Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (4): 912-918.DOI: 10.6023/cjoc201708057 Previous Articles     Next Articles


邢刘桩a, 侯亚东a, 邢雪建a, 惠永海a,b   

  1. a 石油天然气精细化工教育部&新疆维吾尔自治区重点实验室 新疆大学化学化工学院 乌鲁木齐 830046;
    b 岭南师范学院化学化工学院 湛江 524048
  • 收稿日期:2017-08-29 修回日期:2017-11-21 发布日期:2017-12-01
  • 通讯作者: 惠永海
  • 基金资助:


MCM-41@Schiff Base-Mn(OAc)2 Catalyzed Synthesis of Xanthene Derivatives in Water

Xing Liuzhuanga, Hou Yadonga, Xing Xuejiana, Hui Yonghaia,b   

  1. a Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046;
    b School of Chemistry and Chemistry Engineering, Lingnan Normal University, Zhanjiang 524048
  • Received:2017-08-29 Revised:2017-11-21 Published:2017-12-01
  • Contact: 10.6023/cjoc201708057
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21362036, 21161026).

MCM-41@Schiff base-Mn(OAc)2, a heterogeneous catalyst, was used for one pot synthesis of xanthene derivatives in water with aldehydes, 5,5-dimethyl-1,3-cyclohexanedione and 2-naphthol. This method exhibited some advantages including excellent yields, environmentally benign and good functional group tolerance, and the catalytic system presented some features of the less amount of catalyst and excellent reusability by experiment.

Key words: MCM-41, aqueous phase, xanthene, heterogeneous catalyst