Rencent Advances in Asymmetric Michael Addition Catalyzed by Chiral Bifunctional Thioureas

doi:10.6023/cjoc201402029

Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (8): 1509-1522.DOI: 10.6023/cjoc201402029 Previous Articles Next Articles

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双功能手性硫脲催化的不对称Michael加成反应研究进展

侯学会^a, 马志伟^a,b, 王建玲^a, 刘宏民^c

a 河南牧业经济学院质检系郑州 450011;
b 郑州大学化学与分子工程学院郑州 450001;
c 郑州大学药学院郑州 450001

收稿日期:2014-02-24 修回日期:2014-03-12 发布日期:2014-04-28
通讯作者: 侯学会，刘宏民 E-mail:houxh2006@163.com;liuhm@zzu.edu.cn
基金资助:
河南省教育厅科学技术研究重点（Nos.14A150052，12A150026）、郑州市科技攻关计划（No.121PPTGG509-2）资助项目.

Rencent Advances in Asymmetric Michael Addition Catalyzed by Chiral Bifunctional Thioureas

Hou Xuehui^a, Ma Zhiwei^a,b, Wang Jianling^a, Liu Hongmin^c

a Department of Quality Detection and Management, Henan University of Animal Husbandry and Economy, Zhengzhou 450011;
b College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001;
c School of Pharmaceutical Science, Zhengzhou University, Zhengzhou 450001

Received:2014-02-24 Revised:2014-03-12 Published:2014-04-28
Supported by:
Project supported by the Science and Technology Research Projects of Education Department of Henan Province (Nos. 14A150052, 12A150026), the Scientific Research Plan of Zhenzhou City (No. 121PPTGG509-2).

Asymmetric organocatalysis has been a frontier in the field of asymmetric catalysis. The comparable advantages, including mild reaction conditions, environment benign, and so on, render the organocatalytic reaction to possess some features of green chemistry. Chiral amino-thiourea organocatalyst, especially chiral bifunctional thiourea, has been shown excellent catalytic performance in a variety of asymmetric reactions. This review provides an overview of applications of chiral bifunctional thiourea in asymmetry Michael addition reaction, and the prospect and development are depicted finally.

Key words: organocatalysis, bifunctional, chiral thiourea, Michael addition

Cite this article

Hou Xuehui, Ma Zhiwei, Wang Jianling, Liu Hongmin. Rencent Advances in Asymmetric Michael Addition Catalyzed by Chiral Bifunctional Thioureas[J]. Chin. J. Org. Chem., 2014, 34(8): 1509-1522.

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双功能手性硫脲催化的不对称Michael加成反应研究进展

Rencent Advances in Asymmetric Michael Addition Catalyzed by Chiral Bifunctional Thioureas

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