Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (2): 486-491.DOI: 10.6023/cjoc201707017 Previous Articles     Next Articles



胡传峰, 周建豪, 黄志达, 傅惠惠, 彭新华   

  1. 南京理工大学化工学院 南京 210094
  • 收稿日期:2017-07-12 修回日期:2017-08-24 发布日期:2017-10-11
  • 通讯作者: 彭新华

Metal Molybdate Catalysts for the Selective Oxidation of Olefins and Alcohols Using Hydrogen Peroxide as Oxidant

Hu Chuanfeng, Zhou Jianhao, Huang Zhida, Fu Huihui, Peng Xinhua   

  1. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094
  • Received:2017-07-12 Revised:2017-08-24 Published:2017-10-11
  • Contact: 10.6023/cjoc201707017

Several facile metal molybdates were prepared by hydrothermal method and characterized by X-ray diffraction (XRD). Meanwhile, the bimetallic combination effect of these metal molybdates as bimetallic catalysts applied to the selective oxidation of various olefins and alcohols was investigated. It was found that there was the existence of bimetallic combination effect and the combination of Co and Mo had benignant effect compared with the individual metal catalysts and other metal molybdates in the reaction of oxidizing olefins to aldehydes. This bimetallic catalyst also showed very prominent performance (selectivity is 100%) in the oxidation of the alcohols to corresponding carbonyl compounds. The combination of double metal provides a method for the catalytic oxidation of olefins and alcohols.

Key words: metal molybdates, benzaldehyde, bimetallic combination, selective oxidation