Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (4): 899-912.DOI: 10.6023/cjoc201909035 Previous Articles     Next Articles

Special Issue: 镍催化有机反应虚拟合辑


孙越a, 关瑞a, 刘兆洪a, 王也铭b   

  1. a 东北师范大学化学学院 长春 130024;
    b 吉林工程技术师范学院化学与工业生物工程交叉学科研究院 长春 130052
  • 收稿日期:2019-09-26 修回日期:2019-11-15 发布日期:2019-12-19
  • 通讯作者: 王也铭, 刘兆洪;

Recent Advances in Hydroboration of Alkenes Catalyzed by Fe, Co and Ni

Sun Yuea, Guan Ruia, Liu Zhaohonga, Wang Yemingb   

  1. a Department of Chemistry, Northeast Normal University, Changchun 130024;
    b Institute of Chemical and Industrial Bioengineering, Jilin Engineering Normal University, Changchun 130052
  • Received:2019-09-26 Revised:2019-11-15 Published:2019-12-19

The synthesis of alkyl boronic esters has attracted much attention because of their wide applications in organic synthesis, materials and medicines. Transition-metal catalyzed hydroboration of alkenes was one of the most effective methods to construct alkyl boronic esters. Compared with rhodium, ruthenium, palladium, iridium and other precious metal catalysts, iron, cobalt and nickel catalysts were not only low cost, but also they displayed unique reactivity and selectivity. In this paper, the important advances in hydroboration of alkenes catalyzed by iron, cobalt and nickel have been summarized since 1994, including catalytic activity, selectivity and substrate scope of different catalytic systems.

Key words: iron-catalysis, cobalt-catalysis, nickel-catalysis, hydroboration, regio-selectivity