Chinese Journal of Organic Chemistry 2022, 42(5)

- About the Cover:
  
  Structurally diverse polycyclic benzimidazole[2,1-a] isoquinolines are important synthetic intermediates and key structural motifs in biologically active molecules. In this work, a AgSCF₃-mediated oxidative radical cascade cyclization is reported by Liu, Wang, Sun, Tang and Wang on page 1387, which features ease of handling, a wide substrate scope, good functional group compatibility, easily scaled-up operation, and facile derivatization.
- About the Cover:
  
  Structurally diverse polycyclic benzimidazole[2,1-a] isoquinolines are important synthetic intermediates and key structural motifs in biologically active molecules. In this work, a AgSCF₃-mediated oxidative radical cascade cyclization is reported by Liu, Wang, Sun, Tang and Wang on page 1387, which features ease of handling, a wide substrate scope, good functional group compatibility, easily scaled-up operation, and facile derivatization.
2022, 42(5)

25 May 2022
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REVIEWS

Progress in the Synthesis of Boron Dipyrromethene (BODIPY) Fluorescent Dyes

Bin-Kai Liu, Kun-Xu Teng, Li-Ya Niu, Qing-Zheng Yang

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1265-1285 DOI: 10.6023/cjoc202111001

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Electrooxidative Annulation of Unsaturated Molecules via Directed C—H Activation

Wucheng Xie, Xu Chen, Yunyue Li, Jieling Lin, Wanwen Chen, Junjun Shi

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1286-1306 DOI: 10.6023/cjoc202110028

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Research Progress on the Synthesis and Activity of D-Galactose Derived Small Galectin Inhibitors

Can Yong, Yun Li, Tao Bi, Guofeng Chen, Dongxia Zheng, Zhouyu Wang, Yuanyuan Zhang

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1307-1325 DOI: 10.6023/cjoc202110036

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Progress in Rare-Earth Metal-Based Lewis Pair Chemistry

Yiwen Guan, Kejian Chang, Qianlin Sun, Xin Xu

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1326-1335 DOI: 10.6023/cjoc202112008

Abstract( 856) HTML( 34) PDF(683KB)( 723 )

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Advances on the Synthesis of N—N Bonds

Weizhe Zhao, Jiali Xu, Fan Yang, Xianghua Zeng

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1336-1345 DOI: 10.6023/cjoc202111019

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Research Progress on Density Functional Theory Study of Palladium-Catalyzed C—H Functionalization to Form C—X (X=O, N, F, I, …) Bonds

Yubing Shi, Wenji Bai, Weihua Mu, Jiangping Li, Jiawei Yu, Bing Lian

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1346-1374 DOI: 10.6023/cjoc202110027

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Recent Progress on Strategies and Applications of Imaging for Intestinal Microflora

Na Li, Xiaofeng Tan, Qinglai Yang

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1375-1386 DOI: 10.6023/cjoc202112022

Abstract( 567) HTML( 37) PDF(13290KB)( 430 )

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ARTICLES

Silver-Mediated Radical Trifluoromethylthiolation Cyclization: Synthesis of CF₃S-Containing Benzimidazole[2,1-a]isoquinolines

Bing Liu, Zhichuang Wang, Kai Sun, Shi Tang, Xin Wang

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1387-1395 DOI: 10.6023/cjoc202203053

Abstract( 616) HTML( 15) PDF(563KB)( 468 )

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Photoredox Catalytic Cascade Radical Addition to Construct 1,4- Diketone-Functionalized Quinoxalin-2(1H)-one Derivatives

Xin Sun, Chaofan Qu, Chaorui Ma, Xiaowei Zhao, Guobi Chai, Zhiyong Jiang

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1396-1406 DOI: 10.6023/cjoc202201025

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Homogeneous Catalytic Hydrogenation of Dimethyl Malonate into 1,3-Propanediol

Xiaolong Fang, Bin Li, Jie Jin, Ning Duan

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1407-1413 DOI: 10.6023/cjoc202202034

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Photoredox-Copper Dual-Catalyzed Site-Selective O-Alkylation of Glycosides

Tianyi Sun, Yifan Zhang, Yuanjie Meng, Yi Wang, Qifeng Zhu, Yuxin Jiang, Shihui Liu

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1414-1422 DOI: 10.6023/cjoc202112029

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Synthesis and Electroluminescent Properties of Red-Emitting Iridium Complexes Based on Benzofuran-Isoquinoline

Fei Nie, Guanbo Huang, Lei Dai, Shaofu Chen, Shaomin Ji, Jiaxiong Chen, Yanping Huo

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1423-1430 DOI: 10.6023/cjoc202112039

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Radical Aminoselenation of Styrenes: Facile Access to β-Amido-selenides

Yifan Yin, Chen Li, Kai Sun, Yingjie Liu, Xin Wang

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1431-1437 DOI: 10.6023/cjoc202112028

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I₂/t-Butylhydroperoxide (TBHP)-Mediated Oxo-amidation of Alkenes with N,N-Dimethylformamide: A Facile Access to Aryl-α-ketoamide Derivatives

Duoduo Xiao, Hailing Liu, Peng Zhou, Jiantao Zhang, Weibing Liu

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1438-1442 DOI: 10.6023/cjoc202110005

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Visible Light-Induced Metal-Free Benzylation of Quinones via Cross Dehydrogenation Coupling Reaction

Xinyao Wang, Qingqing Zhang, Shuyang Liu, Min Li, Haifang Li, Chunying Duan, Yunhe Jin

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1443-1452 DOI: 10.6023/cjoc202112018

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Design, Synthesis of Pentacyclic Triterpenoid Glucose Conjugate and in vitro Activity against Influenza Virus

Ming Cai, Liang Shao, Fan Yang, Jihong Zhang, Fei Yu

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1453-1462 DOI: 10.6023/cjoc202111008

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Synthesis of Triazole Functionalized Triphenylamine Cu²⁺ Fluorescent Probe and Its Application in Detection and HeLa Cells

Yiping Wen, Zhengfeng Xie, Tianzhu Shi, Yicheng Chu, Ronggui Zhou, Yishan Tao, Huanmin Liang, Haiyan Qiu, Yunhui Zhao

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1463-1473 DOI: 10.6023/cjoc202111013

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Mono-(6-diethylenetriamine-6-deoxy)-β-cyclodextrin Supramolecular Fluorescent Switch Constructed Based on Au³⁺ and I^–

Jiajia Lu, Junli Yang, Jie Gu, Ju Yang, Zhenjie Gao, Lijiao Su, Xin Tao, Mingwei Yuan, Lijuan Yang

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1474-1482 DOI: 10.6023/cjoc202111024

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Asymmetric Boration of para-Quinone Methides Catalyzed by N-Heterocyclic Carbene

Yuzhu Wu, Panpan Shen, Wenzeng Duan, Yudao Ma

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1483-1492 DOI: 10.6023/cjoc202111041

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Visible Light-Induced Hydroxyalkylation of Heteroarenes with Aliphatic Alcohols

Dongping Xu, Fei Huang, Lin Tang, Xinming Zhang, Wu Zhang

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1493-1500 DOI: 10.6023/cjoc202112032

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Synthesis of Tetrahydroindole Derivatives via Metal-Free Intramolecular [4+2] Annulation of Ynamides

Zhixin Zhang, Tongyi Zhai, Bohan Zhu, Pengcheng Qian, Longwu Ye

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1501-1508 DOI: 10.6023/cjoc202201006

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Silver-Catalyzed Synthesis of CF₃-Substituted 2-Imidazolines

Ming Yang, Danfeng Huang, Kehu Wang, Tongyu Han, Pengfei Zhao, Feng Wang, Junjiao Wang, Yingpeng Su, Yulai Hu

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1509-1519 DOI: 10.6023/cjoc202111009

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Chiral Squaramide Catalyzed Enantioselective Michael Addition of Cyclic 1,3-Diketones to β,γ-Unsaturated α-Keto Esters

Zhiwei Ma, Xiaopei Chen, Chuanchuan Wang, Jianling Wang, Jingchao Tao, Quanjian Lü

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1520-1526 DOI: 10.6023/cjoc202111030

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Design, Synthesis and Bioactivity of Novel Fluoropyrazole Hydrazides

Changkai Wang, Tengda Sun, Xuebo Zhang, Xinling Yang, Xingxing Lu, Huan Xu, Fasheng Shi, Li Zhang, Yun Ling

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1527-1536 DOI: 10.6023/cjoc202112021

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Electrochemical Oxidative Trifluoromethylation of α-Oxoketene Ketene Dithioacetals with CF₃SO₂Na

Qingyun Gu, Zhenfeng Cheng, Xiaobao Zeng

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1537-1544 DOI: 10.6023/cjoc202112024

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Oxidation of Sulfides with SO₂F₂/H₂O₂/Base

Yi Zhou, Zhuojun Li, Minghui Hu, Zhaohua Yan, Sen Lin

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1545-1550 DOI: 10.6023/cjoc202111022

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NOTES

One-Step Synthesis of 1,2,4-Triazolo[3,4-i]purine Derivatives

Zhiliang Chu, Huijuan Chen, Shuai Shan, Xiaona Wang, Chunfang Gao, Guirong Qu, Zhongyu Liu, Haiming Guo

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1551-1556 DOI: 10.6023/cjoc202110007

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Discovery of a New Polycyclic Tetramate Macrolactam 3-Hydroxycombamide I

Yaqian Yan, Haoxin Wang, Yaoyao Li

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1557-1561 DOI: 10.6023/cjoc202110001

Abstract( 317) HTML( 8) PDF(1164KB)( 188 )

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HIGHLIGHTS

Catalytic Asymmetric Dearomatization (CADA) through Activation of Ynamide by Chiral Brønsted Acids

Wenzhao Zhang, Sanzhong Luo

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1562-1564 DOI: 10.6023/cjoc202200023

Abstract( 457) HTML( 22) PDF(414KB)( 371 )

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Near-Infrared Photocatalytic Oxidation Functionalization Mediated by Gold Nanoclusters

Rongnan Yi, Weimin He

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1565-1566 DOI: 10.6023/cjoc202200024

Abstract( 329) HTML( 5) PDF(456KB)( 217 )

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Photoredox Nickel-Catalyzed Asymmetric Reductive Cross Coupling

Kun Cui, Gongqiang Li, Ji-Bao Xia

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1567-1568 DOI: 10.6023/cjoc202200025

Abstract( 487) HTML( 15) PDF(447KB)( 411 )

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Synthesis of Chiral Spirocycles by the Enantioselective Domino Heck/Remote C(sp²)—H Alkylation Reaction Catalyzed by Palladium/Xu-Phos

Manman Wang

Chinese Journal of Organic Chemistry 2022, 42 (5), pp 1569-1571 DOI: 10.6023/cjoc202200026

Abstract( 343) HTML( 14) PDF(501KB)( 207 )

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