[1] For reviews, see: (a) Das, J. P.; Marek, I.
Chem. Commun. 2011,
47, 4593;
(b) Hawner, C.; Alexakis, A.
Chem. Commun. 2010,
46, 7295;
(c) Bella, M.; Gasperi, T.
Synthesis 2009, 1583;
(d) Cozzi, P. G.; Hilgraf, R.; Zimmermann, N.
Eur. J. Org. Chem. 2007, 5969.
[2] For selected examples of asymmetric construction of spirocyclic 2-oxindoles, see: (a) Trost, B. M.; Cramer, N.; Silverman, S. M.
J. Am. Chem. Soc. 2007,
129, 12396;
(b) Hojo, D.; Noguchi, K.; Hirano, M.; Tanaka, K.
Angew. Chem. Int. Ed. 2008,
47, 5820;
(c) Chen, X.-H.; Wei, Q.; Luo, S.-W.; Xiao, H.; Gong, L.-Z.
J. Am. Chem. Soc. 2009,
131, 13819;
(d) Bencivenni, G.; Wu, L.-Y.; Mazzanti, A.; Giannichi, B.; Pesciaioli, F.; Song, M. P.; Bartoli, G.; Melchiorre, P.
Angew. Chem. Int. Ed. 2009,
48, 7200;
(e) Jiang, K.; Jia, Z.-J.; Chen, S.; Wu, L.; Chen, Y.-C.
Chem. Eur. J. 2010,
16, 2852;
(f) Jiang, K.; Jia, Z.-J.; Yin, X.; Wu, L.; Chen, Y.-C.
Org. Lett. 2010,
12, 2766;
(g) Antonchick, A. P.; Gerding-Reimers, C.; Catarinella, M.; Sch黵mann, M.; Preut, H.; Ziegler, S.; Rauh, D.; Waldmann, H.
Nat. Chem. 2010,
2, 735;
(h) Voituriez, A.; Pinto, N.; Neel, M.; Retailleau, P.; Marinetti, A.
Chem. Eur. J. 2010,
16, 12541;
(i) Jiang, X.; Cao, Y.; Wang, Y.; Liu, L.; Shen, F.; Wang, R.
J. Am. Chem. Soc. 2010,
132, 15328;
(j) Chen, W.-B.; Wu, Z.-J.; Pei, Q.-L.; Cun, L.-F.; Zhang, X.-M.; Yuan, W.-C.
Org. Lett. 2010,
12, 3132;
(k) Zhong, F.; Han, X.; Wang, Y.; Lu, Y.
Angew. Chem. Int. Ed. 2011,
50, 7837.
[3] For selected examples, see: (a) Hamashima, Y.; Suzuki, T.; Takano, H.; Shimura, Y.; Sedeoka, M.
J. Am. Chem. Soc. 2005,
127, 10164;
(b) Ishimaru, T.; Shibata, N.; Horikawa, T.; Yasuda, N.; Nakamura, S.; Toru, T.; Shiro, M.
Angew. Chem. Ed. Int.
2008,
47, 4157;
(c) Ishimaru, T.; Shibata, N.; Nagai, J.; Nakamura, S.; Toru, T.; Kanemasa, S.
J. Am. Chem. Soc. 2006,
128, 16488;
(d) Shaw, S. A.; Aleman, P.; Christy, J.; Kampf, J. W.; Va, P.; Vedejs, E.
J. Am. Chem. Soc. 2006,
128, 925;
(e) Ogawa, S.; Shibata, N.; Inagaki, J.; Nakamura, S.; Toru, T.; Shiro, M.
Angew. Chem. Ed. Int.
2007,
46, 8666;
(f) Trost, B. M.; Zhang, Y.
J. Am. Chem. Soc. 2007,
129, 14548;
(g) Tian, X.; Jiang, K.; Peng, J.; Du, W.; Chen, Y.-C.
Org. Lett.
2008,
10, 3583;
(h) Jiang, K.; Peng, J.; Cui, H.-L; Chen, Y.-C.
Chem. Commun. 2009, 3955;
(i) Galzerano, P.; Bencivenni, G.; Pesciaioli, F.; Mazzanti, A.; Giannichi, B.; Sambri, L.; Bartoli, G.; Melchiorre, P.
Chem. Eur. J. 2009,
15, 7846;
(j) Kato, Y.; Furutachi, M.; Chen, Z.; Mitsunuma, H.; Matsunaga, S.; Shibasaki, M.
J. Am. Chem. Soc. 2009,
131, 9168;
(k) Cheng, L.; Liu, L.; Wang, D.; Chen, Y.-J.
Org. Lett.
2009,
11, 3874;
(l) He, R.; Shirakawa, S.; Maruoka, K
. J. Am. Chem. Soc. 2009,
131, 16620; (m) Bui, T.; Candeias, N. R.; Barbas, C. F. III.
J. Am. Chem. Soc. 2010,
132, 5574.
[4] (a) Waldmann, H.; Khedkar, V.; D點kert, H.; Sch黵mann, M.; Oppel, I. M.; Kumar, K.
Angew. Chem. Int. Ed.
2008,
47, 6869;
(b) for a review, see: Marcelli, T.; van Maarseveen, J. H.; Hiemstra, H.
Angew. Chem. Int. Ed. 2006,
45, 7496.
[5] For selected examples of organocatalytic asymmetric allylic alkylation of MBH derivatives of aldehydes, see: (a) Cui, H.-L.; Peng, J.; Feng, X.; Du, W.; Jiang, K.; Chen, Y.-C.
Chem. Eur. J. 2009,
15, 1574;
(b) Cui, H.-L.; Feng, X.; Peng, J.; Lei, J.; Jiang, K.; Chen, Y.-C.
Angew. Chem. Int. Ed. 2009,
48, 5737;
(c) Huang, J.- R.; Cui, H.-L.; Lei, J.; Sun, X.-H.; Chen, Y.-C.
Chem. Commun. 2011,
47, 4784;
(d) van Steenis, D. J. V. C.; Marcelli, T.; Lutz, M.; Spek, A. L.; van Maarseveen, A. L. J. H.; Hiemstra, H.
Adv. Synth. Catal. 2007,
349, 281;
(e) Jiang, Y.-Q.; Shi, Y.-L.; Shi, M.
J. Am. Chem. Soc. 2008,
130, 7202;
(f) Ma, G.-N.; Cao, S.-H.; Shi, M.
Tetrahedron: Asymmetry 2009,
20, 1086;
(g) Sun, W.; Hong, L.; Liu, C.; Wang, R.
Org. Lett. 2010,
12, 3914;
(h) Yang, W.; Wei, X.; Pan, Y.; Lee, R.; Zhu, B.; Liu, H.; Yan, L.; Huang, K.-W.; Jiang, Z.; Tan, C.-H.
Chem. Eur. J. 2011,
17, 8066;
(i) Lin, A.; Mao, H.; Zhu, X.; Ge, H.; Tan, R.; Zhu, C.; Cheng, Y.
Chem. Eur. J. 2011,
17, 13676;
(h) For a review, see: Liu, T.-Y.; Xie, M.; Chen, Y.-C.
Chem. Soc. Rev. 2012,
41, 4101.
[6] (a) Peng, J.; Huang, X.; Cui, H.-L.; Chen, Y.-C.
Org. Lett.
2010,
12, 4260;
(b) Peng, J.; Huang, X.; Jiang, L.; Cui, H.-L.; Chen, Y.-C.
Org. Lett.
2011,
13, 4584;
(c) Huang, X.; Peng, J.; Dong, L.; Chen, Y.-C.
Chem. Commun.
2012,
48, 2439.
[7] Xiong, X.-F.; Zhang, H.; Peng, J.; Chen, Y.-C.
Chem. Eur. J.
2011,
17, 2358.
[8] CCDC-895875 (
4l) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
[9] (a) Cava, M. P.; Watanabe, Y.; Bessho, K.
J. Org. Chem.
1968,
33, 3350;
(b) Chen, Z.-C.; Fan, J.-F.; Kende, A. S.
J. Org. Chem.
2004,
69, 79.
