Linear and Nonlinear Optical Properties of meso-Tetra(4-ferrocenylcarbonyloxyphenyl)porphyrin and Its Zinc(Ⅱ) Complex

doi:10.6023/cjoc201308036

Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (2): 371-375.DOI: 10.6023/cjoc201308036 Previous Articles Next Articles

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meso-四(4-二茂铁甲酰氧基苯基)卟啉及其锌配合物的线性与非线性光学性质

赵海英^a, 顾雪松^a, 鄢小卿^b, 刘智波^b, 陈强^a, 边占喜^a

a 内蒙古大学化学化工学院呼和浩特 010021;
b 南开大学泰达应用物理学院弱光非线性光子学教育部重点实验室天津 300457

收稿日期:2013-08-28 修回日期:2013-09-19 发布日期:2013-10-25
通讯作者: 边占喜 E-mail:bzx1957@sina.com
基金资助:
国家自然科学基金（Nos.21102068，11174159）和内蒙古自治区自然科学基金（No.2013MS0207）资助项目.

Linear and Nonlinear Optical Properties of meso-Tetra(4-ferrocenylcarbonyloxyphenyl)porphyrin and Its Zinc(Ⅱ) Complex

Zhao Haiying^a, Gu Xuesong^a, Yan Xiaoqing^b, Liu Zhibo^b, Chen Qiang^a, Bian Zhanxi^a

a College of Chemistry and Chemical Engineering, Inner Mongolia University, Huhhot 010021;
b Key Laboratory of Weak Light Nonlinear Photonics Ministry of Education and Teda Applied Physics School, Nankai University, Tianjin 300457

Received:2013-08-28 Revised:2013-09-19 Published:2013-10-25
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21102068, 11174159) and the Natural Science Foundation of Inner Mongolia (No. 2013MS0207).

meso-Tetra(4-ferrocenylcarbonyloxyphenyl)porphyrin and its zinc(Ⅱ) complex were synthesized. Their linear and nonlinear optical properties were investigated using UV-Vis absorption spectra, steady state and time-resolved fluorescence spectra and open-aperture Z-scan measurements. The results indicated that the introduction of ferrocene to porphyrin had not affected the absorption spectra of porphyrin, but quenched the fluorescence intensively and shortened the fluorescence lifetimes of porphyrin, which indicated that there was almost no interaction between porphyrin and ferrocene in the ground state, but a strong interaction in the excited state. The reverse saturable absorptions of meso-tetra(4-ferrocenylcarbonyloxyphenyl)- porphyrin and its zinc(Ⅱ) complex were weaker than those of the corresponding meso-tetra(4-benzoyloxyphenyl)porphyrin and its zinc(Ⅱ) complex, but were stronger than that of fullerene C₆₀ with excellent performance.

Key words: ferrocene, porphyrin, spectral property, Z-scan

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Zhao Haiying, Gu Xuesong, Yan Xiaoqing, Liu Zhibo, Chen Qiang, Bian Zhanxi. Linear and Nonlinear Optical Properties of meso-Tetra(4-ferrocenylcarbonyloxyphenyl)porphyrin and Its Zinc(Ⅱ) Complex[J]. Chin. J. Org. Chem., 2014, 34(2): 371-375.

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meso-四(4-二茂铁甲酰氧基苯基)卟啉及其锌配合物的线性与非线性光学性质

Linear and Nonlinear Optical Properties of meso-Tetra(4-ferrocenylcarbonyloxyphenyl)porphyrin and Its Zinc(Ⅱ) Complex

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