The first carbene-catalyzed enantioselective 1,6-conjugate addition of boron to para-quinone methides was achieved by using the commercially available chiral triazolium and bis(pinacolato)diboron. The main features of this reaction include mild conditions, broad scope of substrates, excellent functional group tolerance, as well as good yield and enantioselectivity. Notably, in the absence of any transition metals, the reaction proceeded very well even with 0.1 mol% of catalyst loading without obvious erosion of yield and enantioselectivity, albeit longer reaction time was required.