Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (7): 1677-1680.DOI: 10.6023/cjoc201602002 Previous Articles     Next Articles



王立军, 刘彩云, 熊娟, 胡金锋   

  1. 复旦大学药学院 上海 201203
  • 收稿日期:2016-02-01 修回日期:2016-03-04 发布日期:2016-03-28
  • 通讯作者: 胡金锋
  • 基金资助:


Further Chemical Constituents from the Rare Chloranthaceae Plant Chloranthus sessilifolius

Wang Lijun, Lau Choiwan, Xiong Juan, Hu Jinfeng   

  1. School of Pharmacy, Fudan University, Shanghai 201203
  • Received:2016-02-01 Revised:2016-03-04 Published:2016-03-28
  • Supported by:

    Project supported by National Natural Science Foundation of China (Nos. 21472021, 81273401, 21575029) and the National Basic Research Program of China (973 Program, No. 2013CB530700).

Two diterpenoids and a few miscellaneous components (one phenethylpropanoid, one flavonoid, and one lignan) were isolated from the MeOH extract of the whole plant of the rare Chloranthaceae plant Chloranthus sessilifolius during a further phytochemical reinvestigation. Based on their spectroscopic data (i.e., IR, UV, 1D/2D NMR, ECD, and HR-ESIMS) and/or comparing with those reported physicochemical data in related literature, the structures were determined to be (3R,5S,6S,9S,10S,13S)-3,6,13-trihydroxy-ent-abieta-8(14)-en-7-one (1), 3α,15-dihydroxy-13α-methoxy-ent-abieta-8(14)-en- 7-one (2), p-coumaroyl-β-phenethyl amine (3), narigenin trimethyl ether (4), and (3R,4R,3'R,4'R)-6,6'-dimethoxy-3,4,3',4'- tetrahydro-2H,2H'-[3,3']-bichromenyl-4,4'-diol (5). Among them, compound 1 is new, while compounds 3~5 were isolated from the Chloranthus genus for the first time.

Key words: Chloranthus sessilifolius, Chloranthaceae, chemical constituents, ent-abietane-type diterpenoids