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Acta Chimica Sinica >

2022 , Vol. 80 >Issue 10: 1410 - 1423

DOI: https://doi.org/10.6023/A22070314

Review

Key Advances of High-voltage Solid-state Lithium Metal Batteries Based on Poly(ethylene oxide) Polymer Electrolytes

  • Songwei Tian ,
  • Lixue Zhou ,
  • Bingqian Zhang ,
  • Jianjun Zhang ,
  • Xiaofan Du ,
  • Hao Zhang ,
  • Sijia Hu ,
  • Zhixiang Yuan ,
  • Pengxian Han ,
  • Suli Li ,
  • Wei Zhao ,
  • Xinhong Zhou ,
  • Guanglei Cui
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  • a Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, China
    b School of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, Shandong, China
    c Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
    d Zhuhai CosMX Battery Co., Ltd, Zhuhai 519180, Guangdong, China
†These authors contributed equally to this work
* E-mail: ;
;
; Tel.: 0532-80662746; Fax: 0532-80662744

Received date: 2022-07-18

  Online published: 2022-09-13

Supported by

Key-Area Research and Development Program of Guangdong Province(2020B090919005); National Natural Science Foundation of China(52073298); Youth Innovation Promotion Association of CAS(2020217); Natural Science Foundation of Shandong Province(ZR2019BEM037)

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Abstract

Traditional lithium-ion batteries employing carbonate-based liquid electrolytes might suffer from safety hazards such as leakage, combustion and explosion under abused conditions. In comparison, poly(ethylene oxide) (PEO) based solid-state polymer electrolytes can significantly enhance the safety performance of lithium batteries owing to their intrinsic safety. In addition, PEO can also be made into specific shapes to meet the harsh requirements of special fields owing of their excellent plasticity. More importantly, PEO-based solid-state polymer electrolytes possess superior interfacial compatibility with lithium metal anodes, endowing PEO a very promising solid polymer electrolyte (SPE) for solid-state lithium metal batteries. However, the low electrochemical oxidation potential of PEO-based solid polymer electrolytes makes them challenge to accommodate high-voltage cathodes (≥4 V), which greatly limits the energy density of solid-state polymer lithium metal batteries. Recently, through the unremitting efforts of researchers, PEO based solid-state polymer electrolytes have made a series of significant scientific progress in the field of high-voltage solid-state lithium metal batteries. Herein, this review presents an overview on the scientific challenges, fundamental mechanisms, and design strategies for high-voltage solid-state lithium batteries based on poly(ethylene oxide) all-solid-state polymer electrolytes: (1) constructing a ultra-thin layer on high-voltage cathodes, (2) surface coating of high-voltage cathode particles, (3) surface coating of carbon black, (4) employing carboxyl-rich polymer binders, (5) the design of asymmetric SPE architecture, (6) in-situ formation of high-concentration polymeric interlayer, (7) the introduction of -OCH3 group into PEO, (8) (oxalato)borate salts as additive. At the end of this review, the potential challenges and development trend of PEO-based solid-state polymer electrolytes in high-voltage lithium metal batteries are also elaborated.

Key words： solid-state polymer electrolytes; poly(ethylene oxide); high voltage; lithium metal batteries; stable interfacial chemistry

Cite this article

Songwei Tian , Lixue Zhou , Bingqian Zhang , Jianjun Zhang , Xiaofan Du , Hao Zhang , Sijia Hu , Zhixiang Yuan , Pengxian Han , Suli Li , Wei Zhao , Xinhong Zhou , Guanglei Cui . Key Advances of High-voltage Solid-state Lithium Metal Batteries Based on Poly(ethylene oxide) Polymer Electrolytes[J]. Acta Chimica Sinica, 2022 , 80(10) : 1410 -1423 . DOI: 10.6023/A22070314

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