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Acta Chimica Sinica >

2020 , Vol. 78 >Issue 3: 193 - 216

DOI: https://doi.org/10.6023/A20010002

Review

Recent Advances in Catalytic Asymmetric Synthesis of P-Chiral Phosphine Oxides

  • Zhu Ren-Yi ,
  • Liao Kui ,
  • Yu Jin-Sheng ,
  • Zhou Jian
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  • a Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062;
    b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, CAS, Shanghai 200032

Received date: 2020-01-01

  Online published: 2020-02-24

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21725203, 21901074).

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Abstract

P-Chiral phosphine oxides are a class of privileged structures, which have important applications in the field of medicinal chemistry, organic synthesis, life and material science. Recent years have witnessed significant progress in the catalytic asymmetric construction of such scaffolds. These advances are summarized in this review according to the following three major strategies:desymmetrization of prochiral tertiary phosphine oxides, (dynamic) kinetic resolution of tertiary phosphine oxides, and catalytic asymmetric reactions involving secondary phosphine oxides, and discusses the possible reaction mechanism, the advantage and disadvantage of each type of reactions, which would provide reference and inspiration for the researchers engaged in organic synthesis and organic phosphorus chemistry.

Key words： P-chiral phosphine oxide; catalytic asymmetric synthesis; desymmetrization; (dynamic) kinetic resolution; tertiary phosphine oxide; secondary phosphine oxide

Cite this article

Zhu Ren-Yi , Liao Kui , Yu Jin-Sheng , Zhou Jian . Recent Advances in Catalytic Asymmetric Synthesis of P-Chiral Phosphine Oxides[J]. Acta Chimica Sinica, 2020 , 78(3) : 193 -216 . DOI: 10.6023/A20010002

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