Supramolecular Assembly Based on the Novel Sail-Boat-Shaped Self-Complexes

doi:10.6023/cjoc201810001

Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (3): 720-726.DOI: 10.6023/cjoc201810001 Previous Articles Next Articles

Special Issue: 有机超分子化学合辑

Articles

基于新型帆船型络合物的超分子组装

张世龙, 蒋腊生

华南师范大学化学与环境学院广州 510006

收稿日期:2018-10-01 修回日期:2018-10-29 发布日期:2018-11-26
通讯作者: 蒋腊生 E-mail:742923272@qq.com
基金资助:
国家自然科学基金（No.21072066）、广东省省部产学研基金（No.2012B090700003）和华南师范大学青年教师科研培育基金（No.14KJ02）资助项目.

Supramolecular Assembly Based on the Novel Sail-Boat-Shaped Self-Complexes

Zhang Shilong, Jiang Lasheng

School of Chemistry and Environment, South China Normal University, Guangzhou 510006

Received:2018-10-01 Revised:2018-10-29 Published:2018-11-26
Contact: 10.6023/cjoc201810001 E-mail:742923272@qq.com
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21072066), the Key Project on the Integration of Industry, Education and Research of Guangdong Province (No. 2012B090700003), and the Foundation of Young Teachers of South China Normal University (No.14KJ02).

1. Supramolecular Assembly Based on the Novel Sail-Boat-Shaped Self-Complexes.PDF(1212KB)

Abstract

Owing to the unique macrocyclic-cavity structure of crown ether and the capability of complexing with guest molecules, our group successfully designed and synthesized a novel Sailboat-Shaped self-complex by using intramolecular hydrogen bonds, which are able to switch its configuration during the different pH value. Furthermore, a novel catenane which based on the sailboat-shaped self-complex was obtained by using intermolecular charge transfer interaction and through the template-directed method, and its structure was identified by ¹H NMR, ¹³C NMR, HRMS and ¹H-¹H NOESY. It is hoped that it can be successfully controlled by the pH value conversion.

Key words: self-complexes, charge transfer interaction, catenane

Cite this article

Zhang Shilong, Jiang Lasheng. Supramolecular Assembly Based on the Novel Sail-Boat-Shaped Self-Complexes[J]. Chin. J. Org. Chem., 2019, 39(3): 720-726.

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基于新型帆船型络合物的超分子组装

Supramolecular Assembly Based on the Novel Sail-Boat-Shaped Self-Complexes

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