Synthesis of Esters via Barbier Reaction Mediated by Zinc Copper Couple under Solvent-Free Conditions

doi:10.6023/cjoc201409044

Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (3): 712-718.DOI: 10.6023/cjoc201409044 Previous Articles Next Articles

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无溶剂条件下通过锌铜偶促进的Barbier反应合成羧酸酯

孟团结^a,b, 黄现强^a, 王进贤^a, 辛丽^a

a 西北师范大学化学化工学院兰州 730070;
b 商丘师范学院化学化工学院有机新材料合成重点实验室商丘 476000

收稿日期:2014-09-26 修回日期:2014-10-02 发布日期:2014-11-13
通讯作者: 孟团结, 王进贤 E-mail:tuanjiemeng@163.com;wangjx@nwnu.edu.cn
基金资助:
国家自然科学基金(No. U1204204)资助项目.

Synthesis of Esters via Barbier Reaction Mediated by Zinc Copper Couple under Solvent-Free Conditions

Meng Tuanjie^a,b, Huang Xianqiang^a, Wang Jin-Xian^a, Xin Li^a

a College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070;
b Key Laboratory of New Organic Materials synthesis, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000

Received:2014-09-26 Revised:2014-10-02 Published:2014-11-13
Supported by:
Project supported by the National Natural Science Foundation of China (No. U1204204).

1. Synthesis of Esters via Barbier Reaction Mediated by Zinc Copper Couple under Solvent-Free Conditions.PDF(3630KB)

Abstract

A series of homoallyl esters, homopropargyl esters and β-acetoxyl esters were obtained via Barbier reaction from one pot three component reaction of aldehydes, bromohydrocarbons and anhydrides mediated by zinc copper couple under non-catalytic and solvent-free conditions. The studies on the reaction conditions and the reaction mechanism were also carried out. This protocol has advantages of mild conditions, simple work-up, high yield, easily available starting materials and fast reaction rate.

Key words: Barbier reaction, zinc copper couple, one-pot, solvent-free

Cite this article

Meng Tuanjie, Huang Xianqiang, Wang Jin-Xian, Xin Li. Synthesis of Esters via Barbier Reaction Mediated by Zinc Copper Couple under Solvent-Free Conditions[J]. Chin. J. Org. Chem., 2015, 35(3): 712-718.

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无溶剂条件下通过锌铜偶促进的Barbier反应合成羧酸酯

Synthesis of Esters via Barbier Reaction Mediated by Zinc Copper Couple under Solvent-Free Conditions

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