Crown Ether Chemistry of Polydentate Complexing for Lithium Isotope Separation

doi:10.6023/cjoc201307029

Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (2): 316-324.DOI: 10.6023/cjoc201307029 Previous Articles Next Articles

Reviews

多齿络合法分离锂同位素的冠醚化学

刘华^a, 黄祚刚^a, 文珂^a, 姜标^a,b

a 中国科学院上海高等研究院上海 201210;
b 中国科学院上海有机化学研究所上海 200032

收稿日期:2013-07-19 修回日期:2013-10-11 发布日期:2013-10-16
通讯作者: 黄祚刚, 文珂, 姜标 E-mail:jiangb@sari.ac.cn
基金资助:
中国科学院战略性先导科技专项（No.XDA01020304）资助项目.

Crown Ether Chemistry of Polydentate Complexing for Lithium Isotope Separation

Liu Hua^a, Huang Zuogang^a, Wen Ke^a, Jiang Biao^a,b

a Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210;
b Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received:2013-07-19 Revised:2013-10-11 Published:2013-10-16
Supported by:
Project supported by the "Stategic Priority Research Program" of the Chinese Academy of Science (No. XDA01020304).

The two naturally occurring isotopes of lithium, ⁶Li and ⁷Li, have important roles in the nuclear energy industry. Among many techniques for the separation of lithium isotopes, high isotope separation factors are usually realized with the polydentate complex method. Crown ethers, for their selective-complexing ability with metal cations, have been regarded as perhaps the most effective extractants for lithium isotope separation. This review summarizes the application of crown ether and crown ether chelating resin for lithium isotope separation based on polydentate complexing method, exemplify recent developments in complexation of metal-containing crown ethers with metal cations, and prospect their potential in separation of lithium isotopes.

Key words: lithium isotope separation, polydentate complex, crown ether, crown ether chelating resin, metal-containing crown ethers

Cite this article

Liu Hua, Huang Zuogang, Wen Ke, Jiang Biao. Crown Ether Chemistry of Polydentate Complexing for Lithium Isotope Separation[J]. Chin. J. Org. Chem., 2014, 34(2): 316-324.

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多齿络合法分离锂同位素的冠醚化学

Crown Ether Chemistry of Polydentate Complexing for Lithium Isotope Separation

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