Complexation of Novel Water-Soluble Cylindrical Macrotricyclic Host and Paraquat

doi:10.6023/cjoc201603024

Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (8): 1937-1941.DOI: 10.6023/cjoc201603024 Previous Articles Next Articles

NOTE

新型水溶性圆柱形大三环主体与联吡啶盐的络合性能研究

曾飞^a, 唐琳俐^a, 陈小明^a, 李治章^a, 韩莹^b, 陈传峰^b

a 湖南科技学院化学与生物工程学院湘南优势植物资源综合利用湖南省重点实验室永州 425199;
b 中国科学院化学研究所分子识别与功能院重点实验室北京 100190

收稿日期:2016-03-15 修回日期:2016-03-30 发布日期:2016-04-15
通讯作者: 曾飞, 陈传峰 E-mail:zengfei@iccas.ac.cn;cchen@iccas.ac.cn
基金资助:
湖南省高校科技创新团队及湖南省有机化学重点学科（2016）资助项目.

Complexation of Novel Water-Soluble Cylindrical Macrotricyclic Host and Paraquat

Zeng Fei^a, Tang Linli^a, Chen Xiaoming^a, Li Zhizhang^a, Han Ying^b, Chen Chuanfeng^b

a Key Laboratory Comprehensive Utilization of Dominant Plants Resources in South Hunan, Department of Biology and Chemistry, Hunan University of Science and Engineering, Yongzhou 425199;
b CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190

Received:2016-03-15 Revised:2016-03-30 Published:2016-04-15
Supported by:
Project supported by the Sci-Tech Innovation Teams in Universities of Hunan Province and the Construct Program of the Key Discipline in Hunan Province (2016).

1. Complexation of Novel Water-Soluble Cylindrical Macrotricyclic Host and Paraquat.PDF(503KB)

Abstract

The complexation between the novel water-soluble cylindrical macrotricyclic host and paraquat guests in both solution and solid state was investigated in detail. It was found that the host could form 1:1 complexes with paraquat salts in water solution and solid state. Interestingly, the complexation and decomplexation of the complexes between the host and the guest could be achieved by changing the pH of the solution, and the process could also be observed by naked eye.

Key words: macrotricyclic host, paraquat, complexation, acid-base controlled

Cite this article

Zeng Fei, Tang Linli, Chen Xiaoming, Li Zhizhang, Han Ying, Chen Chuanfeng. Complexation of Novel Water-Soluble Cylindrical Macrotricyclic Host and Paraquat[J]. Chin. J. Org. Chem., 2016, 36(8): 1937-1941.

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新型水溶性圆柱形大三环主体与联吡啶盐的络合性能研究

Complexation of Novel Water-Soluble Cylindrical Macrotricyclic Host and Paraquat

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