Chinese Journal of Organic Chemistry ›› 2023, Vol. 43 ›› Issue (10): 3339-3351.DOI: 10.6023/cjoc202305016 Previous Articles     Next Articles

Special Issue: 有机硅化学专辑-2023


孙伟, 朱守非*()   

  1. 南开大学化学学院 元素有机化学国家重点实验室 有机新物质创造前沿科学中心 天津 300071
  • 收稿日期:2023-05-14 修回日期:2023-06-23 发布日期:2023-07-12
  • 基金资助:
    国家重点研发计划(2021YFA1500200); 国家自然科学基金(92256301); 国家自然科学基金(92156006); 国家自然科学基金(22221002); 国家自然科学基金(21971119); 高等学校学科创新引智计划(111 Project); 高等学校学科创新引智计划(B06005); 中央高校基本科研业务费专项资金以及科学探索奖

Hydrosilylation Reactions of Alkene with Tertiary Silanes Catalyzed by Iron-Series Metals

Wei Sun, Shoufei Zhu()   

  1. Frontiers Science Center for New Organic Matter, State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071
  • Received:2023-05-14 Revised:2023-06-23 Published:2023-07-12
  • Contact: *E-mail:
  • Supported by:
    National Key R&D Program of China(2021YFA1500200); National Natural Science Foundation of China(92256301); National Natural Science Foundation of China(92156006); National Natural Science Foundation of China(22221002); National Natural Science Foundation of China(21971119); Program of Introducing Talents of Discipline to Universities(111 Project); Program of Introducing Talents of Discipline to Universities(B06005); Haihe Laboratory of Sustainable Chemical Transformations, and the Fundamental Research Funds for the Central Universities, and the XPLORER PRIZE

Transition metal-catalyzed hydrosilylation of alkene has become one of the most important and fundamental homogeneous catalytic reactions, however, such reactions still face the problems of massive consumption of precious metal catalysts in industrial applications. Iron-series metals are abundant in the Earth's crust, cheap, easy to obtain, and biocompatible. Compared with precious metals such as platinum, iron-series metals have many advantages as catalysts, but there are still large gaps in catalytic hydrosilylation of alkene and tertiary silanes, especially involving industrial applications of silicones, and cannot replace precious metal catalysts for large-scale industrial production at current stage. The development of new iron-series metal catalysts for the efficient and highly selective hydrosilylation reaction of alkene with tertiary silanes and the in-depth discovery of the regulations on activity and selectivity of the catalysts are of great research value and have become a hot research area with a series of important progresses. The research progress in the hydrosilylation of olefins and tertiary silanes catalyzed by iron-series metals is systematically reviewed, the challenges faced in this field are discussed and the future development direction of this field is also prospected. Only the reactions promoted by homogeneous catalysts are introduced.

Key words: iron-series metals, alkene hydrosilylation, tertiary silanes, silicones