Self-Assembly of Polymer-Functionalized Carbon Nanotubes Induced by Polymer Microphase Separation

doi:10.6023/cjoc201301063

Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (07): 1509-1513.DOI: 10.6023/cjoc201301063 Previous Articles Next Articles

Articles

聚合物微相分离诱导聚合物功能化碳纳米管的自组装

郑兴良^a, 高鸿盛^a,b, 丁爱顺^a, 李永军^b

a 长沙理工大学化学与生物工程学院长沙 410076;
b 中国科学院上海有机化学研究所上海 200032

收稿日期:2013-01-24 修回日期:2013-02-20 发布日期:2013-02-22
通讯作者: 郑兴良, 李永军 E-mail:xingliangzheng@163.com;liyongjun78@sioc.ac.cn
基金资助:
国家自然科学基金(No. 20976017)和中国科学院上海有机化学研究所有机氟化学重点实验室开放基金2011资助项目.

Self-Assembly of Polymer-Functionalized Carbon Nanotubes Induced by Polymer Microphase Separation

Zheng Xingliang^a, Gao Hongsheng^a,b, Ding Aishun^a, Li Yongjun^b

a Institute of Chemistry and Biological Engineering, Changsha University of Science and Technology, Changsha 410076;
b Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received:2013-01-24 Revised:2013-02-20 Published:2013-02-22
Supported by:
Project supported by the National Natural Science Foundation of China (No. 20976017) and the 2011 Foundation of Key Laboratory of Organoflurine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.

It is of importance for the application of carbon nanotubes in composite materials via supramolecular self-assembly of surface-functionalized carbon nanotubes. Here the self-assembly of the mixture of poly(4-vinylpyridine) functionalized multi-walled carbon nanotubes and carboxyl-containing graft copolymer, poly(acrylic acid)-g-poly(methyl methacrylate) is reported. Because of the hydrogen bond between the pyridine nitrogen and the carboxyl of the graft copolymer, carbon nanotubes were induced to form organized structure during the polymer microphase separation process, which afforded a kind of honeycomb suprastructure containing carbon nanotubes.

Key words: carbon nanotube, self-assemble, microphase separation, composite materials

Cite this article

Zheng Xingliang, Gao Hongsheng, Ding Aishun, Li Yongjun. Self-Assembly of Polymer-Functionalized Carbon Nanotubes Induced by Polymer Microphase Separation[J]. Chin. J. Org. Chem., 2013, 33(07): 1509-1513.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Iijima, S. Nature 1991, 354, 56.
[2] (a) Wong, E. W.; Sheehan, P. E.; Lieber, C. M. Science 1997, 277, 1971. (b) Jia, N. Q.; Lian, Q.; Shen, H. B. Nano Lett. 2007, 7, 2976. (c) Bianco, A.; Kostarelos, K.; Partidos, C. D. Chem. Commun. 2005, 571.
[3] Park, H.; Afzali, A.; Han, S. J.; Tulevski, G. S.; Franklin, A. D.; Tersoff, J.; Hannon, J. B.; Haensch, W. Nat. Nanotechnol. 2012, 7, 787.
[4] (a) Liu, Z.; Sun, X. M.; Nakayama-Ratchford, N.; Dai, H. J. ACS Nano 2007, 1, 50. (b) Kong, H.; Gao, C.; Yan, D. Y. J. Am. Chem. Soc. 2004, 126, 412. (c) Guo, Z.; Ren, D. M.; Zheng, J. Y. Chin. J. Org. Chem. 2010, 30, 1101 (in Chinese). (郭震, 任冬梅, 郑健禺, 有机化学, 2010, 30, 1101.)
[5] (a) Yang, D.; Guo, G. Q.; Hu, J. H.; Wang, C.; Jiang, D. L. J. Mater. Chem. 2008, 18, 350. (b) Yang, D.; Yang, F.; Hu, J. H.; Long, J.; Wang, C. C.; Fu, D. L.; Ni, Q. X. Chem. Commun. 2009, 4447. (c) Yang, D.; Hu, J. H.; Wang, C. C. Carbon 2006, 44, 3161. (d) Yang, D.; Zhang, X. H.; Wang, C. C.; Tang, Y. T.; Li, J. J.; Hu, J. H. Prog. Nat. Sci. 2009, 19, 991.
[6] Pan, H. L.; Liu, L. Q.; Guo, Z. X.; Dai, L. M.; Zhang, F. S.; Zhu, D. B.; Czerw, R.; Carroll, D. L. Nano Lett. 2003, 3, 29.
[7] Gao, C. Macromol. Rapid Commun. 2006, 27, 841.
[8] Chen, Y.; Liu, H. P.; Ye, T.; Kim, J. K.; Mao, C. D. J. Am. Chem. Soc. 2007, 128, 8696.
[9] Takamori, H.; Fujigaya, T.; Yamaguchi, Y.; Nakashima, N. Adv. Mater. 2007, 19, 2535.
[10] Chen, D. Y.; Jiang, M. Acc. Chem. Res. 2005, 38, 499.
[11] Sun, Q. W.; Yu, Y.; Zhang, N.; Zhang, F. Y. Chin. J. Org. Chem. 2012, 32, 889 (in Chinese). (孙庆文, 于颖, 张南, 张法永, 有机化学, 2012, 32, 889.)
[12] (a) Peng, D.; Zhang, X. H.; Feng, C.; Lu, G. L.; Zhang, S.; Huang, X. Y. Polymer 2007, 48, 5250. (b) Huang, X. W.; Gu, L. N.; Lu, G. L.; Huang, X.; Zhang, Y. Q.; Huang, X. Y. Acta Chim. Sinica 2008, 66, 2653 (in Chinese). (黄晓炜, 顾丽娜, 陆国林, 黄啸, 张亚琴, 黄晓宇, 化学学报, 2008, 66, 2653.) (c) Huang, X. J.; Xiao, Y.; Lang, M. D. Macromol. Res. 2011, 19, 113. (d) Huang, X. J.; Xiao, Y.; Lang, M. D. Macromol. Res. 2012, 20, 597.
[13] (a) Ishizu, K.; Makino, M.; Uchida, S. Macromol. Rapid Commun. 2007, 28, 882. (b) Lan, P.; Li, J.; G. J. L.; Li, L. Acta Chim. Sinica 2012, 70, 45 (in Chinese). (兰平, 李剑, 龚剑亮, 李磊, 化学学报, 2012, 70, 45.)

聚合物微相分离诱导聚合物功能化碳纳米管的自组装

Self-Assembly of Polymer-Functionalized Carbon Nanotubes Induced by Polymer Microphase Separation

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 8

Recommended Articles

Metrics

Comments

[1]	Yang Yang, Li Ruomei, Wang Wei, Xu Zi-Wen, Xie Guanghui, Lu Zhengquan, Li Jingjing, Song Liping, Li Wei-Shi. Research Advances on the Mechanism of Polymer Solubilization and Selective Separation of Single-Wall Carbon Nanotubes [J]. Chinese Journal of Organic Chemistry, 2020, 40(10): 3249-3261.
[2]	Zhu Fangxia, Zhuang Yuan, Li Qing, Yang Qinglai, Wu Xinyan, Shao Zhifen, Gong Bin, Shen Yumei. Synthesis and Application of pH-Sensitive Linkers in Amphiphilic Block Copolymer [J]. Chin. J. Org. Chem., 2014, 34(9): 1806-1815.
[3]	Qingwen Sun, Ying Yu, Nan Zhang, Fayong Zhang. Preparation of Polyelectrolyte Functionalized Multiwalled Carbon Nanotubes via Surface-Initiated Atom Transfer Radical Polymerization [J]. Chin. J. Org. Chem., 2012, 32(05): 889-895.
[4]	GUO Zhen, REN Dong-Mei, ZHENG Jian-Yu. Advances in Porphyrin-Carbon Nanotube Hybrid Systems [J]. Chin. J. Org. Chem., 2010, 30(08): 1101-1112.
[5]	CHI Xing-Bao*^,a,LI You-Gui^b. A Novel Multifunctional Tetrathiafulvalene-cyclophane Based on Tetrathiafulvalene Units and Anthracene Units [J]. Chin. J. Org. Chem., 2008, 28(2): 266-273.
[6]	YUAN, Wei-Kang^a WU, Hong^a JIANG, Zhong-Yi*^,a^,b XU, Song-Wei^a^,b. Covalent Functionalization of Carbon Nanotubes [J]. Chin. J. Org. Chem., 2006, 26(11): 1508-1517.
[7]	YAN Xi*,ZHENG Ze-Bao,WU Fu-Li,LIU Yun,LI Jia-Mian,YAN Hui-Qing. Synthesis and Properties of Calixarene-porphyrin Conjugates [J]. Chin. J. Org. Chem., 2005, 25(04): 375-385.
[8]	Feng Xinliang;Guan Chuanjin;Zhao Chengxue. Progress of Cation-Exchange Resins in Organic Catalysis [J]. Chin. J. Org. Chem., 2003, 23(12): 1348-1355.