Chinese Journal of Organic Chemistry ›› 2023, Vol. 43 ›› Issue (9): 3312-3318.DOI: 10.6023/cjoc202301024 Previous Articles Next Articles
收稿日期:
2023-01-29
修回日期:
2023-03-26
发布日期:
2023-05-11
基金资助:
Min Xi, Chao Duan, Jie Chi, Tian Fu, Xiaolong Su, Hongshe Wang()
Received:
2023-01-29
Revised:
2023-03-26
Published:
2023-05-11
Contact:
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Min Xi, Chao Duan, Jie Chi, Tian Fu, Xiaolong Su, Hongshe Wang. An Efficient and Rapid Synthesis of α-Aminonitriles via Strecker Reaction Catalyzed by Humic Acid[J]. Chinese Journal of Organic Chemistry, 2023, 43(9): 3312-3318.
Entry | Conditions | Yield/% | Reference |
---|---|---|---|
1a | Mitsunobu's reagent (100 mol%), solvent-free, r.t., 20 min | 98 | [35] |
2 | Fe3O4 (10 mol%), solvent-free, r.t., 20 min | 95 | [16] |
3 | TiCl3•4H2O (1 mol%), solvent-free, r.t., 15 min | 94 | [36] |
4 | SO42–/ZrO2 (0.1 g/mmol), THF, r.t., 90 min | 93 | [37] |
5a | I2 (10 mol%), CH3CN, r.t., 1 h | 94 | [19] |
6 | Fe3O4@SiO2 core-shell MNP (1 mg/mmol), solvent-free, 50 ℃, 30 min | 87 | [13] |
7 | Fe3O4@cellulose-OSO3H (0.04 g/mmol), EtOH, r.t., 15 min | 87 | [38] |
8 | Cd(II)-MOF (3 mol%), solvent-free, r.t., 6 h | 91 | [29f] |
9 | SmI3 (10 mol%), THF, r.t., 30 min | 98 | [27] |
10a | Humic acid (0.1 g/mmol), solvent-free, r.t., 5 min | 98 | This work |
Entry | Conditions | Yield/% | Reference |
---|---|---|---|
1a | Mitsunobu's reagent (100 mol%), solvent-free, r.t., 20 min | 98 | [35] |
2 | Fe3O4 (10 mol%), solvent-free, r.t., 20 min | 95 | [16] |
3 | TiCl3•4H2O (1 mol%), solvent-free, r.t., 15 min | 94 | [36] |
4 | SO42–/ZrO2 (0.1 g/mmol), THF, r.t., 90 min | 93 | [37] |
5a | I2 (10 mol%), CH3CN, r.t., 1 h | 94 | [19] |
6 | Fe3O4@SiO2 core-shell MNP (1 mg/mmol), solvent-free, 50 ℃, 30 min | 87 | [13] |
7 | Fe3O4@cellulose-OSO3H (0.04 g/mmol), EtOH, r.t., 15 min | 87 | [38] |
8 | Cd(II)-MOF (3 mol%), solvent-free, r.t., 6 h | 91 | [29f] |
9 | SmI3 (10 mol%), THF, r.t., 30 min | 98 | [27] |
10a | Humic acid (0.1 g/mmol), solvent-free, r.t., 5 min | 98 | This work |
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