One-Pot Synthesis of A New [2]rotaxane Based on the Phenylene-Diacetylene Crown Ether

doi:10.6023/cjoc201406009

Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (12): 2559-2565.DOI: 10.6023/cjoc201406009 Previous Articles Next Articles

Notes

一锅法合成基于丁二炔-苯环冠醚的[2]轮烷

陈木娟, 郭浩玉, 周松根, 陈坤, 蒋腊生

华南师范大学化学与环境学院广州 510006

收稿日期:2014-06-07 修回日期:2014-07-19 发布日期:2014-08-11
通讯作者: 蒋腊生 E-mail:jianglsh@scnu.edu.cn
基金资助:
国家自然科学基金(No.21072066)和广东省省部产学研基金(No.2012B090700003)资助项目.

One-Pot Synthesis of A New [2]rotaxane Based on the Phenylene-Diacetylene Crown Ether

Chen Mujuan, Guo Haoyu, Zhou Songgen, Chen Kun, Jiang Lasheng

School of Chemistry and Environment, South China Normal University, Guangzhou 510006

Received:2014-06-07 Revised:2014-07-19 Published:2014-08-11
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21072066) and the Key Project on the Integration of Industry, Education and Research of Guangdong Province (No. 2012B090700003).

A new [2]rotaxane was synthesized via one-pot method, based on the assembly of the phenylene-diacetylene crown ether (acted as ring molecule) and the paraquat derivative (acted as semi-axle molecule). The HR-MS, ¹H NMR and ¹³C NMR spectra have confirmed that one phenylene-diacetylene crown ether ring threaded though the axle molecule forming the corresponding [2]rotaxane, and the macrocyclic ring moves from one 4,4'-bipyridinium station to another 4,4'-bipyridinium station.

Key words: phenylene-diacetylene crown ether, one-pot method, synthesis, [2]rotaxane

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Chen Mujuan, Guo Haoyu, Zhou Songgen, Chen Kun, Jiang Lasheng. One-Pot Synthesis of A New [2]rotaxane Based on the Phenylene-Diacetylene Crown Ether[J]. Chin. J. Org. Chem., 2014, 34(12): 2559-2565.

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一锅法合成基于丁二炔-苯环冠醚的[2]轮烷

One-Pot Synthesis of A New [2]rotaxane Based on the Phenylene-Diacetylene Crown Ether

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