Mesoporous MCM-41 Supported Schiff Base-Cu(ClO4)2·6H2O Catalyzed Synthesis of Spiro[indole-thiazolidine] Derivatives

doi:10.6023/cjoc201801039

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (8): 2036-2044.DOI: 10.6023/cjoc201801039 Previous Articles Next Articles

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介孔分子筛MCM-41固载席夫碱与Cu(ClO₄)₂·6H₂O催化合成螺[吲哚-噻唑啉酮]衍生物

侯亚东^a, 庞海霞^a, 杨超^a, 惠永海^a,b

a 新疆大学化学化工学院石油天然气精细化工教育部重点实验室乌鲁木齐 830046;
b 岭南师范学院化学化工学院湛江 524048

收稿日期:2018-01-26 修回日期:2018-04-18 发布日期:2018-05-03
通讯作者: 杨超, 惠永海 E-mail:jerryyang1924@163.com;hyhai97@126.com
基金资助:
国家自然科学基金（Nos.21362036，51564045）资助项目.

Mesoporous MCM-41 Supported Schiff Base-Cu(ClO₄)₂·6H₂O Catalyzed Synthesis of Spiro[indole-thiazolidine] Derivatives

Hou Yadong^a, Pang Haixia^a, Yang Chao^a, HuiYonghai^a,b

a Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046;
b School of Chemistry and Chemistry Engineering, Lingnan Normal University, Zhanjiang 524048

Received:2018-01-26 Revised:2018-04-18 Published:2018-05-03
Contact: 10.6023/cjoc201801039 E-mail:jerryyang1924@163.com;hyhai97@126.com
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21362036, 51564045).

1. Mesoporous MCM-41 Supported Schiff Base-Cu(ClO₄)₂·6H₂O Catalyzed Synthesis of Spiro[indole-thiazolidine] Derivatives.PDF(801KB)

Abstract

Herein, Michael addition-condensation of isatin-3-imines with mercaptoacetic acid to afford a new simple and efficient synthesis of spiro[indole-thiazolidine] derivatives in high yield (up to 99%) by using of MCM-41@Schiff base-Cu(ClO₄)₂·6H₂O as heterogeneous catalyst is reported. In addition, it is found that heterogeneous catalyst exhibits better activity than homogeneous catalyst in the same functional groups. The effect of the pore structure on mesoporous molecular sieve nanoreactor MCM-41 for this reaction is further explored. Consistent activity of recovered catalyst was found to be almost same up to six cycles in 93% yield.

Key words: MCM-41, heterogeneous catalyst, spiro[indole-thiazolidine], nano-reactors

Cite this article

Hou Yadong, Pang Haixia, Yang Chao, HuiYonghai. Mesoporous MCM-41 Supported Schiff Base-Cu(ClO₄)₂·6H₂O Catalyzed Synthesis of Spiro[indole-thiazolidine] Derivatives[J]. Chin. J. Org. Chem., 2018, 38(8): 2036-2044.

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介孔分子筛MCM-41固载席夫碱与Cu(ClO₄)₂·6H₂O催化合成螺[吲哚-噻唑啉酮]衍生物

Mesoporous MCM-41 Supported Schiff Base-Cu(ClO₄)₂·6H₂O Catalyzed Synthesis of Spiro[indole-thiazolidine] Derivatives

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介孔分子筛MCM-41固载席夫碱与Cu(ClO4)2·6H2O催化合成螺[吲哚-噻唑啉酮]衍生物