang, Z.; Dai, F.; Yuan, D.; Sun, D.; Zhou, H.-C. J. Am. Chem. Soc. 2020, 142, 8728. doi: 10.1021/jacs.0c00805
[43]	Li, S.; Zhou, X.; Yu, L.; Mao, S.; Gao, M.; Li, J.; Wang, H. ACS Mater. Lett. 2025, 7, 2390.
[44]	Reinsch, H.; Marszałek, B.; Wack, J.; Senker, J.; Gil, B.; Stock, N. Chem. Commun. 2012, 48, 9486. doi: 10.1039/c2cc34909d
[45]	Zhang, C. Y.; Wu, Z.; Han, G.; Wu, D. S.; Chi, L.; Niu, J. Y.; Zhao, C.; Fang, W. H.; Zhang, J. Angew. Chem., Int. Ed. 2025, 64, e20241484.
[46]	Xu, H.; Wu, Y.; Yang, L.; Rao, Y.; Wang, J.; Peng, S.; Li, Q. Angew. Chem., Int. Ed. 2023, 62, e202217864. doi: 10.1002/anie.v62.6
[47]	Hu, L.; Wu, W.; Hu, M.; Jiang, L.; Lin, D.; Wu, J.; Yang, K. Nat. Commun. 2024, 15, 3204. doi: 10.1038/s41467-024-47612-x
[48]	Wang, Z.-S.; Zhou, M.-Y.; Hu, D.-Y.; Chen, X.-X.; Chen, J.-X.; Zhang, X.-W.; Zhou, D.-D.; Zhang, J.-P.; Chen, X.-M. J. Am. Chem. Soc. 2025, 147, 47977. doi: 10.1021/jacs.5c12200
[49]	Li, S.; Yu, L.; Zhou, X.; Zhou, K.; Yin, L.; Gao, M.; Wang, H. Chin. J. Chem. 2025, 43, 2637. doi: 10.1002/cjoc.v43.20
[50]	Wegner, L.; Morelli Venturi, D.; Ikonnikova, E.; Hetze, K.; Theissen, J.; Derveaux, E.; Oschatz, M.; Willhammar, T.; Stock, N. Inorg. Chem. 2025, 64, 20254. doi: 10.1021/acs.inorgchem.5c03315 pmid: 41037797
[51]	Wang, W.; Chen, Y.; Bu, X.; Feng, P. J. Am. Chem. Soc. 2025, 147, 15146. doi: 10.1021/jacs.4c18251
[52]	Luo, D.; Liu, C. H.; Chen, Y. B.; Wang, S. T.; Fang, W. H.; Zhang, J. Adv. Sci. 2023, 2305833.
[53]	Geng, L.; Wang, D.; Chen, R.-Q.; Wang, S.-T.; Zheng, C.; Fang, W.-H.; Zhang, J. Inorg. Chem. Front. 2024, 11, 8770. doi: 10.1039/D4QI02507E
[54]	Lv, W.; Sui, S.-Y.; Xue, Z.; Guo, L.-L.; Li, X.-Y.; Wang, G.-M. Cryst. Growth Des. 2024, 24, 8544.
[55]	Al Azzi, P.; El Kurdi, R.; Patra, D. ACS Omega 2024, 9, 50561. doi: 10.1021/acsomega.4c08387
[56]	Wang, Z.-Q.; Deng, C.-H.; Liu, X.; Wang, W.-M. Dalton Trans. 2023, 52, 11163. doi: 10.1039/D3DT01846F
[57]	Aghazadeh Asl, E.; Pooresmaeil, M.; Namazi, H. Mater. Chem. Phys. 2023, 293, 126933. doi: 10.1016/j.matchemphys.2022.126933
[58]	Zhang, Z.; Guo, J.; Fang, Z.; Zheng, Y.; Zhang, L.; Liang, X.; Liu, R.; Zhao, J.; He, W.; Lu, L.; Chen, W. Electrochim. Acta 2024, 482, 143989. doi: 10.1016/j.electacta.2024.143989
[59]	Wu, Z.; Zhang, L.; Chen, Y.; Li, J.; Li, L. Acta Chim. Sinica 2025, 83, 917 (in Chinese). doi: 10.6023/A25040140
	(吴子林, 张璐, 陈杨, 李晋平, 李立博, 化学学报, 2025, 83, 917.) doi: 10.6023/A25040140
[60]	Wang, L.; Yu, J.; Liu, Z.; Shi, W. Acta Chim. Sinica 2025, 83, 401 (in Chinese). doi: 10.6023/A24120376
	(王丽英, 于吉攀, 刘峙嵘, 石伟群, 化学学报, 2025, 83, 401.) doi: 10.6023/A24120376
[61]	Chen, Z.; Li, P.; Anderson, R.; Wang, X.; Zhang, X.; Robison, L.; Redfern, L. R.; Moribe, S.; Islamoglu, T.; Gómez-Gualdrón, D. A.; Yildirim, T.; Stoddart, J. F.; Farha, O. K. Science 2020, 368, 297. doi: 10.1126/science.aaz8881
[62]	Volkringer, C.; Loiseau, T.; Haouas, M.; Taulelle, F.; Popov, D.; Burghammer, M.; Riekel, C.; Zlotea, C.; Cuevas, F.; Latroche, M.; Phanon, D.; Knöfelv, C.; Llewellyn, P. L.; Férey, G. Chem. Mater. 2009, 21, 5783. doi: 10.1021/cm9023106
[63]	Gándara, F.; Furukawa, H.; Lee, S.; Yaghi, O. M. J. Am. Chem. Soc. 2014, 136, 5271. doi: 10.1021/ja501606h pmid: 24661065
[64]	Yu, L.; He, M.; Yao, J.; Xia, Q.; Yang, S.; Li, J.; Wang, H. Chem. Sci. 2024, 15, 8530. doi: 10.1039/D4SC01877J
[65]	Lin, H.; Ma, R.; Jiang, Y.; Xu, M.; Lin, Y.; Du, K. Acta Chim. Sinica 2024, 82, 62 (in Chinese). doi: 10.6023/A23080392
	(林航青, 马若茹, 江怡蓝, 许木榕, 林洋彭, 杜克钊, 化学学报, 2024, 82, 62.) doi: 10.6023/A23080392
[66]	Luo, D.; Wang, F.; Liu, C. H.; Wang, S. T.; Sun, Y. Y.; Fang, W. H.; Zhang, J. Inorg. Chem. Front. 2022, 9, 4506. doi: 10.1039/D2QI01108E
[67]	Hanikel, N.; Pei, X.; Chheda, S.; Lyu, H.; Jeong, W.; Sauer, J.; Gagliardi, L.; Yaghi, O. M. Science 2021, 374, 454. doi: 10.1126/science.abj0890 pmid: 34672755
[68]	Yoon, S.; Park, J.; Police, A. K. R.; Choe, J. K.; Bae, S. J. Hazard. Mater. 2025, 483, 136687. doi: 10.1016/j.jhazmat.2024.136687
[69]	Ahmadijokani, F.; Tajahmadi, S.; Rezakazemi, M.; Sehat, A. A.; Molavi, H.; Aminabhavi, T. M.; Arjmand, M. J. Environ. Sci. Manage. 2021, 277, 111448.

MOFs	Formula	Linker	SBU	Condition	BET/(m²•g^－1)^a	Ref.
ZJU-520	AlC₁₈H₁₀O₅N₂	H₂DBP	[Al(OH)(COO)₂]_n	130 ℃, 72 h	2235	[47]
MCF-66	AlC₁₄H₁₁O₅	HBA	[Al(OH)(COO)₂]_n	160 ℃, 48 h	—	[48]
ZJU-928	Al₁₆C₉₀O₇₉H₄₂	H₃BTA	[Al₈(OH)₁₅(COO)₉]	130 ℃, 72 h	2344	[3]
HIAM-340	Al₂₇C₂₂₂H₁₅₃O₁₄₁	H₆btei	[Al₉(OH)₁₅(COO)₁₂], [Al₃O(COO)₄]	155 ℃, 72 h	2800	[43]
HIAM-341	Al₃C₃₀H₁₂O₁₆	H₆BHB	[Al₃O(OH)₃(COO)₆]	180 ℃, 72 h	1094	[49]
CAU-63	Al₇C₂₁H₂₄O₂₇N₃	2,4-H₂Pydc	Al₄O₁₄N₂	135 ℃, 6 h	—	[50]
AlOC-200-Cu	Al₁₂C₇₂H₇₆O₅₆N₄₈Cu₁₂	HPyzc	[Al₁₂(µ₃-O)₄(Hpyzc)₁₂(COO)₆(H₂O)₁₂]	100 ℃, 24 h	1526.2	[45]
AlOC-200-Ag	Al₁₂C₇₂H₄₈O₄₀N₄₈Ag₁₂	Hpyzc	[Al₁₂(µ₃-O)₄(Hpyzc)₁₂(COO)₆(H₂O)₁₂]	100 ℃, 24 h	1461.8	[45]
MAl-bcp-pacs	(M)_3－_x(Al₂)_x(O/OH)(bcp)₃(tpbz)	tpbz	M₂Al(OH) (M=Mg, Mn, Co, Ni)	130 ℃, 24 h	1027	[51]
MAl-bdc-pacs	(M)_3－_x(Al₂)_x(O/OH)(bdc)₃(tpt)	tpt	M₂Al(OH) (M=Mg, Mn, Co, Ni)	150 ℃, 15 h	1328	[51]
MAl-bdc-pacs	(M)_3－_x(Al₂)_x(O/OH)(bdc)₃(tppy)	tppy	M₂Al(OH) (M=Mg, Mn, Co, Ni)	130 ℃, 15 h	—	[51]
AlOC-132	Al₄C₈₈H₁₂₀O₃₂N₁₆Eu₄Cu₄I₄	Hpyba	[Al₄Eu₄(IN)₈(COO)₈(H₂O)]	100 ℃, 96 h	—	[52]
AlOC-197	Al₈C₉₆H₁₁₀N₁₂O_37.25Cu₂Cl₃	HNA	[Al₈(µ-OH)₄(OⁱPr)₈(COO)₁₂(Cl)]	100 ℃, 120 h	—	[53]
Ag-Al₈	Al₈C₁₀₁H₇₆O₄₆N₁₉Ag₂F₆S₂	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]
AgCl-Al₈	Al₈C₉₈H₈₆O₄₆N₁₆Ag₆Cl₂₀F₆S₂	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]
CuBr-Al₈-1	Al₈C₁₀₇H₈₀O₄₄N₁₉Cu₄Br₃	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]
CuBr-Al₈-2	Al₈C₁₀₈H₇₂O₄₄N₁₈Cu₄Br₂	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]

MOFs	Formula	Linker	SBU	Condition	BET/(m²•g^－1)^a	Ref.
ZJU-520	AlC₁₈H₁₀O₅N₂	H₂DBP	[Al(OH)(COO)₂]_n	130 ℃, 72 h	2235	[47]
MCF-66	AlC₁₄H₁₁O₅	HBA	[Al(OH)(COO)₂]_n	160 ℃, 48 h	—	[48]
ZJU-928	Al₁₆C₉₀O₇₉H₄₂	H₃BTA	[Al₈(OH)₁₅(COO)₉]	130 ℃, 72 h	2344	[3]
HIAM-340	Al₂₇C₂₂₂H₁₅₃O₁₄₁	H₆btei	[Al₉(OH)₁₅(COO)₁₂], [Al₃O(COO)₄]	155 ℃, 72 h	2800	[43]
HIAM-341	Al₃C₃₀H₁₂O₁₆	H₆BHB	[Al₃O(OH)₃(COO)₆]	180 ℃, 72 h	1094	[49]
CAU-63	Al₇C₂₁H₂₄O₂₇N₃	2,4-H₂Pydc	Al₄O₁₄N₂	135 ℃, 6 h	—	[50]
AlOC-200-Cu	Al₁₂C₇₂H₇₆O₅₆N₄₈Cu₁₂	HPyzc	[Al₁₂(µ₃-O)₄(Hpyzc)₁₂(COO)₆(H₂O)₁₂]	100 ℃, 24 h	1526.2	[45]
AlOC-200-Ag	Al₁₂C₇₂H₄₈O₄₀N₄₈Ag₁₂	Hpyzc	[Al₁₂(µ₃-O)₄(Hpyzc)₁₂(COO)₆(H₂O)₁₂]	100 ℃, 24 h	1461.8	[45]
MAl-bcp-pacs	(M)_3－_x(Al₂)_x(O/OH)(bcp)₃(tpbz)	tpbz	M₂Al(OH) (M=Mg, Mn, Co, Ni)	130 ℃, 24 h	1027	[51]
MAl-bdc-pacs	(M)_3－_x(Al₂)_x(O/OH)(bdc)₃(tpt)	tpt	M₂Al(OH) (M=Mg, Mn, Co, Ni)	150 ℃, 15 h	1328	[51]
MAl-bdc-pacs	(M)_3－_x(Al₂)_x(O/OH)(bdc)₃(tppy)	tppy	M₂Al(OH) (M=Mg, Mn, Co, Ni)	130 ℃, 15 h	—	[51]
AlOC-132	Al₄C₈₈H₁₂₀O₃₂N₁₆Eu₄Cu₄I₄	Hpyba	[Al₄Eu₄(IN)₈(COO)₈(H₂O)]	100 ℃, 96 h	—	[52]
AlOC-197	Al₈C₉₆H₁₁₀N₁₂O_37.25Cu₂Cl₃	HNA	[Al₈(µ-OH)₄(OⁱPr)₈(COO)₁₂(Cl)]	100 ℃, 120 h	—	[53]
Ag-Al₈	Al₈C₁₀₁H₇₆O₄₆N₁₉Ag₂F₆S₂	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]
AgCl-Al₈	Al₈C₉₈H₈₆O₄₆N₁₆Ag₆Cl₂₀F₆S₂	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]
CuBr-Al₈-1	Al₈C₁₀₇H₈₀O₄₄N₁₉Cu₄Br₃	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]
CuBr-Al₈-2	Al₈C₁₀₈H₇₂O₄₄N₁₈Cu₄Br₂	HNA	[Al₈(OH)₈(COO)₁₆]	100 ℃, 168 h	—	[54]

铝基金属有机框架材料的主客体化学研究进展^★

Recent Advances in Host-Guest Chemistry of Aluminum-Based Metal-Organic Framework Materials^★

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 7

References 69

Related Articles 5

Recommended Articles

Metrics

Comments

[1]	Xiuqing Huang, Qi Zhang. A Gourd-shaped Organometallic Coordination Cage: Synthesis and Selective Binding of Two Drug Molecules [J]. Acta Chimica Sinica, 2023, 81(3): 217-221.
[2]	Minggang Wu, Yong Yang, Min Xue. Tetraaminopillar[5]arene Dimers: Synthesis, Structure and Properties [J]. Acta Chimica Sinica, 2022, 80(8): 1057-1060.
[3]	Zhou Li, Xu Lijin, Gong Hanyuan. Pattern and Protonation Effect of Benzene Dicarboxylate Anion Species in Self-assembly System [J]. Acta Chimica Sinica, 2014, 72(4): 447-455.
[4]	Han Chengyou, Zhang Zibin, Chi Xiaodong, Zhang Mingming, Yu Guocan, Huang Feihe. Synthesis of 1,4-Bis(n-propoxy)pillar[7]arene and Its Host-guest Chemistry [J]. Acta Chimica Sinica, 2012, 70(17): 1775-1778.
[5]	Yang Dengke, Zeng Zhijian, Chen Mujuan, Pan Shaowu, Yang Yu, Li Mei, Lei Chunyan, Jiang Lasheng. Studies on the Complexation of di-Amide Based Macrocycles with Pyridine N-oxides [J]. Acta Chimica Sinica, 2012, 70(12): 1385-1393.

铝基金属有机框架材料的主客体化学研究进展★

Recent Advances in Host-Guest Chemistry of Aluminum-Based Metal-Organic Framework Materials★

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 7

References 69

Related Articles 5

Recommended Articles

Metrics

Comments

铝基金属有机框架材料的主客体化学研究进展^★

Recent Advances in Host-Guest Chemistry of Aluminum-Based Metal-Organic Framework Materials^★