Overview on Low-oxidation-state Alkaline Earth Organometallic Chemistry
Received date: 2024-10-28
Online published: 2024-12-25
Supported by
National Natural Science Foundation of China(22271312); start-up funds of Central South University and the Central South University Innovation-Driven Research Programme(2023CXQD047)
The chemistry of main group elements with low oxidation states occupies an important position in main group chemistry. Research results in this field can not only enrich the theoretical connotation of chemical bonding, but also have great significance in organometallic chemistry and catalysis, small molecule activation and transformation, etc. Compared with the chemistry of low-oxidation-state p-block elements, the s-block alkaline earth metal elements with low electronegativity can easily lose two valence electrons to form stable ＋2 oxidation state compounds, but it is more difficult to form low-oxidation-state species with relatively low stability and strong reducing property. Therefore, the study on low-oxidation-state alkaline earth organometallic chemistry is full of challenges. This review outlines the development history of low-oxidation-state alkaline earth organometallic chemistry, briefly describes the relatively mature low-oxidation-state magnesium chemistry, comprehensively introduces the low-oxidation-state beryllium chemistry that has recently made significant progress, highlights the low-oxidation-state calcium, strontium, and barium chemistry that still needs urgent breakthrough.
Rong Chen , Baosheng Wei . Overview on Low-oxidation-state Alkaline Earth Organometallic Chemistry[J]. Acta Chimica Sinica, 2025 , 83(2) : 139 -151 . DOI: 10.6023/A24100325
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