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0 202611 - 202611

DOI: https://doi.org/10.6023/A25110360

Research Progress on the Preparation and Recovery of Nuclear-Grade Zirconium Using Molten Salts

  • Zhou Mingyu ,
  • Liu Lebin ,
  • Mei Lei ,
  • Liu Yalan ,
  • Shi Weiqun
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  • a Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China;
    b Institute of Nuclear Fuel Cycle and Materials, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200030, China;
    c School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China

Online published: 2026-01-04

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Abstract

Nuclear-grade zirconium is a critical metallic material for nuclear power plants. It boasts a low neutron absorption cross-section and corrosion resistance that are far superior to those of ordinary commercial zirconium materials. With high economic value and vital strategic significance, it serves as a strategic reserve resource critical to national energy security. Consequently, the efficient and economical preparation and recovery of nuclear-grade zirconium have garnered increasing attention. Molten salt technology serves as a crucial pathway for the separation of zirconium and hafnium, the preparation of metallic zirconium, and the recycling of the used zirconium, offering advantages such as a simplified process and strong adaptability. This review outlines the key role of molten salts in the life cycle management of nuclear-grade zirconium, including the analysis and comparison of the application characteristics of different molten salt systems (fluoride, chloride, and fluorine-chloride mixed salt systems) in the preparation and recovery of metallic zirconium. In addition, it focuses on systematically sorting out and summarizing the electroreduction behavior of zirconium ions in molten salts, aiming to promote the green metallurgy and recycling of nuclear-grade zirconium.

Key words： nuclear-grade zirconium; molten salts; electrodeposition; electrorefining

Cite this article

Zhou Mingyu , Liu Lebin , Mei Lei , Liu Yalan , Shi Weiqun . Research Progress on the Preparation and Recovery of Nuclear-Grade Zirconium Using Molten Salts[J]. Acta Chimica Sinica, 0 : 202611 -202611 . DOI: 10.6023/A25110360

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